Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau
Gaseous elemental mercury (Hg 0 ) was investigated in the troposphere and in the interstitial air extracted from the snow at Dome Concordia station (alt. 3320 m) on the Antarctic Plateau during January 2009. Measurements and modeling studies showed evidence of a very dynamic and daily cycling of Hg...
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ftdoajarticles:oai:doaj.org/article:8c2ddf5feaec4973aabd2949fe550da7 2023-05-15T13:56:15+02:00 Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau A. Dommergue M. Barret J. Courteaud P. Cristofanelli C. P. Ferrari H. Gallée 2012-11-01T00:00:00Z https://doi.org/10.5194/acp-12-11027-2012 https://doaj.org/article/8c2ddf5feaec4973aabd2949fe550da7 EN eng Copernicus Publications http://www.atmos-chem-phys.net/12/11027/2012/acp-12-11027-2012.pdf https://doaj.org/toc/1680-7316 https://doaj.org/toc/1680-7324 doi:10.5194/acp-12-11027-2012 1680-7316 1680-7324 https://doaj.org/article/8c2ddf5feaec4973aabd2949fe550da7 Atmospheric Chemistry and Physics, Vol 12, Iss 22, Pp 11027-11036 (2012) Physics QC1-999 Chemistry QD1-999 article 2012 ftdoajarticles https://doi.org/10.5194/acp-12-11027-2012 2022-12-31T02:10:32Z Gaseous elemental mercury (Hg 0 ) was investigated in the troposphere and in the interstitial air extracted from the snow at Dome Concordia station (alt. 3320 m) on the Antarctic Plateau during January 2009. Measurements and modeling studies showed evidence of a very dynamic and daily cycling of Hg 0 inside the mixing layer with a range of values from 0.2 ng m −3 up to 2.3 ng m −3 . During low solar irradiation periods, fast Hg 0 oxidation processes in a confined layer were suspected. Unexpectedly high Hg 0 concentrations for such a remote place were measured under higher solar irradiation due to snow photochemistry. We suggest that a daily cycling of reemission/oxidation occurs during summer within the mixing layer at Dome Concordia. Hg 0 concentrations showed a negative correlation with ozone mixing ratios, which contrasts with atmospheric mercury depletion events observed during the Arctic spring. Unlike previous Antarctic studies, we think that atmospheric Hg 0 removal may not be the result of advection processes. The daily and dramatic Hg 0 losses could be a consequence of surface or snow induced oxidation pathways. It remains however unclear whether halogens are involved. The cycling of other oxidants should be investigated together with Hg species in order to clarify the complex reactivity on the Antarctic plateau. Article in Journal/Newspaper Antarc* Antarctic Arctic Directory of Open Access Journals: DOAJ Articles Arctic Antarctic The Antarctic Concordia Station ENVELOPE(123.333,123.333,-75.100,-75.100) Atmospheric Chemistry and Physics 12 22 11027 11036 |
institution |
Open Polar |
collection |
Directory of Open Access Journals: DOAJ Articles |
op_collection_id |
ftdoajarticles |
language |
English |
topic |
Physics QC1-999 Chemistry QD1-999 |
spellingShingle |
Physics QC1-999 Chemistry QD1-999 A. Dommergue M. Barret J. Courteaud P. Cristofanelli C. P. Ferrari H. Gallée Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau |
topic_facet |
Physics QC1-999 Chemistry QD1-999 |
description |
Gaseous elemental mercury (Hg 0 ) was investigated in the troposphere and in the interstitial air extracted from the snow at Dome Concordia station (alt. 3320 m) on the Antarctic Plateau during January 2009. Measurements and modeling studies showed evidence of a very dynamic and daily cycling of Hg 0 inside the mixing layer with a range of values from 0.2 ng m −3 up to 2.3 ng m −3 . During low solar irradiation periods, fast Hg 0 oxidation processes in a confined layer were suspected. Unexpectedly high Hg 0 concentrations for such a remote place were measured under higher solar irradiation due to snow photochemistry. We suggest that a daily cycling of reemission/oxidation occurs during summer within the mixing layer at Dome Concordia. Hg 0 concentrations showed a negative correlation with ozone mixing ratios, which contrasts with atmospheric mercury depletion events observed during the Arctic spring. Unlike previous Antarctic studies, we think that atmospheric Hg 0 removal may not be the result of advection processes. The daily and dramatic Hg 0 losses could be a consequence of surface or snow induced oxidation pathways. It remains however unclear whether halogens are involved. The cycling of other oxidants should be investigated together with Hg species in order to clarify the complex reactivity on the Antarctic plateau. |
format |
Article in Journal/Newspaper |
author |
A. Dommergue M. Barret J. Courteaud P. Cristofanelli C. P. Ferrari H. Gallée |
author_facet |
A. Dommergue M. Barret J. Courteaud P. Cristofanelli C. P. Ferrari H. Gallée |
author_sort |
A. Dommergue |
title |
Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau |
title_short |
Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau |
title_full |
Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau |
title_fullStr |
Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau |
title_full_unstemmed |
Dynamic recycling of gaseous elemental mercury in the boundary layer of the Antarctic Plateau |
title_sort |
dynamic recycling of gaseous elemental mercury in the boundary layer of the antarctic plateau |
publisher |
Copernicus Publications |
publishDate |
2012 |
url |
https://doi.org/10.5194/acp-12-11027-2012 https://doaj.org/article/8c2ddf5feaec4973aabd2949fe550da7 |
long_lat |
ENVELOPE(123.333,123.333,-75.100,-75.100) |
geographic |
Arctic Antarctic The Antarctic Concordia Station |
geographic_facet |
Arctic Antarctic The Antarctic Concordia Station |
genre |
Antarc* Antarctic Arctic |
genre_facet |
Antarc* Antarctic Arctic |
op_source |
Atmospheric Chemistry and Physics, Vol 12, Iss 22, Pp 11027-11036 (2012) |
op_relation |
http://www.atmos-chem-phys.net/12/11027/2012/acp-12-11027-2012.pdf https://doaj.org/toc/1680-7316 https://doaj.org/toc/1680-7324 doi:10.5194/acp-12-11027-2012 1680-7316 1680-7324 https://doaj.org/article/8c2ddf5feaec4973aabd2949fe550da7 |
op_doi |
https://doi.org/10.5194/acp-12-11027-2012 |
container_title |
Atmospheric Chemistry and Physics |
container_volume |
12 |
container_issue |
22 |
container_start_page |
11027 |
op_container_end_page |
11036 |
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1766263616698318848 |