Experimental Simulation of Hydrate Formation Process in a Circulating Device

• Published in: Processes
• Main Authors: Dávid Hečko, Pavol Mičko, Michal Holubčík, Andrej Kapjor
• Format: Article in Journal/Newspaper
• Language: English
• Published: MDPI AG 2021
• Subjects: methane; hydrate; modelling and simulation; energy storage; experimental device; Chemical technology; TP1-1185; Chemistry; QD1-999; Methane hydrate
• Online Access: https://doi.org/10.3390/pr9091529; https://doaj.org/article/834cc88e4a62424fb002cf3546123b80

This paper focuses on the model of gas hydrate formation in an experimental device, which allows the circulation of the resulting mixture (water and gas) and significantly accelerates the process of hydrate formation in the laboratory. A 3D model was developed to better imagine the placement of individual parts of the device. The kinetics of hydrate formation were predicted from equilibrium values of chemical potentials. The aim of solving the equations of state gases in the mathematical model was to optimize the parameters involved in the formation of hydrates. The prediction of the mathematical model was verified by numerical simulation. The mathematical model and numerical simulation predict the chemical reaction evolving over time and determine the amount of crystallized water in the reactor. A remarkable finding is that the deviation of the model and simulation at the initiation the calculation of crystallized water starts at 76% and decreases over time to 2%. Subsequently, the number of moles of bound gas in the hydrate acquires the same percentage deviations. The amount of water supplied to the reactor is expressed by both methods identically with a maximum deviation of 0.10%. The different character is shown by the number of moles of gas remaining in the reactor. At the beginning of the calculation, the deviation of both methods is 0%, but over time the deviation slowly increases, and at the end it expresses the number of moles in the reactor with a deviation of 0.14%. By previous detection, we can confirm that the model successfully determines the amount of methane hydrate formed in the reactor of the experimental equipment. With the attached pictures from the realized experiment, we confirmed that the proposed method of hydrate production is tested and takes minutes. The article calculates the energy efficiency of natural gas hydrate in the proposed experimental device.