Aragonite saturation states and pH in western Norwegian fjords: seasonal cycles and controlling factors, 2005–2009

• Published in: Ocean Science
• Main Authors: A. M. Omar, I. Skjelvan, S. R. Erga, A. Olsen
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2016
• Subjects: Geography. Anthropology. Recreation; G; Environmental sciences; GE1-350; Ocean acidification
• Online Access: https://doi.org/10.5194/os-12-937-2016; https://doaj.org/article/65df04a237b349e987054ec024cf3575

The uptake of anthropogenic carbon dioxide (CO 2 ) by the ocean leads to a process known as ocean acidification (OA), which lowers the aragonite saturation state (Ω Ar ) and pH, and this is poorly documented in coastal environments including fjords due to lack of appropriate observations. Here we use weekly underway data from the Voluntary Observing Ships (VOS) program covering the period 2005–2009 combined with data from research cruises to estimate Ω Ar and pH values in several adjacent western Norwegian fjords, and to evaluate how seawater CO 2 chemistry drives their variations in response to physical and biological factors. The OA parameters in the surface waters of the fjords are subject to strong seasonal and spatially coherent variations. These changes are governed by the seasonal changes in temperature, salinity, formation and decay of organic matter, and vertical mixing with deeper, carbon-rich coastal water. Annual mean pH and Ω Ar values were 8.13 and 2.21, respectively. The former varies from minimum values ( ≈ 8.05) in late December – early January to maximum values of around 8.2 during early spring (March–April) as a consequence of the phytoplankton spring bloom, which reduces dissolved inorganic carbon (DIC). In the following months, pH decreases in response to warming. This thermodynamic decrease in pH is reinforced by the deepening of the mixed layer, which enables carbon-rich coastal water to reach the surface, and this trend continues until the low winter values of pH are reached again. Ω Ar , on the other hand, reaches its seasonal maximum (> 2.5) in mid- to late summer (July–September), when the spring bloom is over and pH is decreasing. The lowest Ω Ar values ( ≈ 1.3–1.6) occur during winter (January–March), when both pH and sea surface temperature (SST) are low and DIC is its highest. Consequently, seasonal Ω Ar variations align with those of SST and salinity normalized DIC (nDIC). We demonstrate that underway measurements of fugacity of CO 2 in seawater ( f CO 2 ) and SST from VOS ...