Dracocephalum palmatum S. and Dracocephalum ruyschiana L. Originating from Yakutia: A High-Resolution Mass Spectrometric Approach for the Comprehensive Characterization of Phenolic Compounds
Dracocephalum palmatum S. and Dracocephalum ruyschiana L. contain a large number of target analytes, which are biologically active compounds. High performance liquid chromatography (HPLC) in combination with an ion trap (tandem mass spectrometry) was used to identify target analytes in extracts of D...
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MDPI AG
2022
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ftdoajarticles:oai:doaj.org/article:61d0f0a468144539a11be75e20b6e71f 2023-05-15T18:44:54+02:00 Dracocephalum palmatum S. and Dracocephalum ruyschiana L. Originating from Yakutia: A High-Resolution Mass Spectrometric Approach for the Comprehensive Characterization of Phenolic Compounds Zhanna M. Okhlopkova Mayya P. Razgonova Konstantin S. Pikula Alexander M. Zakharenko Wojciech Piekoszewski Yuri A. Manakov Sezai Ercisli Kirill S. Golokhvast 2022-02-01T00:00:00Z https://doi.org/10.3390/app12031766 https://doaj.org/article/61d0f0a468144539a11be75e20b6e71f EN eng MDPI AG https://www.mdpi.com/2076-3417/12/3/1766 https://doaj.org/toc/2076-3417 doi:10.3390/app12031766 2076-3417 https://doaj.org/article/61d0f0a468144539a11be75e20b6e71f Applied Sciences, Vol 12, Iss 1766, p 1766 (2022) Dracocephalum palmatum Dracocephalum ruyschiana ion trap tandem mass spectrometry polyphenolic compounds Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 article 2022 ftdoajarticles https://doi.org/10.3390/app12031766 2022-12-31T15:04:19Z Dracocephalum palmatum S. and Dracocephalum ruyschiana L. contain a large number of target analytes, which are biologically active compounds. High performance liquid chromatography (HPLC) in combination with an ion trap (tandem mass spectrometry) was used to identify target analytes in extracts of D. palmatum S. and D. ruyschiana L. originating from Yakutia. The results of initial studies revealed the presence of 114 compounds, of which 92 were identified for the first time in the genus Dracocephalum . New identified metabolites belonged to 17 classes, including 16 phenolic acids and their conjugates, 18 flavones, 5 flavonols, 2 flavan-3-ols, 1 flavanone, 2 stilbenes, 10 anthocyanins, 1 condensed tannin, 2 lignans, 6 carotenoids, 3 oxylipins, 2 amino acids, 3 sceletium alkaloids, 3 carboxylic acids, 8 fatty acids, 1 sterol, and 3 terpenes, along with 6 miscellaneous compounds. It was shown that extracts of D. palmatum are richer in the spectrum of polyphenolic compounds compared with extracts of D. ruyschiana , according to a study of the presence of these compounds in extracts, based on the results of mass spectrometric studies. Article in Journal/Newspaper Yakutia Directory of Open Access Journals: DOAJ Articles Applied Sciences 12 3 1766 |
institution |
Open Polar |
collection |
Directory of Open Access Journals: DOAJ Articles |
op_collection_id |
ftdoajarticles |
language |
English |
topic |
Dracocephalum palmatum Dracocephalum ruyschiana ion trap tandem mass spectrometry polyphenolic compounds Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 |
spellingShingle |
Dracocephalum palmatum Dracocephalum ruyschiana ion trap tandem mass spectrometry polyphenolic compounds Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 Zhanna M. Okhlopkova Mayya P. Razgonova Konstantin S. Pikula Alexander M. Zakharenko Wojciech Piekoszewski Yuri A. Manakov Sezai Ercisli Kirill S. Golokhvast Dracocephalum palmatum S. and Dracocephalum ruyschiana L. Originating from Yakutia: A High-Resolution Mass Spectrometric Approach for the Comprehensive Characterization of Phenolic Compounds |
topic_facet |
Dracocephalum palmatum Dracocephalum ruyschiana ion trap tandem mass spectrometry polyphenolic compounds Technology T Engineering (General). Civil engineering (General) TA1-2040 Biology (General) QH301-705.5 Physics QC1-999 Chemistry QD1-999 |
description |
Dracocephalum palmatum S. and Dracocephalum ruyschiana L. contain a large number of target analytes, which are biologically active compounds. High performance liquid chromatography (HPLC) in combination with an ion trap (tandem mass spectrometry) was used to identify target analytes in extracts of D. palmatum S. and D. ruyschiana L. originating from Yakutia. The results of initial studies revealed the presence of 114 compounds, of which 92 were identified for the first time in the genus Dracocephalum . New identified metabolites belonged to 17 classes, including 16 phenolic acids and their conjugates, 18 flavones, 5 flavonols, 2 flavan-3-ols, 1 flavanone, 2 stilbenes, 10 anthocyanins, 1 condensed tannin, 2 lignans, 6 carotenoids, 3 oxylipins, 2 amino acids, 3 sceletium alkaloids, 3 carboxylic acids, 8 fatty acids, 1 sterol, and 3 terpenes, along with 6 miscellaneous compounds. It was shown that extracts of D. palmatum are richer in the spectrum of polyphenolic compounds compared with extracts of D. ruyschiana , according to a study of the presence of these compounds in extracts, based on the results of mass spectrometric studies. |
format |
Article in Journal/Newspaper |
author |
Zhanna M. Okhlopkova Mayya P. Razgonova Konstantin S. Pikula Alexander M. Zakharenko Wojciech Piekoszewski Yuri A. Manakov Sezai Ercisli Kirill S. Golokhvast |
author_facet |
Zhanna M. Okhlopkova Mayya P. Razgonova Konstantin S. Pikula Alexander M. Zakharenko Wojciech Piekoszewski Yuri A. Manakov Sezai Ercisli Kirill S. Golokhvast |
author_sort |
Zhanna M. Okhlopkova |
title |
Dracocephalum palmatum S. and Dracocephalum ruyschiana L. Originating from Yakutia: A High-Resolution Mass Spectrometric Approach for the Comprehensive Characterization of Phenolic Compounds |
title_short |
Dracocephalum palmatum S. and Dracocephalum ruyschiana L. Originating from Yakutia: A High-Resolution Mass Spectrometric Approach for the Comprehensive Characterization of Phenolic Compounds |
title_full |
Dracocephalum palmatum S. and Dracocephalum ruyschiana L. Originating from Yakutia: A High-Resolution Mass Spectrometric Approach for the Comprehensive Characterization of Phenolic Compounds |
title_fullStr |
Dracocephalum palmatum S. and Dracocephalum ruyschiana L. Originating from Yakutia: A High-Resolution Mass Spectrometric Approach for the Comprehensive Characterization of Phenolic Compounds |
title_full_unstemmed |
Dracocephalum palmatum S. and Dracocephalum ruyschiana L. Originating from Yakutia: A High-Resolution Mass Spectrometric Approach for the Comprehensive Characterization of Phenolic Compounds |
title_sort |
dracocephalum palmatum s. and dracocephalum ruyschiana l. originating from yakutia: a high-resolution mass spectrometric approach for the comprehensive characterization of phenolic compounds |
publisher |
MDPI AG |
publishDate |
2022 |
url |
https://doi.org/10.3390/app12031766 https://doaj.org/article/61d0f0a468144539a11be75e20b6e71f |
genre |
Yakutia |
genre_facet |
Yakutia |
op_source |
Applied Sciences, Vol 12, Iss 1766, p 1766 (2022) |
op_relation |
https://www.mdpi.com/2076-3417/12/3/1766 https://doaj.org/toc/2076-3417 doi:10.3390/app12031766 2076-3417 https://doaj.org/article/61d0f0a468144539a11be75e20b6e71f |
op_doi |
https://doi.org/10.3390/app12031766 |
container_title |
Applied Sciences |
container_volume |
12 |
container_issue |
3 |
container_start_page |
1766 |
_version_ |
1766235760573284352 |