Formation of Natural Magnesium Silica Hydrate (M-S-H) and Magnesium Alumina Silica Hydrate (M-A-S-H) Cement

• Published in: Materials
• Main Authors: Håkon Austrheim, Depan Hu, Ole Ivar Ulven, Niels H. Andersen
• Format: Article in Journal/Newspaper
• Language: English
• Published: MDPI AG 2024
• Subjects: serpentinization; weathering; CO 2 sequestration; Feragen and Leka ultramafic complexes; brucite; natural (M-(A)-S-H) cement; Technology; T; Electrical engineering. Electronics. Nuclear engineering; TK1-9971; Engineering (General). Civil engineering (General); TA1-2040; Microscopy; QH201-278.5; Descriptive and experimental mechanics; QC120-168.85; Subarctic
• Online Access: https://doi.org/10.3390/ma17050994; https://doaj.org/article/5faa39ce95e743a6a1e538c3a6c915c8

Occurrences of natural magnesium alumina silicate hydrate (M-(A)-S-H) cement are present in Feragen and Leka, in eastern and western Trøndelag Norway, respectively. Both occurrences are in the subarctic climate zone and form in glacial till and moraine material deposited on ultramafic rock during the Weichselian glaciation. Weathering of serpentinized peridotite dissolves brucite and results in an alkaline fluid with a relatively high pH which subsequently reacts with the felsic minerals of the till (quartz, plagioclase, K-feldspar) to form a cement consisting of an amorphous material or a mixture of nanocrystalline Mg-rich phyllosilicates, including illite. The presence of plagioclase in the till results in the enrichment of alumina in the cement, i.e., forms M-A-S-H instead of the M-S-H cement. Dissolution of quartz results in numerous etch pits and negative quartz crystals filled with M-A-S-H cement. Where the quartz dissolution is faster than the cement precipitation, a honeycomb-like texture is formed. Compositionally, the cemented till (tillite) contains more MgO and has a higher loss of ignition than the till, suggesting that the cement is formed by a MgO fluid that previously reacted with the peridotite. The M-(A)-S-H cemented till represents a new type of duricrust, coined magsilcrete. The study of natural Mg cement provides information on peridotites as a Mg source for Mg cement and as a feedstock for CO 2 sequestration.