New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale
Under the framework of the GMOS project (Global Mercury Observation System) atmospheric mercury monitoring has been implemented at Concordia Station on the high-altitude Antarctic plateau (75°06′ S, 123°20′ E, 3220 m above sea level). We report here the first year-round measurements of gaseous eleme...
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ftdoajarticles:oai:doaj.org/article:548a10f6e91c47ffa84f187e394b3caa 2023-05-15T13:51:07+02:00 New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale H. Angot O. Magand D. Helmig P. Ricaud B. Quennehen H. Gallée M. Del Guasta F. Sprovieri N. Pirrone J. Savarino A. Dommergue 2016-07-01T00:00:00Z https://doi.org/10.5194/acp-16-8249-2016 https://doaj.org/article/548a10f6e91c47ffa84f187e394b3caa EN eng Copernicus Publications https://www.atmos-chem-phys.net/16/8249/2016/acp-16-8249-2016.pdf https://doaj.org/toc/1680-7316 https://doaj.org/toc/1680-7324 doi:10.5194/acp-16-8249-2016 1680-7316 1680-7324 https://doaj.org/article/548a10f6e91c47ffa84f187e394b3caa Atmospheric Chemistry and Physics, Vol 16, Pp 8249-8264 (2016) Physics QC1-999 Chemistry QD1-999 article 2016 ftdoajarticles https://doi.org/10.5194/acp-16-8249-2016 2022-12-31T02:02:29Z Under the framework of the GMOS project (Global Mercury Observation System) atmospheric mercury monitoring has been implemented at Concordia Station on the high-altitude Antarctic plateau (75°06′ S, 123°20′ E, 3220 m above sea level). We report here the first year-round measurements of gaseous elemental mercury (Hg(0)) in the atmosphere and in snowpack interstitial air on the East Antarctic ice sheet. This unique data set shows evidence of an intense oxidation of atmospheric Hg(0) in summer (24-hour daylight) due to the high oxidative capacity of the Antarctic plateau atmosphere in this period of the year. Summertime Hg(0) concentrations exhibited a pronounced daily cycle in ambient air with maximal concentrations around midday. Photochemical reactions and chemical exchange at the air–snow interface were prominent, highlighting the role of the snowpack on the atmospheric mercury cycle. Our observations reveal a 20 to 30 % decrease of atmospheric Hg(0) concentrations from May to mid-August (winter, 24 h darkness). This phenomenon has not been reported elsewhere and possibly results from the dry deposition of Hg(0) onto the snowpack. We also reveal the occurrence of multi-day to weeklong atmospheric Hg(0) depletion events in summer, not associated with depletions of ozone, and likely due to a stagnation of air masses above the plateau triggering an accumulation of oxidants within the shallow boundary layer. Our observations suggest that the inland atmospheric reservoir is depleted in Hg(0) in summer. Due to katabatic winds flowing out from the Antarctic plateau down the steep vertical drops along the coast and according to observations at coastal Antarctic stations, the striking reactivity observed on the plateau most likely influences the cycle of atmospheric mercury on a continental scale. Article in Journal/Newspaper Antarc* Antarctic Antarctica Ice Sheet Directory of Open Access Journals: DOAJ Articles Antarctic Concordia Station ENVELOPE(123.333,123.333,-75.100,-75.100) East Antarctic Ice Sheet The Antarctic Atmospheric Chemistry and Physics 16 13 8249 8264 |
institution |
Open Polar |
collection |
Directory of Open Access Journals: DOAJ Articles |
op_collection_id |
ftdoajarticles |
language |
English |
topic |
Physics QC1-999 Chemistry QD1-999 |
spellingShingle |
Physics QC1-999 Chemistry QD1-999 H. Angot O. Magand D. Helmig P. Ricaud B. Quennehen H. Gallée M. Del Guasta F. Sprovieri N. Pirrone J. Savarino A. Dommergue New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale |
topic_facet |
Physics QC1-999 Chemistry QD1-999 |
description |
Under the framework of the GMOS project (Global Mercury Observation System) atmospheric mercury monitoring has been implemented at Concordia Station on the high-altitude Antarctic plateau (75°06′ S, 123°20′ E, 3220 m above sea level). We report here the first year-round measurements of gaseous elemental mercury (Hg(0)) in the atmosphere and in snowpack interstitial air on the East Antarctic ice sheet. This unique data set shows evidence of an intense oxidation of atmospheric Hg(0) in summer (24-hour daylight) due to the high oxidative capacity of the Antarctic plateau atmosphere in this period of the year. Summertime Hg(0) concentrations exhibited a pronounced daily cycle in ambient air with maximal concentrations around midday. Photochemical reactions and chemical exchange at the air–snow interface were prominent, highlighting the role of the snowpack on the atmospheric mercury cycle. Our observations reveal a 20 to 30 % decrease of atmospheric Hg(0) concentrations from May to mid-August (winter, 24 h darkness). This phenomenon has not been reported elsewhere and possibly results from the dry deposition of Hg(0) onto the snowpack. We also reveal the occurrence of multi-day to weeklong atmospheric Hg(0) depletion events in summer, not associated with depletions of ozone, and likely due to a stagnation of air masses above the plateau triggering an accumulation of oxidants within the shallow boundary layer. Our observations suggest that the inland atmospheric reservoir is depleted in Hg(0) in summer. Due to katabatic winds flowing out from the Antarctic plateau down the steep vertical drops along the coast and according to observations at coastal Antarctic stations, the striking reactivity observed on the plateau most likely influences the cycle of atmospheric mercury on a continental scale. |
format |
Article in Journal/Newspaper |
author |
H. Angot O. Magand D. Helmig P. Ricaud B. Quennehen H. Gallée M. Del Guasta F. Sprovieri N. Pirrone J. Savarino A. Dommergue |
author_facet |
H. Angot O. Magand D. Helmig P. Ricaud B. Quennehen H. Gallée M. Del Guasta F. Sprovieri N. Pirrone J. Savarino A. Dommergue |
author_sort |
H. Angot |
title |
New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale |
title_short |
New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale |
title_full |
New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale |
title_fullStr |
New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale |
title_full_unstemmed |
New insights into the atmospheric mercury cycling in central Antarctica and implications on a continental scale |
title_sort |
new insights into the atmospheric mercury cycling in central antarctica and implications on a continental scale |
publisher |
Copernicus Publications |
publishDate |
2016 |
url |
https://doi.org/10.5194/acp-16-8249-2016 https://doaj.org/article/548a10f6e91c47ffa84f187e394b3caa |
long_lat |
ENVELOPE(123.333,123.333,-75.100,-75.100) |
geographic |
Antarctic Concordia Station East Antarctic Ice Sheet The Antarctic |
geographic_facet |
Antarctic Concordia Station East Antarctic Ice Sheet The Antarctic |
genre |
Antarc* Antarctic Antarctica Ice Sheet |
genre_facet |
Antarc* Antarctic Antarctica Ice Sheet |
op_source |
Atmospheric Chemistry and Physics, Vol 16, Pp 8249-8264 (2016) |
op_relation |
https://www.atmos-chem-phys.net/16/8249/2016/acp-16-8249-2016.pdf https://doaj.org/toc/1680-7316 https://doaj.org/toc/1680-7324 doi:10.5194/acp-16-8249-2016 1680-7316 1680-7324 https://doaj.org/article/548a10f6e91c47ffa84f187e394b3caa |
op_doi |
https://doi.org/10.5194/acp-16-8249-2016 |
container_title |
Atmospheric Chemistry and Physics |
container_volume |
16 |
container_issue |
13 |
container_start_page |
8249 |
op_container_end_page |
8264 |
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1766254708848066560 |