Analysis of an Antarctic ice core by ion chromatography (Mg2+, Na+, Cl−, and SO42− content)

• Main Authors: Magdalena de Mello Marques, Maria do Carmo Ruaro Peralba, Jefferson Cardia Simões, Ronaldo Torma Bernardo, Sharon B. Sneed, Gino Casassa
• Format: Article in Journal/Newspaper
• Language: English; Portuguese
• Published: Sociedade Brasileira de Geoquímica 2014
• Subjects: glaciochemistry; ice core; ion chromatography; Geology; QE1-996.5; Chemistry; QD1-999; Antarctic; The Antarctic; Antarc*; Ice Sheet
• Online Access: https://doaj.org/article/512e900c4ac24cbbb7315f4e2b7d7b75

This study presents the ion chromatography analysis of an Antarctic ice core (IC-3; 85°59’S, 81°35’W) and discusses Mg2+, Na+, Cl-, and SO42− concentration data. The Mg2+, Na+ and Cl- concentration peaks, are environmentally interpreted as winter layers and lower concentrations are considered as summer ones and can be directly associated to sea spray. The higher concentrations in winter are probably caused by transport of marine air masses over the Antarctic ice sheet, which are stronger in this season. There are probably additional sources for Cl− in the IC-3 core region, which could have originated from gaseous HCl adsorption processes, essentially as a result of acid–base reactions between NaCl and HNO3 or H2SO4 in aerosol particles or directly over the snow surface.