Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation
A second-generation bio-based feedstock—tall oil fatty acids—was epoxidised via two pathways. Oxirane rings were introduced into the fatty acid carbon backbone using a heterogeneous epoxidation catalyst-ion exchange resin Amberlite IR-120 H or enzyme catalyst Candida antarctica lipase B under the tr...
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ftdoajarticles:oai:doaj.org/article:4bdb419a3c1d473d870ac912f3da7036 2024-01-14T09:59:25+01:00 Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation Arnis Abolins Ralfs Pomilovskis Edgars Vanags Inese Mierina Slawomir Michalowski Anda Fridrihsone Mikelis Kirpluks 2021-02-01T00:00:00Z https://doi.org/10.3390/ma14040894 https://doaj.org/article/4bdb419a3c1d473d870ac912f3da7036 EN eng MDPI AG https://www.mdpi.com/1996-1944/14/4/894 https://doaj.org/toc/1996-1944 doi:10.3390/ma14040894 1996-1944 https://doaj.org/article/4bdb419a3c1d473d870ac912f3da7036 Materials, Vol 14, Iss 4, p 894 (2021) tall oil fatty acids ion-exchange resin lipase enzyme catalyst high functionality polyols rigid polyurethane foam Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 article 2021 ftdoajarticles https://doi.org/10.3390/ma14040894 2023-12-17T01:45:56Z A second-generation bio-based feedstock—tall oil fatty acids—was epoxidised via two pathways. Oxirane rings were introduced into the fatty acid carbon backbone using a heterogeneous epoxidation catalyst-ion exchange resin Amberlite IR-120 H or enzyme catalyst Candida antarctica lipase B under the trade name Novozym ® 435. High functionality bio-polyols were synthesised from the obtained epoxidated tall oil fatty acids by oxirane ring-opening and subsequent esterification reactions with different polyfunctional alcohols: trimethylolpropane and triethanolamine. The synthesised epoxidised tall oil fatty acids (ETOFA) were studied by proton nuclear magnetic resonance. The chemical structure of obtained polyols was studied by Fourier-transform infrared spectroscopy and size exclusion chromatography. Average molecular weight and polydispersity of polyols were determined from size exclusion chromatography data. The obtained polyols were used to develop rigid polyurethane (PU) foam thermal insulation material with an approximate density of 40 kg/m 3 . Thermal conductivity, apparent density and compression strength of the rigid PU foams were determined. The rigid PU foams obtained from polyols synthesised using Novozym ® 435 catalyst had superior properties in comparison to rigid PU foams obtained from polyols synthesised using Amberlite IR-120 H. The developed rigid PU foams had an excellent thermal conductivity of 21.2–25.9 mW/(m·K). Article in Journal/Newspaper Antarc* Antarctica Directory of Open Access Journals: DOAJ Articles Materials 14 4 894 |
institution |
Open Polar |
collection |
Directory of Open Access Journals: DOAJ Articles |
op_collection_id |
ftdoajarticles |
language |
English |
topic |
tall oil fatty acids ion-exchange resin lipase enzyme catalyst high functionality polyols rigid polyurethane foam Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 |
spellingShingle |
tall oil fatty acids ion-exchange resin lipase enzyme catalyst high functionality polyols rigid polyurethane foam Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 Arnis Abolins Ralfs Pomilovskis Edgars Vanags Inese Mierina Slawomir Michalowski Anda Fridrihsone Mikelis Kirpluks Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation |
topic_facet |
tall oil fatty acids ion-exchange resin lipase enzyme catalyst high functionality polyols rigid polyurethane foam Technology T Electrical engineering. Electronics. Nuclear engineering TK1-9971 Engineering (General). Civil engineering (General) TA1-2040 Microscopy QH201-278.5 Descriptive and experimental mechanics QC120-168.85 |
description |
A second-generation bio-based feedstock—tall oil fatty acids—was epoxidised via two pathways. Oxirane rings were introduced into the fatty acid carbon backbone using a heterogeneous epoxidation catalyst-ion exchange resin Amberlite IR-120 H or enzyme catalyst Candida antarctica lipase B under the trade name Novozym ® 435. High functionality bio-polyols were synthesised from the obtained epoxidated tall oil fatty acids by oxirane ring-opening and subsequent esterification reactions with different polyfunctional alcohols: trimethylolpropane and triethanolamine. The synthesised epoxidised tall oil fatty acids (ETOFA) were studied by proton nuclear magnetic resonance. The chemical structure of obtained polyols was studied by Fourier-transform infrared spectroscopy and size exclusion chromatography. Average molecular weight and polydispersity of polyols were determined from size exclusion chromatography data. The obtained polyols were used to develop rigid polyurethane (PU) foam thermal insulation material with an approximate density of 40 kg/m 3 . Thermal conductivity, apparent density and compression strength of the rigid PU foams were determined. The rigid PU foams obtained from polyols synthesised using Novozym ® 435 catalyst had superior properties in comparison to rigid PU foams obtained from polyols synthesised using Amberlite IR-120 H. The developed rigid PU foams had an excellent thermal conductivity of 21.2–25.9 mW/(m·K). |
format |
Article in Journal/Newspaper |
author |
Arnis Abolins Ralfs Pomilovskis Edgars Vanags Inese Mierina Slawomir Michalowski Anda Fridrihsone Mikelis Kirpluks |
author_facet |
Arnis Abolins Ralfs Pomilovskis Edgars Vanags Inese Mierina Slawomir Michalowski Anda Fridrihsone Mikelis Kirpluks |
author_sort |
Arnis Abolins |
title |
Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation |
title_short |
Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation |
title_full |
Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation |
title_fullStr |
Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation |
title_full_unstemmed |
Impact of Different Epoxidation Approaches of Tall Oil Fatty Acids on Rigid Polyurethane Foam Thermal Insulation |
title_sort |
impact of different epoxidation approaches of tall oil fatty acids on rigid polyurethane foam thermal insulation |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doi.org/10.3390/ma14040894 https://doaj.org/article/4bdb419a3c1d473d870ac912f3da7036 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_source |
Materials, Vol 14, Iss 4, p 894 (2021) |
op_relation |
https://www.mdpi.com/1996-1944/14/4/894 https://doaj.org/toc/1996-1944 doi:10.3390/ma14040894 1996-1944 https://doaj.org/article/4bdb419a3c1d473d870ac912f3da7036 |
op_doi |
https://doi.org/10.3390/ma14040894 |
container_title |
Materials |
container_volume |
14 |
container_issue |
4 |
container_start_page |
894 |
_version_ |
1788059088693755904 |