Spatial variations in snowpack chemistry, isotopic composition of NO 3 − and nitrogen deposition from the ice sheet margin to the coast of western Greenland

• Published in: Biogeosciences
• Main Authors: C. J. Curtis, J. Kaiser, A. Marca, N. J. Anderson, G. Simpson, V. Jones, E. Whiteford
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2018
• Subjects: Ecology; QH540-549.5; Life; QH501-531; Geology; QE1-996.5; Arctic; Greenland; Climate change; Ice Sheet
• Online Access: https://doi.org/10.5194/bg-15-529-2018; https://doaj.org/article/26a1e5007f334f3784bbd76a58e28c82

The relative roles of anthropogenic nitrogen (N) deposition and climate change in causing ecological change in remote Arctic ecosystems, especially lakes, have been the subject of debate over the last decade. Some palaeoecological studies have cited isotopic signals ( δ ( 15 N)) preserved in lake sediments as evidence linking N deposition with ecological change, but a key limitation has been the lack of co-located data on both deposition input fluxes and isotopic composition of deposited nitrate (NO 3 − ). In Arctic lakes, including those in western Greenland, previous palaeolimnological studies have indicated a spatial variation in δ ( 15 N) trends in lake sediments but data are lacking for deposition chemistry, input fluxes and stable isotope composition of NO 3 − . In the present study, snowpack chemistry, NO 3 − stable isotopes and net deposition fluxes for the largest ice-free region in Greenland were investigated to determine whether there are spatial gradients from the ice sheet margin to the coast linked to a gradient in precipitation. Late-season snowpack was sampled in March 2011 at eight locations within three lake catchments in each of three regions (ice sheet margin in the east, the central area near Kelly Ville and the coastal zone to the west). At the coast, snowpack accumulation averaged 181 mm snow water equivalent (SWE) compared with 36 mm SWE by the ice sheet. Coastal snowpack showed significantly greater concentrations of marine salts (Na + , Cl − , other major cations), ammonium (NH 4 + regional means 1.4–2.7 µmol L −1 ), total and non-sea-salt sulfate (SO 4 2− total 1.8–7.7, non-sea-salt 1.0–1.8 µmol L −1 ) than the two inland regions. Nitrate (1.5–2.4 µmol L −1 ) showed significantly lower concentrations at the coast. Despite lower concentrations, higher precipitation at the coast results in greater net deposition for NO 3 − as well as NH 4 + and non-sea-salt sulfate (nss-SO 4 2− ) relative to the inland regions (lowest at Kelly Ville 6, 4 and 3; highest at coast 9, 17 and 11 mol ha −1 ...