Denitrification by large NAT particles: the impact of reduced settling velocities and hints on particle characteristics
Vertical redistribution of HNO 3 through large HNO 3 -containing particles associated with polar stratospheric clouds (PSCs) plays an important role in the chemistry of the Arctic winter stratosphere. During the RECONCILE (Reconciliation of essential process parameters for an enhanced predictability...
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ftdoajarticles:oai:doaj.org/article:18b24114bffb4293a3de46d1b63c3974 2023-05-15T15:01:48+02:00 Denitrification by large NAT particles: the impact of reduced settling velocities and hints on particle characteristics W. Woiwode J.-U. Grooß H. Oelhaf S. Molleker S. Borrmann A. Ebersoldt W. Frey T. Gulde S. Khaykin G. Maucher C. Piesch J. Orphal 2014-10-01T00:00:00Z https://doi.org/10.5194/acp-14-11525-2014 https://doaj.org/article/18b24114bffb4293a3de46d1b63c3974 EN eng Copernicus Publications http://www.atmos-chem-phys.net/14/11525/2014/acp-14-11525-2014.pdf https://doaj.org/toc/1680-7316 https://doaj.org/toc/1680-7324 1680-7316 1680-7324 doi:10.5194/acp-14-11525-2014 https://doaj.org/article/18b24114bffb4293a3de46d1b63c3974 Atmospheric Chemistry and Physics, Vol 14, Iss 20, Pp 11525-11544 (2014) Physics QC1-999 Chemistry QD1-999 article 2014 ftdoajarticles https://doi.org/10.5194/acp-14-11525-2014 2022-12-30T21:26:57Z Vertical redistribution of HNO 3 through large HNO 3 -containing particles associated with polar stratospheric clouds (PSCs) plays an important role in the chemistry of the Arctic winter stratosphere. During the RECONCILE (Reconciliation of essential process parameters for an enhanced predictability of Arctic stratospheric ozone loss and its climate interactions) campaign, apparently very large NAT (nitric acid trihydrate) particles were observed by the airborne in situ probe FSSP-100 (Molleker et al., 2014). Our analysis shows that the FSSP-100 observations associated with the flight on 25 January 2010 cannot easily be explained assuming compact spherical NAT particles due to much too short growing time at temperatures below the existence temperature of NAT ( T NAT ). State-of-the-art simulations using CLaMS (Chemical Lagrangian Model of the Stratosphere; Grooß et al., 2014) suggest considerably smaller particles. We consider the hypothesis that the simulation reproduces the NAT particle masses in a realistic way, but that real NAT particles may have larger apparent sizes compared to compact spherical particles, e.g. due to non-compact morphology or aspheric shape. Our study focuses on the consequence that such particles would have reduced settling velocities compared to compact spheres, altering the vertical redistribution of HNO 3 . Utilising CLaMS simulations, we investigate the impact of reduced settling velocities of NAT particles on vertical HNO 3 redistribution and compare the results with observations of gas-phase HNO 3 by the airborne Fourier transform spectrometer MIPAS-STR associated with two RECONCILE flights. The MIPAS-STR observations confirm conditions consistent with denitrification by NAT particles for the flight on 25 January 2010 and show good agreement with the simulations within the limitations of the comparison. Best agreement is found if settling velocities between 100 and 50% relative to compact spherical particles are considered (slight preference for the 70% scenario). In contrast, ... Article in Journal/Newspaper Arctic Directory of Open Access Journals: DOAJ Articles Arctic Atmospheric Chemistry and Physics 14 20 11525 11544 |
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Directory of Open Access Journals: DOAJ Articles |
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ftdoajarticles |
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English |
topic |
Physics QC1-999 Chemistry QD1-999 |
spellingShingle |
Physics QC1-999 Chemistry QD1-999 W. Woiwode J.-U. Grooß H. Oelhaf S. Molleker S. Borrmann A. Ebersoldt W. Frey T. Gulde S. Khaykin G. Maucher C. Piesch J. Orphal Denitrification by large NAT particles: the impact of reduced settling velocities and hints on particle characteristics |
topic_facet |
Physics QC1-999 Chemistry QD1-999 |
description |
Vertical redistribution of HNO 3 through large HNO 3 -containing particles associated with polar stratospheric clouds (PSCs) plays an important role in the chemistry of the Arctic winter stratosphere. During the RECONCILE (Reconciliation of essential process parameters for an enhanced predictability of Arctic stratospheric ozone loss and its climate interactions) campaign, apparently very large NAT (nitric acid trihydrate) particles were observed by the airborne in situ probe FSSP-100 (Molleker et al., 2014). Our analysis shows that the FSSP-100 observations associated with the flight on 25 January 2010 cannot easily be explained assuming compact spherical NAT particles due to much too short growing time at temperatures below the existence temperature of NAT ( T NAT ). State-of-the-art simulations using CLaMS (Chemical Lagrangian Model of the Stratosphere; Grooß et al., 2014) suggest considerably smaller particles. We consider the hypothesis that the simulation reproduces the NAT particle masses in a realistic way, but that real NAT particles may have larger apparent sizes compared to compact spherical particles, e.g. due to non-compact morphology or aspheric shape. Our study focuses on the consequence that such particles would have reduced settling velocities compared to compact spheres, altering the vertical redistribution of HNO 3 . Utilising CLaMS simulations, we investigate the impact of reduced settling velocities of NAT particles on vertical HNO 3 redistribution and compare the results with observations of gas-phase HNO 3 by the airborne Fourier transform spectrometer MIPAS-STR associated with two RECONCILE flights. The MIPAS-STR observations confirm conditions consistent with denitrification by NAT particles for the flight on 25 January 2010 and show good agreement with the simulations within the limitations of the comparison. Best agreement is found if settling velocities between 100 and 50% relative to compact spherical particles are considered (slight preference for the 70% scenario). In contrast, ... |
format |
Article in Journal/Newspaper |
author |
W. Woiwode J.-U. Grooß H. Oelhaf S. Molleker S. Borrmann A. Ebersoldt W. Frey T. Gulde S. Khaykin G. Maucher C. Piesch J. Orphal |
author_facet |
W. Woiwode J.-U. Grooß H. Oelhaf S. Molleker S. Borrmann A. Ebersoldt W. Frey T. Gulde S. Khaykin G. Maucher C. Piesch J. Orphal |
author_sort |
W. Woiwode |
title |
Denitrification by large NAT particles: the impact of reduced settling velocities and hints on particle characteristics |
title_short |
Denitrification by large NAT particles: the impact of reduced settling velocities and hints on particle characteristics |
title_full |
Denitrification by large NAT particles: the impact of reduced settling velocities and hints on particle characteristics |
title_fullStr |
Denitrification by large NAT particles: the impact of reduced settling velocities and hints on particle characteristics |
title_full_unstemmed |
Denitrification by large NAT particles: the impact of reduced settling velocities and hints on particle characteristics |
title_sort |
denitrification by large nat particles: the impact of reduced settling velocities and hints on particle characteristics |
publisher |
Copernicus Publications |
publishDate |
2014 |
url |
https://doi.org/10.5194/acp-14-11525-2014 https://doaj.org/article/18b24114bffb4293a3de46d1b63c3974 |
geographic |
Arctic |
geographic_facet |
Arctic |
genre |
Arctic |
genre_facet |
Arctic |
op_source |
Atmospheric Chemistry and Physics, Vol 14, Iss 20, Pp 11525-11544 (2014) |
op_relation |
http://www.atmos-chem-phys.net/14/11525/2014/acp-14-11525-2014.pdf https://doaj.org/toc/1680-7316 https://doaj.org/toc/1680-7324 1680-7316 1680-7324 doi:10.5194/acp-14-11525-2014 https://doaj.org/article/18b24114bffb4293a3de46d1b63c3974 |
op_doi |
https://doi.org/10.5194/acp-14-11525-2014 |
container_title |
Atmospheric Chemistry and Physics |
container_volume |
14 |
container_issue |
20 |
container_start_page |
11525 |
op_container_end_page |
11544 |
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1766333808247832576 |