High-resolution glacial and deglacial record of atmospheric methane by continuous-flow and laser spectrometer analysis along the NEEM ice core

• Published in: Climate of the Past
• Main Authors: J. Chappellaz, C. Stowasser, T. Blunier, D. Baslev-Clausen, E. J. Brook, R. Dallmayr, X. Faïn, J. E. Lee, L. E. Mitchell, O. Pascual, D. Romanini, J. Rosen, S. Schüpbach
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2013
• Subjects: Environmental pollution; TD172-193.5; Environmental protection; TD169-171.8; Environmental sciences; GE1-350; Greenland; ice core; North Greenland
• Online Access: https://doi.org/10.5194/cp-9-2579-2013; https://doaj.org/article/14174a2e47844c6191b8fa89f93044e8

The Greenland NEEM (North Greenland Eemian Ice Drilling) operation in 2010 provided the first opportunity to combine trace-gas measurements by laser spectroscopic instruments and continuous-flow analysis along a freshly drilled ice core in a field-based setting. We present the resulting atmospheric methane (CH 4 ) record covering the time period from 107.7 to 9.5 ka b2k (thousand years before 2000 AD). Companion discrete CH 4 measurements are required to transfer the laser spectroscopic data from a relative to an absolute scale. However, even on a relative scale, the high-resolution CH 4 data set significantly improves our knowledge of past atmospheric methane concentration changes. New significant sub-millennial-scale features appear during interstadials and stadials, generally associated with similar changes in water isotopic ratios of the ice, a proxy for local temperature. In addition to the midpoint of Dansgaard–Oeschger (D/O) CH 4 transitions usually used for cross-dating, sharp definition of the start and end of these events brings precise depth markers (with ±20 cm uncertainty) for further cross-dating with other palaeo- or ice core records, e.g. speleothems. The method also provides an estimate of CH 4 rates of change. The onsets of D/O events in the methane signal show a more rapid rate of change than their endings. The rate of CH 4 increase associated with the onsets of D/O events progressively declines from 1.7 to 0.6 ppbv yr −1 in the course of marine isotope stage 3. The largest observed rate of increase takes place at the onset of D/O event #21 and reaches 2.5 ppbv yr −1 .