Chromatographic, Spectrometric and NMR Characterization of a New Set of Glucuronic Acid Esters Synthesized by Lipase

An enzymatic synthesis was developed on a new set of D-glucuronic acid esters and particularly the tetradecyl-D-glucopyranosiduronate also named tetradecyl D-glucuronate. Chromatographic analyses revealed the presence of the ester as a mixture of anomeric forms for carbon chain lengths superior to 1...

Full description

Bibliographic Details
Main Authors: Michel Marlier, Michel Paquot, Patrick Rollin, Florence Chéry, Jacqueline Destain, Pascal Gerbaux, Georges Lognay, Christophe Blecker, Benoît Moreau
Format: Article in Journal/Newspaper
Language:English
French
Published: Presses Agronomiques de Gembloux 2007
Subjects:
Glucuronic acid esters
Candida antarctica lipase B
RP-HPLC
electrospray
NMR
Biotechnology
TP248.13-248.65
Environmental sciences
GE1-350
Antarc*
Antarctica
Online Access:https://doaj.org/article/063f259ac29e41568ca153948b53d6fb
id ftdoajarticles:oai:doaj.org/article:063f259ac29e41568ca153948b53d6fb
record_format openpolar
spelling ftdoajarticles:oai:doaj.org/article:063f259ac29e41568ca153948b53d6fb 2023-05-15T13:57:47+02:00 Chromatographic, Spectrometric and NMR Characterization of a New Set of Glucuronic Acid Esters Synthesized by Lipase Michel Marlier Michel Paquot Patrick Rollin Florence Chéry Jacqueline Destain Pascal Gerbaux Georges Lognay Christophe Blecker Benoît Moreau 2007-01-01T00:00:00Z https://doaj.org/article/063f259ac29e41568ca153948b53d6fb EN FR eng fre Presses Agronomiques de Gembloux http://www.pressesagro.be/base/text/v11n1/9.pdf https://doaj.org/toc/1370-6233 https://doaj.org/toc/1780-4507 1370-6233 1780-4507 https://doaj.org/article/063f259ac29e41568ca153948b53d6fb Biotechnologie, Agronomie, Société et Environnement, Vol 11, Iss 1, Pp 9-17 (2007) Glucuronic acid esters Candida antarctica lipase B RP-HPLC electrospray NMR Biotechnology TP248.13-248.65 Environmental sciences GE1-350 article 2007 ftdoajarticles 2022-12-31T06:02:40Z An enzymatic synthesis was developed on a new set of D-glucuronic acid esters and particularly the tetradecyl-D-glucopyranosiduronate also named tetradecyl D-glucuronate. Chromatographic analyses revealed the presence of the ester as a mixture of anomeric forms for carbon chain lengths superior to 12. TOF/MS and MS/MS studies confirmed the synthesis of glucuronic acid ester. The NMR study also confirmed the structure of glucuronic acid esters and clearly revealed an anomeric (α/β) ratio equivalent to 3/2 Article in Journal/Newspaper Antarc* Antarctica Directory of Open Access Journals: DOAJ Articles
institution Open Polar
collection Directory of Open Access Journals: DOAJ Articles
op_collection_id ftdoajarticles
language English
French
topic Glucuronic acid esters
Candida antarctica lipase B
RP-HPLC
electrospray
NMR
Biotechnology
TP248.13-248.65
Environmental sciences
GE1-350
spellingShingle Glucuronic acid esters
Candida antarctica lipase B
RP-HPLC
electrospray
NMR
Biotechnology
TP248.13-248.65
Environmental sciences
GE1-350
Michel Marlier
Michel Paquot
Patrick Rollin
Florence Chéry
Jacqueline Destain
Pascal Gerbaux
Georges Lognay
Christophe Blecker
Benoît Moreau
Chromatographic, Spectrometric and NMR Characterization of a New Set of Glucuronic Acid Esters Synthesized by Lipase
topic_facet Glucuronic acid esters
Candida antarctica lipase B
RP-HPLC
electrospray
NMR
Biotechnology
TP248.13-248.65
Environmental sciences
GE1-350
description An enzymatic synthesis was developed on a new set of D-glucuronic acid esters and particularly the tetradecyl-D-glucopyranosiduronate also named tetradecyl D-glucuronate. Chromatographic analyses revealed the presence of the ester as a mixture of anomeric forms for carbon chain lengths superior to 12. TOF/MS and MS/MS studies confirmed the synthesis of glucuronic acid ester. The NMR study also confirmed the structure of glucuronic acid esters and clearly revealed an anomeric (α/β) ratio equivalent to 3/2
format Article in Journal/Newspaper
author Michel Marlier
Michel Paquot
Patrick Rollin
Florence Chéry
Jacqueline Destain
Pascal Gerbaux
Georges Lognay
Christophe Blecker
Benoît Moreau
author_facet Michel Marlier
Michel Paquot
Patrick Rollin
Florence Chéry
Jacqueline Destain
Pascal Gerbaux
Georges Lognay
Christophe Blecker
Benoît Moreau
author_sort Michel Marlier
title Chromatographic, Spectrometric and NMR Characterization of a New Set of Glucuronic Acid Esters Synthesized by Lipase
title_short Chromatographic, Spectrometric and NMR Characterization of a New Set of Glucuronic Acid Esters Synthesized by Lipase
title_full Chromatographic, Spectrometric and NMR Characterization of a New Set of Glucuronic Acid Esters Synthesized by Lipase
title_fullStr Chromatographic, Spectrometric and NMR Characterization of a New Set of Glucuronic Acid Esters Synthesized by Lipase
title_full_unstemmed Chromatographic, Spectrometric and NMR Characterization of a New Set of Glucuronic Acid Esters Synthesized by Lipase
title_sort chromatographic, spectrometric and nmr characterization of a new set of glucuronic acid esters synthesized by lipase
publisher Presses Agronomiques de Gembloux
publishDate 2007
url https://doaj.org/article/063f259ac29e41568ca153948b53d6fb
genre Antarc*
Antarctica
genre_facet Antarc*
Antarctica
op_source Biotechnologie, Agronomie, Société et Environnement, Vol 11, Iss 1, Pp 9-17 (2007)
op_relation http://www.pressesagro.be/base/text/v11n1/9.pdf
https://doaj.org/toc/1370-6233
https://doaj.org/toc/1780-4507
1370-6233
1780-4507
https://doaj.org/article/063f259ac29e41568ca153948b53d6fb
_version_ 1766265675211341824

Similar Items