Future impact of non-land based traffic emissions on atmospheric ozone and OH � an optimistic scenario and a possible mitigation strategy

• Published in: Atmospheric Chemistry and Physics
• Main Authors: Hodnebrog, Ø., Berntsen, T. K., Dessens, O., Gauss, M., Grewe, V., Isaksen, I. S. A., Koffi, B., Myhre, G., Olivié, D., Prather, M. J., Pyle, J. A., Stordal, F., Szopa, S., Tang, Q., van Velthoven, P., Williams, J. E., Ødemark, K.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2011
• Subjects: Dynamik der Atmosphäre; North Atlantic
• Online Access: https://elib.dlr.de/71708/; http://www.atmos-chem-phys.net/11/11293/2011/acp-11-11293-2011.pdf

The impact of future emissions from aviation and shipping on the atmospheric chemical composition has been estimated using an ensemble of six different atmospheric chemistry models. This study considers an optimistic emission scenario (B1) taking into account e.g. rapid introduction of clean and resource-efficient technologies, and a mitigation option for the aircraft sector (B1 ACARE), assuming further technological improvements. Results from sensitivity simulations, where emissions from each of the transport sectors were reduced by 5 %, show that emissions from both aircraft and shipping will have a larger impact on atmospheric ozone and OH in near future (2025; B1) and for longer time horizons (2050; B1) compared to recent time (2000). However, the ozone and OH impact from aircraft can be reduced substantially in 2050 if the technological improvements considered in the B1 ACARE will be achieved. Shipping emissions have the largest impact in the marine boundary layer and their ozone contribution may exceed 4 ppbv (when scaling the response of the 5% emission perturbation to 100% by applying a factor 20) overthe North Atlantic Ocean in the future (2050; B1) during northern summer (July). In the zonal mean, shipinduced ozone relative to the background levels may exceed 12% near the surface. Corresponding numbers for OH are 6.0��105 molecules cmâ��3 and 30 %, respectively. This large impact on OH from shipping leads to a relative methane lifetime reduction of 3.92 (�±0.48)% on the global average in 2050 B1 (ensemble mean CH4 lifetime is 8.0 (�±1.0) yr), compared to 3.68 (�±0.47)% in 2000. Aircraft emissions have about 4 times higher ozone enhancement efficiency (ozone molecules enhanced relative to NOx molecules emitted) than shipping emissions, and the maximum impact is found in the UTLS region. Zonal mean aircraft-induced ozone could reach up to 5 ppbv at northern mid- and high latitudes during future summer (July 2050; B1), while the relative impact peaks during northern winter (January) with a ...