Ground-based validation of the MetOp-A and MetOp-B GOME-2 OClO measurements

• Published in: Atmospheric Measurement Techniques
• Main Authors: Pinardi, G., Van Roozendael, M., Hendrick, F., Richter, A., Valks, Pieter, Alwarda, R., Bognar, K., Friess, Udo, Granville, J., Gu, Myojeong, Johnston, P., Prados-Roman, C., Querel, R., Strong, K., Wagner, T., Wittrock, F., Yela, M.
• Format: Article in Journal/Newspaper
• Language: English
• Published: Copernicus Publications 2022
• Subjects: Atmosphärenprozessoren; Arctic; Antarctic; Antarc*
• Online Access: https://elib.dlr.de/186912/; https://amt.copernicus.org/articles/15/3439/2022/

This paper reports on ground-based validation of the atmospheric OClO data record produced within the framework of EUMETSAT's Satellite Application Facility on Atmospheric Chemistry Monitoring (AC SAF) using the Global Ozone Monitoring Experiment (GOME)-2A and GOME-2B instrument measurements, covering the 2007–2016 and 2013–2016 periods, respectively. OClO slant column densities are compared to correlative measurements collected from nine Zenith-Scattered-Light Differential Optical Absorption Spectroscopy (ZSL-DOAS) instruments from the Network for the Detection of Atmospheric Composition Change (NDACC) distributed in both the Arctic and Antarctic. Sensitivity tests are performed on the ground-based data to estimate the impact of the different OClO DOAS analysis settings. On this basis, we infer systematic uncertainties of about 25 % (i.e., about 3.75×10^13 molec. cm−2) between the different ground-based data analyses, reaching total uncertainties ranging from about 26 % to 33 % for the different stations (i.e., around 4 to 5×10^13 molec. cm−2). Time series at the different sites show good agreement between satellite and ground-based data for both the inter-annual variability and the overall OClO seasonal behavior. GOME-2A results are found to be noisier than those of GOME-2B, especially after 2011, probably due to instrumental degradation effects. Daily linear regression analysis for OClO-activated periods yield correlation coefficients of 0.8 for GOME-2A and 0.87 for GOME-2B, with slopes with respect to the ground-based data ensemble of 0.64 and 0.72, respectively. Satellite minus ground-based offsets are within 8×10^13 molec. cm−2, with some differences between GOME-2A and GOME-2B depending on the station. Overall, considering all the stations, a median offset of about -2.2×10^13 molec. cm−2 is found for both GOME-2 instruments.