Deconstruction of tropospheric chemical reactivity using aircraft measurements: the Atmospheric Tomography Mission (ATom) data ...

• Main Authors: Prather, Michael J., Guo, Hao, Flynn, Clare M., Strode, Sarah A., Steenrod, Stephen D., Emmons, Louisa, Lacey, Forrest, Lamarque, Jean-Francois, Fiore, Arlene M., Correa, Gus, Murray, Lee T., Wolfe, Glenn M., St. Clair, Jason M., Kim, Michelle, Crounse, John, Diskin, Glenn, DiGangi, Joshua, Daube, Bruce C., Commane, Roisin, McKain, Kathryn, Peischl, Jeff, Ryerson, Thomas B., Thompson, Chelsea, Hanisco, Thomas F., Blake, Donald, Blake, Nicola J., Apel, Eric C., Hornbrook, Rebecca S., Elkins, James W., Hintsa, Eric J., Moore, Fred L., Wofsy, Steven C., Zhu, Xin
• Format: Dataset
• Language: English
• Published: Dryad 2022
• Subjects: FOS Earth and related environmental sciences; Tropospheric Chemistry; Ozone; Methane; Aircraft Observations; NASA ATom; General Earth and Planetary Sciences; Arctic; Pacific; Southern Ocean; Antarc*; Antarctica; Arctic Basin
• Online Access: https://dx.doi.org/10.7280/d1b12h; https://datadryad.org/stash/dataset/doi:10.7280/D1B12H

The NASA Atmospheric Tomography Mission (ATom) completed four seasonal deployments (August 2016, February 2017, October 2017, May 2018), each with regular 0.2–12 km profiling by transecting the remote Pacific Ocean and Atlantic Ocean basins. Additional data were also acquired for the Southern Ocean, the Arctic basin, and two flights over Antarctica. ATom in situ measurements provide a near-complete chemical characterization of the ∼ 140 000 10 s (80 m by 2 km) air parcels measured along the flight path. This paper presents the Modeling Data Stream (MDS), a continuous gap-filled record of the 10 s parcels containing the chemical species needed to initialize a gas-phase chemistry model for the budgets of tropospheric ozone and methane. Global 3D models have been used to calculate the Reactivity Data Stream (RDS), which is comprised of the chemical reactivities (production and loss) for methane, ozone, and carbon monoxide, through 24 h integration of the 10 s parcels. These parcels accurately sample ... : The Modeling Data Stream (MDS) is based on in situ measurements with the NASA DC-8 aircraft along objectively planned profiling transects through the middle of the Pacific and Atlantic oceans during ATom deployments 1–4. The MDS is merged observations and gap-filled (see published paper) with 10 s (2 km) average data, see Wofsy et al. (2018, 2021) and Thompson et al. (2022). The Reactivity Data Stream (RDS) is derived from the MDS using the UCI chemistry model in a manner described in Prather et al. (2017; 2018). See related papers and dataset DOIs below. An earlier version of the MDS (MDS-0) was used to calculate RDS with six independent chemsitry models, and these results are shown in the published paper. The MDS-0 and RDS-0 versions and other previous versions are not archived here because there were too many errors in the MDS, and so the RDS results should not be used further. If a next-generation multi-model comparison of the calculated reactivities is organized, it is recommended that the MDS-3 data be ...