Origin of megacrysts by carbonate-bearing metasomatism: A case study for the Muskox kimberlite, Slave craton, Canada.
Low-Cr and high-Cr clinopyroxene, garnet, olivine, and ilmenite megacrysts from the Muskox kimberlite (Canada) were analyzed for major and trace elements, as well as Sr, Nd, and Pb isotopes. Samples display compositional overlap with respective phases in websterites, while clinopyroxene isotope syst...
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Geological Society of London
2021
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ftdatacite:10.6084/m9.figshare.c.5255825.v2 2023-05-15T17:13:40+02:00 Origin of megacrysts by carbonate-bearing metasomatism: A case study for the Muskox kimberlite, Slave craton, Canada. Cone, Dylan Kopylova, Maya 2021 https://dx.doi.org/10.6084/m9.figshare.c.5255825.v2 https://geolsoc.figshare.com/collections/Origin_of_megacrysts_by_carbonate-bearing_metasomatism_A_case_study_for_the_Muskox_kimberlite_Slave_craton_Canada_/5255825/2 unknown Geological Society of London https://dx.doi.org/10.1144/jgs2020-184 https://dx.doi.org/10.6084/m9.figshare.c.5255825 Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/legalcode cc-by-4.0 CC-BY Geology FOS Earth and related environmental sciences Collection article 2021 ftdatacite https://doi.org/10.6084/m9.figshare.c.5255825.v2 https://doi.org/10.1144/jgs2020-184 https://doi.org/10.6084/m9.figshare.c.5255825 2021-11-05T12:55:41Z Low-Cr and high-Cr clinopyroxene, garnet, olivine, and ilmenite megacrysts from the Muskox kimberlite (Canada) were analyzed for major and trace elements, as well as Sr, Nd, and Pb isotopes. Samples display compositional overlap with respective phases in websterites, while clinopyroxene isotope systematics reveal similarities with both websteritic and metasomatic clinopyroxene in peridotites from the same kimberlite, in addition to Muskox and Jericho kimberlites. All lithologies may represent the products of mixing between EM1 mantle, relic Proterozoic enriched mantle and HIMU carbonatitic fluid. Equilibrium melts calculated from clinopyroxene trace element data using experimental distribution coefficients for feasible proto kimberlitic melts yield a range of metasomatic agents. Conclusion on the carbonate bearing nature of the metasomatism is based on the presence of a HIMU isotopic signature and results obtained from thermodynamic modeling using the Deep Earth Water model. Modelling was carried out with three fluid compositions; asthenospheric, eclogitic and kimberlitic. Our results suggest mineral compositions analogous to megacrysts cannot be produced by metasomatism of mantle peridotite by carbonate-free hydrous fluids. Isotope systematics argue against a strictly cognate relationship between megacrysts and their host kimberlite, instead suggesting megacrysts and websterites may represent products of regional metasomatism by carbonatitic HIMU fluids shortly predating kimberlite magmatism. Article in Journal/Newspaper muskox DataCite Metadata Store (German National Library of Science and Technology) Canada |
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Open Polar |
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DataCite Metadata Store (German National Library of Science and Technology) |
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language |
unknown |
topic |
Geology FOS Earth and related environmental sciences |
spellingShingle |
Geology FOS Earth and related environmental sciences Cone, Dylan Kopylova, Maya Origin of megacrysts by carbonate-bearing metasomatism: A case study for the Muskox kimberlite, Slave craton, Canada. |
topic_facet |
Geology FOS Earth and related environmental sciences |
description |
Low-Cr and high-Cr clinopyroxene, garnet, olivine, and ilmenite megacrysts from the Muskox kimberlite (Canada) were analyzed for major and trace elements, as well as Sr, Nd, and Pb isotopes. Samples display compositional overlap with respective phases in websterites, while clinopyroxene isotope systematics reveal similarities with both websteritic and metasomatic clinopyroxene in peridotites from the same kimberlite, in addition to Muskox and Jericho kimberlites. All lithologies may represent the products of mixing between EM1 mantle, relic Proterozoic enriched mantle and HIMU carbonatitic fluid. Equilibrium melts calculated from clinopyroxene trace element data using experimental distribution coefficients for feasible proto kimberlitic melts yield a range of metasomatic agents. Conclusion on the carbonate bearing nature of the metasomatism is based on the presence of a HIMU isotopic signature and results obtained from thermodynamic modeling using the Deep Earth Water model. Modelling was carried out with three fluid compositions; asthenospheric, eclogitic and kimberlitic. Our results suggest mineral compositions analogous to megacrysts cannot be produced by metasomatism of mantle peridotite by carbonate-free hydrous fluids. Isotope systematics argue against a strictly cognate relationship between megacrysts and their host kimberlite, instead suggesting megacrysts and websterites may represent products of regional metasomatism by carbonatitic HIMU fluids shortly predating kimberlite magmatism. |
format |
Article in Journal/Newspaper |
author |
Cone, Dylan Kopylova, Maya |
author_facet |
Cone, Dylan Kopylova, Maya |
author_sort |
Cone, Dylan |
title |
Origin of megacrysts by carbonate-bearing metasomatism: A case study for the Muskox kimberlite, Slave craton, Canada. |
title_short |
Origin of megacrysts by carbonate-bearing metasomatism: A case study for the Muskox kimberlite, Slave craton, Canada. |
title_full |
Origin of megacrysts by carbonate-bearing metasomatism: A case study for the Muskox kimberlite, Slave craton, Canada. |
title_fullStr |
Origin of megacrysts by carbonate-bearing metasomatism: A case study for the Muskox kimberlite, Slave craton, Canada. |
title_full_unstemmed |
Origin of megacrysts by carbonate-bearing metasomatism: A case study for the Muskox kimberlite, Slave craton, Canada. |
title_sort |
origin of megacrysts by carbonate-bearing metasomatism: a case study for the muskox kimberlite, slave craton, canada. |
publisher |
Geological Society of London |
publishDate |
2021 |
url |
https://dx.doi.org/10.6084/m9.figshare.c.5255825.v2 https://geolsoc.figshare.com/collections/Origin_of_megacrysts_by_carbonate-bearing_metasomatism_A_case_study_for_the_Muskox_kimberlite_Slave_craton_Canada_/5255825/2 |
geographic |
Canada |
geographic_facet |
Canada |
genre |
muskox |
genre_facet |
muskox |
op_relation |
https://dx.doi.org/10.1144/jgs2020-184 https://dx.doi.org/10.6084/m9.figshare.c.5255825 |
op_rights |
Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/legalcode cc-by-4.0 |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.6084/m9.figshare.c.5255825.v2 https://doi.org/10.1144/jgs2020-184 https://doi.org/10.6084/m9.figshare.c.5255825 |
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1766070847705972736 |