Synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution
The possibility to synthesize stereoregular tris- cis -tris- trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane (tris- cis -tris- trans -[PhSi(O)OH]12) in an inorganic liquid medium – aqueous carbonic acid solution – was shown. The interaction of polyhedral phenylcoppersodiumsiloxane, {[(C 6 H 5 S...
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Taylor & Francis
2016
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ftdatacite:10.6084/m9.figshare.3115501 2023-05-15T15:52:18+02:00 Synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution M. V. Shchemelinina O. I. Shchegolikhina Yu. A. Molodtsova A. A. Anisimov A. S. Goloveshkin E. G. Kononova M. A. Pigaleva I. V. Elmanovich M. O. Gallyamov A. M. Muzafarov 2016 https://dx.doi.org/10.6084/m9.figshare.3115501 https://tandf.figshare.com/articles/journal_contribution/Synthesis_of_macrocyclic_tris_i_cis_i_tris_i_trans_i_dodeca_phenyl_hydroxy_cyclododecasiloxane_in_carbonic_acid_solution/3115501/1 unknown Taylor & Francis https://dx.doi.org/10.1080/17518253.2016.1151084 Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/legalcode cc-by-4.0 CC-BY Biophysics Biochemistry Medicine 39999 Chemical Sciences not elsewhere classified FOS Chemical sciences Text article-journal Journal contribution ScholarlyArticle 2016 ftdatacite https://doi.org/10.6084/m9.figshare.3115501 https://doi.org/10.1080/17518253.2016.1151084 2021-11-05T12:55:41Z The possibility to synthesize stereoregular tris- cis -tris- trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane (tris- cis -tris- trans -[PhSi(O)OH]12) in an inorganic liquid medium – aqueous carbonic acid solution – was shown. The interaction of polyhedral phenylcoppersodiumsiloxane, {[(C 6 H 5 Si(O)O − ] 12 (Cu 2 + ) 4 (Na + ) 4 }*(L) m (L = Bu n OH, H 2 O), with carbonic acid can be considered as a new ‘green’ method to obtain functional organosiloxane macrocycles. In contrast to the known methods, no organic solvents were used during the reaction. The identification of the structure of the end compound was performed by means of NMR and Infrared spectroscopy as well as X-ray crystallography. Text Carbonic acid DataCite Metadata Store (German National Library of Science and Technology) |
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Biophysics Biochemistry Medicine 39999 Chemical Sciences not elsewhere classified FOS Chemical sciences |
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Biophysics Biochemistry Medicine 39999 Chemical Sciences not elsewhere classified FOS Chemical sciences M. V. Shchemelinina O. I. Shchegolikhina Yu. A. Molodtsova A. A. Anisimov A. S. Goloveshkin E. G. Kononova M. A. Pigaleva I. V. Elmanovich M. O. Gallyamov A. M. Muzafarov Synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution |
topic_facet |
Biophysics Biochemistry Medicine 39999 Chemical Sciences not elsewhere classified FOS Chemical sciences |
description |
The possibility to synthesize stereoregular tris- cis -tris- trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane (tris- cis -tris- trans -[PhSi(O)OH]12) in an inorganic liquid medium – aqueous carbonic acid solution – was shown. The interaction of polyhedral phenylcoppersodiumsiloxane, {[(C 6 H 5 Si(O)O − ] 12 (Cu 2 + ) 4 (Na + ) 4 }*(L) m (L = Bu n OH, H 2 O), with carbonic acid can be considered as a new ‘green’ method to obtain functional organosiloxane macrocycles. In contrast to the known methods, no organic solvents were used during the reaction. The identification of the structure of the end compound was performed by means of NMR and Infrared spectroscopy as well as X-ray crystallography. |
format |
Text |
author |
M. V. Shchemelinina O. I. Shchegolikhina Yu. A. Molodtsova A. A. Anisimov A. S. Goloveshkin E. G. Kononova M. A. Pigaleva I. V. Elmanovich M. O. Gallyamov A. M. Muzafarov |
author_facet |
M. V. Shchemelinina O. I. Shchegolikhina Yu. A. Molodtsova A. A. Anisimov A. S. Goloveshkin E. G. Kononova M. A. Pigaleva I. V. Elmanovich M. O. Gallyamov A. M. Muzafarov |
author_sort |
M. V. Shchemelinina |
title |
Synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution |
title_short |
Synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution |
title_full |
Synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution |
title_fullStr |
Synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution |
title_full_unstemmed |
Synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution |
title_sort |
synthesis of macrocyclic tris -cis- tris -trans - dodeca[(phenyl)(hydroxy)]cyclododecasiloxane in carbonic acid solution |
publisher |
Taylor & Francis |
publishDate |
2016 |
url |
https://dx.doi.org/10.6084/m9.figshare.3115501 https://tandf.figshare.com/articles/journal_contribution/Synthesis_of_macrocyclic_tris_i_cis_i_tris_i_trans_i_dodeca_phenyl_hydroxy_cyclododecasiloxane_in_carbonic_acid_solution/3115501/1 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_relation |
https://dx.doi.org/10.1080/17518253.2016.1151084 |
op_rights |
Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/legalcode cc-by-4.0 |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.6084/m9.figshare.3115501 https://doi.org/10.1080/17518253.2016.1151084 |
_version_ |
1766387531103862784 |