Lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media
Recently, several scientific groups investigated the suitable enzymatic route for synthesis of structured phenolic lipids for cosmetic and nutritive purposes. The feruloylated palm stearin (FPS) was obtained from enzymatic transesterification reactions of palm stearin with ferulic acid in solvent-fr...
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ftdatacite:10.6084/m9.figshare.14938691 2023-05-15T13:47:12+02:00 Lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media Abdelgawad, Ahmed Eid, Mounir Abou-Elmagd, Wael Abou-Elregal, Mohsen 2021 https://dx.doi.org/10.6084/m9.figshare.14938691 https://tandf.figshare.com/articles/journal_contribution/Lipase_catalysed_transesterification_of_palm_stearin_with_ferulic_acid_in_solvent-free_media/14938691 unknown Taylor & Francis https://dx.doi.org/10.1080/10242422.2021.1949001 Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/legalcode cc-by-4.0 CC-BY Biophysics Biochemistry Microbiology FOS Biological sciences Genetics Molecular Biology Physiology Pharmacology Biotechnology 39999 Chemical Sciences not elsewhere classified FOS Chemical sciences Ecology Sociology FOS Sociology 69999 Biological Sciences not elsewhere classified Inorganic Chemistry Science Policy Plant Biology Text article-journal Journal contribution ScholarlyArticle 2021 ftdatacite https://doi.org/10.6084/m9.figshare.14938691 https://doi.org/10.1080/10242422.2021.1949001 2021-11-05T12:55:41Z Recently, several scientific groups investigated the suitable enzymatic route for synthesis of structured phenolic lipids for cosmetic and nutritive purposes. The feruloylated palm stearin (FPS) was obtained from enzymatic transesterification reactions of palm stearin with ferulic acid in solvent-free media with 1 mmol of glycerol or without it, using non-specific lipases, NovoCor ADL ( Candida antarctica lipase A); Novozyme435 ® ( Candida antarctica lipase B), and 1,3-specific lipase Lipozyme TL 100L from Thermomyces lanuginosus . The individual lipases and their combinational systems were examined. ESI + -MS/MS confirmed the formation of 19 feruloylated compounds. FPSs were produced by all lipases and their combinations. The positive synergetic effect occurred for 1,3-specific lipase and unspecified lipases with mass ratio 8:2, respectively. The antioxidant activities of all FPSs were examined. FPS produced by NovoCor ADL lipase in presence of free glycerol showed an antioxidant activity 10.3-times higher. In conclusion, the two low-cost lipases NovoCor ADL and Lipozyme TL 100L and its combi-lipase system could be considered suitable low-cost alternative to the expensive wide use N435 lipase in the solvent free production process of FPS for food and cosmetic applications. Text Antarc* Antarctica DataCite Metadata Store (German National Library of Science and Technology) |
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Biophysics Biochemistry Microbiology FOS Biological sciences Genetics Molecular Biology Physiology Pharmacology Biotechnology 39999 Chemical Sciences not elsewhere classified FOS Chemical sciences Ecology Sociology FOS Sociology 69999 Biological Sciences not elsewhere classified Inorganic Chemistry Science Policy Plant Biology |
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Biophysics Biochemistry Microbiology FOS Biological sciences Genetics Molecular Biology Physiology Pharmacology Biotechnology 39999 Chemical Sciences not elsewhere classified FOS Chemical sciences Ecology Sociology FOS Sociology 69999 Biological Sciences not elsewhere classified Inorganic Chemistry Science Policy Plant Biology Abdelgawad, Ahmed Eid, Mounir Abou-Elmagd, Wael Abou-Elregal, Mohsen Lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media |
topic_facet |
Biophysics Biochemistry Microbiology FOS Biological sciences Genetics Molecular Biology Physiology Pharmacology Biotechnology 39999 Chemical Sciences not elsewhere classified FOS Chemical sciences Ecology Sociology FOS Sociology 69999 Biological Sciences not elsewhere classified Inorganic Chemistry Science Policy Plant Biology |
description |
Recently, several scientific groups investigated the suitable enzymatic route for synthesis of structured phenolic lipids for cosmetic and nutritive purposes. The feruloylated palm stearin (FPS) was obtained from enzymatic transesterification reactions of palm stearin with ferulic acid in solvent-free media with 1 mmol of glycerol or without it, using non-specific lipases, NovoCor ADL ( Candida antarctica lipase A); Novozyme435 ® ( Candida antarctica lipase B), and 1,3-specific lipase Lipozyme TL 100L from Thermomyces lanuginosus . The individual lipases and their combinational systems were examined. ESI + -MS/MS confirmed the formation of 19 feruloylated compounds. FPSs were produced by all lipases and their combinations. The positive synergetic effect occurred for 1,3-specific lipase and unspecified lipases with mass ratio 8:2, respectively. The antioxidant activities of all FPSs were examined. FPS produced by NovoCor ADL lipase in presence of free glycerol showed an antioxidant activity 10.3-times higher. In conclusion, the two low-cost lipases NovoCor ADL and Lipozyme TL 100L and its combi-lipase system could be considered suitable low-cost alternative to the expensive wide use N435 lipase in the solvent free production process of FPS for food and cosmetic applications. |
format |
Text |
author |
Abdelgawad, Ahmed Eid, Mounir Abou-Elmagd, Wael Abou-Elregal, Mohsen |
author_facet |
Abdelgawad, Ahmed Eid, Mounir Abou-Elmagd, Wael Abou-Elregal, Mohsen |
author_sort |
Abdelgawad, Ahmed |
title |
Lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media |
title_short |
Lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media |
title_full |
Lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media |
title_fullStr |
Lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media |
title_full_unstemmed |
Lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media |
title_sort |
lipase catalysed transesterification of palm stearin with ferulic acid in solvent-free media |
publisher |
Taylor & Francis |
publishDate |
2021 |
url |
https://dx.doi.org/10.6084/m9.figshare.14938691 https://tandf.figshare.com/articles/journal_contribution/Lipase_catalysed_transesterification_of_palm_stearin_with_ferulic_acid_in_solvent-free_media/14938691 |
genre |
Antarc* Antarctica |
genre_facet |
Antarc* Antarctica |
op_relation |
https://dx.doi.org/10.1080/10242422.2021.1949001 |
op_rights |
Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/legalcode cc-by-4.0 |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.6084/m9.figshare.14938691 https://doi.org/10.1080/10242422.2021.1949001 |
_version_ |
1766246756124721152 |