Clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ...
<!--!introduction!--> The clumped-isotope composition of oxygen, denoted by Δ 36 , measures the proportional abundance of two heavy oxygen isotopes, 18 O 18 O in oxygen, and is sensitive to photochemical and thermal properties of the atmosphere. Ozone photochemistry controls Δ 36 values via is...
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GFZ German Research Centre for Geosciences
2023
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ftdatacite:10.57757/iugg23-2473 2023-07-23T04:15:52+02:00 Clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ... Banerjee, Asmita Yeung, Laurence Yan, Yuzhen 2023 https://dx.doi.org/10.57757/iugg23-2473 https://gfzpublic.gfz-potsdam.de/pubman/item/item_5018279 unknown GFZ German Research Centre for Geosciences Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/legalcode cc-by-4.0 Article ConferencePaper Oral 2023 ftdatacite https://doi.org/10.57757/iugg23-2473 2023-07-03T17:36:25Z <!--!introduction!--> The clumped-isotope composition of oxygen, denoted by Δ 36 , measures the proportional abundance of two heavy oxygen isotopes, 18 O 18 O in oxygen, and is sensitive to photochemical and thermal properties of the atmosphere. Ozone photochemistry controls Δ 36 values via isotope exchange reactions, yielding a higher abundance of 18 O 18 O than would be expected for a stochastic distribution. Colder temperatures increase this preference for 18 O 18 O formation at equilibrium by 0.013‰/K. If tropospheric ozone and stratosphere-troposphere exchange fluxes remain unchanged, Δ 36 would record changes in free-tropospheric temperatures to provide a high-resolution record of upper tropospheric (UT) temperatures on glacial-interglacial timescales. We present an ice core record of Δ 36 values measured in the West Antarctic Ice Sheet Divide ice core spanning 15–8ka BP. Measured Δ 36 values decrease to Early Holocene (EH; 8-11ka BP)/Pre-industrial (PI; 1850CE) levels at the onset of the Bølling ... : The 28th IUGG General Assembly (IUGG2023) (Berlin 2023) ... Conference Object Antarc* Antarctic ice core Ice Sheet DataCite Metadata Store (German National Library of Science and Technology) Antarctic West Antarctic Ice Sheet |
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DataCite Metadata Store (German National Library of Science and Technology) |
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description |
<!--!introduction!--> The clumped-isotope composition of oxygen, denoted by Δ 36 , measures the proportional abundance of two heavy oxygen isotopes, 18 O 18 O in oxygen, and is sensitive to photochemical and thermal properties of the atmosphere. Ozone photochemistry controls Δ 36 values via isotope exchange reactions, yielding a higher abundance of 18 O 18 O than would be expected for a stochastic distribution. Colder temperatures increase this preference for 18 O 18 O formation at equilibrium by 0.013‰/K. If tropospheric ozone and stratosphere-troposphere exchange fluxes remain unchanged, Δ 36 would record changes in free-tropospheric temperatures to provide a high-resolution record of upper tropospheric (UT) temperatures on glacial-interglacial timescales. We present an ice core record of Δ 36 values measured in the West Antarctic Ice Sheet Divide ice core spanning 15–8ka BP. Measured Δ 36 values decrease to Early Holocene (EH; 8-11ka BP)/Pre-industrial (PI; 1850CE) levels at the onset of the Bølling ... : The 28th IUGG General Assembly (IUGG2023) (Berlin 2023) ... |
format |
Conference Object |
author |
Banerjee, Asmita Yeung, Laurence Yan, Yuzhen |
spellingShingle |
Banerjee, Asmita Yeung, Laurence Yan, Yuzhen Clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ... |
author_facet |
Banerjee, Asmita Yeung, Laurence Yan, Yuzhen |
author_sort |
Banerjee, Asmita |
title |
Clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ... |
title_short |
Clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ... |
title_full |
Clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ... |
title_fullStr |
Clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ... |
title_full_unstemmed |
Clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ... |
title_sort |
clumped isotope constraints on upper tropospheric temperature changes during the last deglaciation ... |
publisher |
GFZ German Research Centre for Geosciences |
publishDate |
2023 |
url |
https://dx.doi.org/10.57757/iugg23-2473 https://gfzpublic.gfz-potsdam.de/pubman/item/item_5018279 |
geographic |
Antarctic West Antarctic Ice Sheet |
geographic_facet |
Antarctic West Antarctic Ice Sheet |
genre |
Antarc* Antarctic ice core Ice Sheet |
genre_facet |
Antarc* Antarctic ice core Ice Sheet |
op_rights |
Creative Commons Attribution 4.0 International https://creativecommons.org/licenses/by/4.0/legalcode cc-by-4.0 |
op_doi |
https://doi.org/10.57757/iugg23-2473 |
_version_ |
1772176965357273088 |