Molar gas ratios and stable oxygen and nitrogen isotopes of air entrapped in ice, North America ...

• Main Authors: Cardyn, Raphaelle, Clark, Ian D, Lacelle, Denis, Lauriol, Bernard, Zdanowicz, Christian, Calmels, Fabrice
• Format: Article in Journal/Newspaper
• Language: English
• Published: PANGAEA 2007
• Subjects: International Polar Year 2007-2008 IPY; Ice; International Polar Year; IPY; permafrost
• Online Access: https://dx.doi.org/10.1594/pangaea.808160; https://doi.pangaea.de/10.1594/PANGAEA.808160

The molar ratios of atmospheric gases change during dissolution in water due to differences in their relative solubilities. We exploited this characteristic to develop a tool to clarify the origin of ice formations in permafrost regions. Extracted from ice, molar gas ratios can distinguish buried glacier ice from intrasedimental ground ice formed by freezing groundwaters. An extraction line was built to isolate gases from ice by melting and trapping with liquid He, followed by analysis of N2, O2, Ar, 18O-O2 and 15N-N2, by continuous flow mass spectrometry. The method was tested using glacier ice, aufeis ice (river icing) and intrasedimental ground ice from sites in the Canadian Arctic. O2/Ar and N2/Ar ratios clearly distinguish between atmospheric gas in glacial ice and gases from intrasedimental ground ice, which are exsolved from freezing water. 615NN2 and 618OO2 in glacier ice, aufeis ice and intrasedimental ground ice do not show clear distinguishing trends as they are affected by various physical ... : Data extracted in the frame of a joint ICSTI/PANGAEA IPY effort, see http://doi.pangaea.de/10.1594/PANGAEA.150150 ...