Dichlorodiphenyltrichloroethane (DDT) and Dichlorodiphenyldichloroethylene (DDE) levels in air and surface sea waters along the Antarctic Peninsula

• Published in: Marine Pollution Bulletin
• Main Authors: Galbán-Malagón, Cristóbal, Gómez-Aburto, Victoria Antonieta, Hirmas-Olivares, Andrea, Luarte, Thais, Berrojalbiz, Naiara, Dachs, Jordi
• Format: Article in Journal/Newspaper
• Language: English
• Published: Elsevier 2023
• Subjects: Secondary sources; Antarctica; DDT; Enantiomeric ratios; Organochlorine pesticides; http://metadata.un.org/sdg/6; http://metadata.un.org/sdg/13; http://metadata.un.org/sdg/14; Ensure availability and sustainable management of water and sanitation for all; Take urgent action to combat climate change and its impacts; Conserve and sustainably use the oceans; seas and marine resources for sustainable development; Antarctic; Antarctic Peninsula; Austral; Inach; The Antarctic; Antarc*
• Online Access: http://hdl.handle.net/10261/338814; https://doi.org/10.1016/j.marpolbul.2023.115699; https://api.elsevier.com/content/abstract/scopus_id/85175482388

Persistent organic pollutants (POPs) are widespread worldwide, even reaching polar regions. Among POPs, dichlorodiphenyltrichloroethane (DDT) and their metabolites have been reported scarcely in the Antarctic environment. Here we report the levels of p,p'-DDT, o,p'-DDT, p,p'-DDE, and o,p'-DDE in air and water samples collected during austral summer 2009. The levels found ranged from 0.25 to 4.26 pg m-3 in the atmospheric samples while in the water samples ranged from 0.07 to 0.25 pg L-1. These concentrations were within the range of the reported concentrations in the last 20 years in Antarctica. However, the source ratio showed that most of p,p'-DDT comes from fresh applications and Dicofol formulations. The back-trajectories estimated for the air masses revealed that most of the p,p'-DDT came from the continental Antarctic peninsula and surrounding waters. The diffusive exchange direction showed that Antarctic surface waters are the final sink of the studied compounds during the survey period. CGM acknowledges funding from the ANID FONDECYT REGULAR 1210946, ANID-PIA-INACH-ACT192057, and INACH REGULAR RT_12_17; VG is supported through an ANID FONDECYT POSTDOC 3230076; TL is supported through the INACH DG_02_21. The authors acknowledge the R/V Hespérides crew. This work was also funded by the ATOS project of the Spanish Ministry of Science and Innovation. Peer reviewed