Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer
22 pags., 10 figs., 2 tabs. Iodine chemistry has noteworthy impacts on the oxidising capacity of the marine boundary layer (MBL) through the depletion of ozone (O3) and changes to HOx (OH=HO2) and NOx (NO=NO2) ratios. Hitherto, studies have shown that the reaction of atmospheric O3 with surface seaw...
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European Geophysical Society
2020
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Online Access: | http://hdl.handle.net/10261/228948 https://doi.org/10.5194/acp-20-12093-2020 https://doi.org/10.13039/501100000270 https://doi.org/10.13039/501100001851 |
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ftcsic:oai:digital.csic.es:10261/228948 2024-02-11T10:08:50+01:00 Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer Inamdar, Swaleha Tinel, L. Chance, R. Carpenter, L.J. Sabu, P. Chacko, R. Tripathy, S.C. Kerkar, A.U. Sinha, A.K. Venkateswaran Bhaskar, P. Sarkar, A. Roy, R. Sherwen, T. Cuevas, Carlos A. Saiz-Lopez, A. Ram, K. Mahajan, Anoop S. Ministry of Earth Sciences (India) Natural Environment Research Council (UK) 2020-10-26 http://hdl.handle.net/10261/228948 https://doi.org/10.5194/acp-20-12093-2020 https://doi.org/10.13039/501100000270 https://doi.org/10.13039/501100001851 unknown European Geophysical Society Publisher's version http://dx.doi.org/10.5194/acp-20-12093-2020 Sí doi:10.5194/acp-20-12093-2020 issn: 1680-7324 Atmospheric Chemistry and Physics 20: 12093-12114 (2020) http://hdl.handle.net/10261/228948 http://dx.doi.org/10.13039/501100000270 http://dx.doi.org/10.13039/501100001851 open artículo http://purl.org/coar/resource_type/c_6501 2020 ftcsic https://doi.org/10.5194/acp-20-12093-202010.13039/50110000027010.13039/501100001851 2024-01-16T11:02:28Z 22 pags., 10 figs., 2 tabs. Iodine chemistry has noteworthy impacts on the oxidising capacity of the marine boundary layer (MBL) through the depletion of ozone (O3) and changes to HOx (OH=HO2) and NOx (NO=NO2) ratios. Hitherto, studies have shown that the reaction of atmospheric O3 with surface seawater iodide (I-) contributes to the flux of iodine species into the MBL mainly as hypoiodous acid (HOI) and molecular iodine (I2). Here, we present the first concomitant observations of iodine oxide (IO), O3 in the gas phase, and sea surface iodide concentrations. The results from three field campaigns in the Indian Ocean and the Southern Ocean during 2015 2017 are used to compute reactive iodine fluxes in the MBL. Observations of atmospheric IO by multi-axis differential optical absorption spectroscopy (MAX-DOAS) show active iodine chemistry in this environment, with IO values up to 1 pptv (parts per trillion by volume) below latitudes of 40° S. In order to compute the sea-to-air iodine flux supporting this chemistry, we compare previously established global sea surface iodide parameterisations with new regionspecific parameterisations based on the new iodide observations. This study shows that regional changes in salinity and sea surface temperature play a role in surface seawater iodide estimation. Sea air fluxes of HOI and I2, calculated from the atmospheric ozone and seawater iodide concentrations (observed and predicted), failed to adequately explain the detected IO in this region. This discrepancy highlights the need to measure direct fluxes of inorganic and organic iodine species in the marine environment. Amongst other potential drivers of reactive iodine chemistry investigated, chlorophyll a showed a significant correlation with atmospheric IO (R D 0:7 above the 99 % significance level) to the north of the polar front. This correlation might be indicative of a biogenic control on iodine sources in this region. The authors thank the Ministry of Earth Sciences for funding the expeditions and IITM for ... Article in Journal/Newspaper Southern Ocean Digital.CSIC (Spanish National Research Council) Indian Southern Ocean Atmospheric Chemistry and Physics 20 20 12093 12114 |
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Digital.CSIC (Spanish National Research Council) |
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22 pags., 10 figs., 2 tabs. Iodine chemistry has noteworthy impacts on the oxidising capacity of the marine boundary layer (MBL) through the depletion of ozone (O3) and changes to HOx (OH=HO2) and NOx (NO=NO2) ratios. Hitherto, studies have shown that the reaction of atmospheric O3 with surface seawater iodide (I-) contributes to the flux of iodine species into the MBL mainly as hypoiodous acid (HOI) and molecular iodine (I2). Here, we present the first concomitant observations of iodine oxide (IO), O3 in the gas phase, and sea surface iodide concentrations. The results from three field campaigns in the Indian Ocean and the Southern Ocean during 2015 2017 are used to compute reactive iodine fluxes in the MBL. Observations of atmospheric IO by multi-axis differential optical absorption spectroscopy (MAX-DOAS) show active iodine chemistry in this environment, with IO values up to 1 pptv (parts per trillion by volume) below latitudes of 40° S. In order to compute the sea-to-air iodine flux supporting this chemistry, we compare previously established global sea surface iodide parameterisations with new regionspecific parameterisations based on the new iodide observations. This study shows that regional changes in salinity and sea surface temperature play a role in surface seawater iodide estimation. Sea air fluxes of HOI and I2, calculated from the atmospheric ozone and seawater iodide concentrations (observed and predicted), failed to adequately explain the detected IO in this region. This discrepancy highlights the need to measure direct fluxes of inorganic and organic iodine species in the marine environment. Amongst other potential drivers of reactive iodine chemistry investigated, chlorophyll a showed a significant correlation with atmospheric IO (R D 0:7 above the 99 % significance level) to the north of the polar front. This correlation might be indicative of a biogenic control on iodine sources in this region. The authors thank the Ministry of Earth Sciences for funding the expeditions and IITM for ... |
author2 |
Ministry of Earth Sciences (India) Natural Environment Research Council (UK) |
format |
Article in Journal/Newspaper |
author |
Inamdar, Swaleha Tinel, L. Chance, R. Carpenter, L.J. Sabu, P. Chacko, R. Tripathy, S.C. Kerkar, A.U. Sinha, A.K. Venkateswaran Bhaskar, P. Sarkar, A. Roy, R. Sherwen, T. Cuevas, Carlos A. Saiz-Lopez, A. Ram, K. Mahajan, Anoop S. |
spellingShingle |
Inamdar, Swaleha Tinel, L. Chance, R. Carpenter, L.J. Sabu, P. Chacko, R. Tripathy, S.C. Kerkar, A.U. Sinha, A.K. Venkateswaran Bhaskar, P. Sarkar, A. Roy, R. Sherwen, T. Cuevas, Carlos A. Saiz-Lopez, A. Ram, K. Mahajan, Anoop S. Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer |
author_facet |
Inamdar, Swaleha Tinel, L. Chance, R. Carpenter, L.J. Sabu, P. Chacko, R. Tripathy, S.C. Kerkar, A.U. Sinha, A.K. Venkateswaran Bhaskar, P. Sarkar, A. Roy, R. Sherwen, T. Cuevas, Carlos A. Saiz-Lopez, A. Ram, K. Mahajan, Anoop S. |
author_sort |
Inamdar, Swaleha |
title |
Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer |
title_short |
Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer |
title_full |
Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer |
title_fullStr |
Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer |
title_full_unstemmed |
Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer |
title_sort |
estimation of reactive inorganic iodine fluxes in the indian and southern ocean marine boundary layer |
publisher |
European Geophysical Society |
publishDate |
2020 |
url |
http://hdl.handle.net/10261/228948 https://doi.org/10.5194/acp-20-12093-2020 https://doi.org/10.13039/501100000270 https://doi.org/10.13039/501100001851 |
geographic |
Indian Southern Ocean |
geographic_facet |
Indian Southern Ocean |
genre |
Southern Ocean |
genre_facet |
Southern Ocean |
op_relation |
Publisher's version http://dx.doi.org/10.5194/acp-20-12093-2020 Sí doi:10.5194/acp-20-12093-2020 issn: 1680-7324 Atmospheric Chemistry and Physics 20: 12093-12114 (2020) http://hdl.handle.net/10261/228948 http://dx.doi.org/10.13039/501100000270 http://dx.doi.org/10.13039/501100001851 |
op_rights |
open |
op_doi |
https://doi.org/10.5194/acp-20-12093-202010.13039/50110000027010.13039/501100001851 |
container_title |
Atmospheric Chemistry and Physics |
container_volume |
20 |
container_issue |
20 |
container_start_page |
12093 |
op_container_end_page |
12114 |
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1790608450933227520 |