Carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (DFAs)-enriched caramels from d -Fructose
Activation of a concentrated solution of d-fructose with carbonic acid, generated from carbon dioxide, induces the formation of difructose dianhydrides (DFAs) and their glycosylated derivatives (glycosyl-DFAs), a family of prebiotic oligosaccharides. Under optimized conditions, up to 70% of the acti...
Published in: | Journal of Agricultural and Food Chemistry |
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American Chemical Society
2017
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Online Access: | http://hdl.handle.net/10261/190473 https://doi.org/10.1021/acs.jafc.7b01601 |
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ftcsic:oai:digital.csic.es:10261/190473 2024-02-11T10:02:52+01:00 Carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (DFAs)-enriched caramels from d -Fructose Audemar, Maite Atencio-Genes, Loyda Ortiz-Mellet, Carmen Jérôme, François García Fernández, José Manuel Oliveira Vigier, K. de 2017-08-02 http://hdl.handle.net/10261/190473 https://doi.org/10.1021/acs.jafc.7b01601 unknown American Chemical Society https://doi.org/10.1021/acs.jafc.7b01601 Sí Journal of agricultural and food chemistry 65(30): 6093-6099 (2017) 0021-8561 http://hdl.handle.net/10261/190473 doi:10.1021/acs.jafc.7b01601 1520-5118 none Prebiotic Difructose dianhydrides Caramelization Carbon dioxide D-fructose artículo http://purl.org/coar/resource_type/c_6501 2017 ftcsic https://doi.org/10.1021/acs.jafc.7b01601 2024-01-16T10:43:33Z Activation of a concentrated solution of d-fructose with carbonic acid, generated from carbon dioxide, induces the formation of difructose dianhydrides (DFAs) and their glycosylated derivatives (glycosyl-DFAs), a family of prebiotic oligosaccharides. Under optimized conditions, up to 70% of the active DFA species were obtained from a highly concentrated solution of fructose, avoiding the filtration step and contamination risk associated with the current procedures that employ heterogeneous catalysis with acid ion-exchange resins. The optimized CO-promoted preparation of DFA-enriched caramel described here has been already successfully scaled up to 150 kg of d-fructose for nutritional studies, showing that implementation of this process is possible at a larger scale. Article in Journal/Newspaper Carbonic acid Digital.CSIC (Spanish National Research Council) Journal of Agricultural and Food Chemistry 65 30 6093 6099 |
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Open Polar |
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Digital.CSIC (Spanish National Research Council) |
op_collection_id |
ftcsic |
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unknown |
topic |
Prebiotic Difructose dianhydrides Caramelization Carbon dioxide D-fructose |
spellingShingle |
Prebiotic Difructose dianhydrides Caramelization Carbon dioxide D-fructose Audemar, Maite Atencio-Genes, Loyda Ortiz-Mellet, Carmen Jérôme, François García Fernández, José Manuel Oliveira Vigier, K. de Carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (DFAs)-enriched caramels from d -Fructose |
topic_facet |
Prebiotic Difructose dianhydrides Caramelization Carbon dioxide D-fructose |
description |
Activation of a concentrated solution of d-fructose with carbonic acid, generated from carbon dioxide, induces the formation of difructose dianhydrides (DFAs) and their glycosylated derivatives (glycosyl-DFAs), a family of prebiotic oligosaccharides. Under optimized conditions, up to 70% of the active DFA species were obtained from a highly concentrated solution of fructose, avoiding the filtration step and contamination risk associated with the current procedures that employ heterogeneous catalysis with acid ion-exchange resins. The optimized CO-promoted preparation of DFA-enriched caramel described here has been already successfully scaled up to 150 kg of d-fructose for nutritional studies, showing that implementation of this process is possible at a larger scale. |
format |
Article in Journal/Newspaper |
author |
Audemar, Maite Atencio-Genes, Loyda Ortiz-Mellet, Carmen Jérôme, François García Fernández, José Manuel Oliveira Vigier, K. de |
author_facet |
Audemar, Maite Atencio-Genes, Loyda Ortiz-Mellet, Carmen Jérôme, François García Fernández, José Manuel Oliveira Vigier, K. de |
author_sort |
Audemar, Maite |
title |
Carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (DFAs)-enriched caramels from d -Fructose |
title_short |
Carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (DFAs)-enriched caramels from d -Fructose |
title_full |
Carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (DFAs)-enriched caramels from d -Fructose |
title_fullStr |
Carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (DFAs)-enriched caramels from d -Fructose |
title_full_unstemmed |
Carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (DFAs)-enriched caramels from d -Fructose |
title_sort |
carbon dioxide as a traceless caramelization promotor: preparation of prebiotic difructose dianhydrides (dfas)-enriched caramels from d -fructose |
publisher |
American Chemical Society |
publishDate |
2017 |
url |
http://hdl.handle.net/10261/190473 https://doi.org/10.1021/acs.jafc.7b01601 |
genre |
Carbonic acid |
genre_facet |
Carbonic acid |
op_relation |
https://doi.org/10.1021/acs.jafc.7b01601 Sí Journal of agricultural and food chemistry 65(30): 6093-6099 (2017) 0021-8561 http://hdl.handle.net/10261/190473 doi:10.1021/acs.jafc.7b01601 1520-5118 |
op_rights |
none |
op_doi |
https://doi.org/10.1021/acs.jafc.7b01601 |
container_title |
Journal of Agricultural and Food Chemistry |
container_volume |
65 |
container_issue |
30 |
container_start_page |
6093 |
op_container_end_page |
6099 |
_version_ |
1790598947489710080 |