Nonlinear increase in seawater 87Sr/86Sr in the Oligocene to early Miocene and implications for climate-sensitive weathering

• Main Authors: Stoll, Heather M., Pena, Leopoldo D., Hernandez-Almeida, Ivan, Guitián, José, Tanner, Thomas, Paelike, Heiko
• Format: Text
• Language: English
• Published: 2023
• Subjects: Antarctic; Pacific; Antarc*
• Online Access: https://doi.org/10.5194/cp-2023-29; https://cp.copernicus.org/preprints/cp-2023-29/

The 87 Sr/ 86 Sr of marine carbonates provides a key constraint on the balance of continental weathering and hydrothermal Sr fluxes to the ocean, and mid-Oligocene to mid-Miocene features the most rapid rates of increase in the 87 Sr/ 86 Sr of the Cenozoic. Because previous records of the 87 Sr/ 86 Sr increase with time were based on biostratigraphically defined age models in diverse locations, it was difficult to unambigiously distinguish m.y. scale variations in the rate of 87 Sr/ 86 Sr change from variations in sedimentation rate. In this study, we produce the first 87 Sr/ 86 Sr results from an Oligocene to early Miocene site with a precise age model derived orbital tuning of high resolution benthic δ 18 O, at the Equatorial Pacific Ocean Drilling Program (ODP) Site 1218. Our new dataset resolves transient decreases in 87 Sr/ 86 Sr, as well as periods of relative stasis. These changes can be directly compared with the high resolution benthic δ 18 O in the same site. We find slowing of the rate of 87 Sr/ 86 Sr increase coincides with the onset of Antarctic ice expansion at the beginning of the Mid-Oligocene Glacial Interval, and a rapid steeping in the 87 Sr/ 86 Sr increase coincides with the benthic δ 18 O evidence for rapid ice retreat. This pattern may reflect either northward shifts in the Intertropical Convergence Zone precipitation to areas of nonradiogenic bedrock, and/or lowered weathering fluxes from highly radiogenic glacial flours on Antarctic. We additionally generate the first 87 Sr/ 86 Sr data from ODP Site 1168 and International Ocean Discovery Program (IODP) Site 1406 during the Oligocene to early Miocene to improve the precision of age correlation of these Northern Hemisphere and Southern Hemisphere mid-latitude sites, and to better estimate the duration of early Miocene hiatus and condensed sedimentation.