Southern Hemisphere atmospheric history of carbon monoxide over the late Holocene reconstructed from multiple Antarctic ice archives

• Main Authors: Faïn, Xavier, Etheridge, David M., Fourteau, Kévin, Martinerie, Patricia, Trudinger, Cathy M., Rhodes, Rachael H., Chellman, Nathan J., Langenfelds, Ray L., McConnell, Joseph R., Curran, Mark A. J., Brook, Edward J., Blunier, Thomas, Teste, Grégory, Grilli, Roberto, Lemoine, Anthony, Sturges, William T., Vannière, Boris, Freitag, Johannes, Chappellaz, Jérôme
• Format: Text
• Language: English
• Published: 2023
• Subjects: Antarctic; East Antarctica; Mawson Station; South Pole; Antarc*; Antarctica; ice core; South pole
• Online Access: https://doi.org/10.5194/cp-2023-9; https://cp.copernicus.org/preprints/cp-2023-9/

Carbon monoxide (CO) is a naturally occurring atmospheric trace gas, a regulated pollutant and one of the main components determining the oxidative capacity of the atmosphere. Evaluating climate-chemical models under different conditions than today and constraining past CO sources requires a reliable record of atmospheric CO mixing ratios ([CO]) since pre-industrial times. Here, we report the first continuous record of atmospheric [CO] for Southern Hemisphere (SH) high latitudes over the past three millennia. Our continuous record is a composite of three high-resolution Antarctic ice core gas records and firn air measurements from seven Antarctic locations. The ice core gas [CO] records were measured by continuous flow analysis (CFA) using an optical-feedback cavity-enhanced absorption spectrometer (OF-CEAS), achieving excellent external precision (2.8–8.8 ppbv, 2σ), and consistently low blanks (ranging from 4.1 ± 1.2 to 7.4 ± 1.4 ppbv), enabling paleo-atmospheric interpretations. Six new firn air [CO] Antarctic datasets collected between 1993 and 2016 CE at the DE08-2, DSSW19K, DSSW20K, South Pole, ABN, and Lock-In sites (and one previously published firn CO dataset at Berkner) were used to reconstruct the atmospheric history of CO from ~1897 CE using inverse modeling that incorporates the influence of gas transport in firn. Excellent consistency was observed between the youngest ice core gas [CO] and the [CO] from the base of the firn, and between the recent firn [CO] and atmospheric [CO] measurements at Mawson station (East Antarctica), yielding a consistent and contiguous record of CO across these different archives. Our Antarctic [CO] record is relatively stable from −835 to 1500 CE with mixing ratios within a 30–45 ppbv range (2σ). There is a ~5 ppbv decrease in [CO] to a minimum at around 1700 CE, during the Little Ice Age. CO mixing ratios then increase over time to reach a maximum of ~54 ppbv by ~1985 CE. Most of the industrial period [CO] growth occurred between about 1940 to 1985 CE, after which there ...