Southern Hemisphere atmospheric history of carbon monoxide over the late Holocene reconstructed from multiple Antarctic ice archives
Carbon monoxide (CO) is a naturally occurring atmospheric trace gas, a regulated pollutant and one of the main components determining the oxidative capacity of the atmosphere. Evaluating climate-chemical models under different conditions than today and constraining past CO sources requires a reliabl...
Main Authors: | , , , , , , , , , , , , , , , , , , |
---|---|
Format: | Text |
Language: | English |
Published: |
2023
|
Subjects: | |
Online Access: | https://doi.org/10.5194/cp-2023-9 https://cp.copernicus.org/preprints/cp-2023-9/ |
Summary: | Carbon monoxide (CO) is a naturally occurring atmospheric trace gas, a regulated pollutant and one of the main components determining the oxidative capacity of the atmosphere. Evaluating climate-chemical models under different conditions than today and constraining past CO sources requires a reliable record of atmospheric CO mixing ratios ([CO]) since pre-industrial times. Here, we report the first continuous record of atmospheric [CO] for Southern Hemisphere (SH) high latitudes over the past three millennia. Our continuous record is a composite of three high-resolution Antarctic ice core gas records and firn air measurements from seven Antarctic locations. The ice core gas [CO] records were measured by continuous flow analysis (CFA) using an optical-feedback cavity-enhanced absorption spectrometer (OF-CEAS), achieving excellent external precision (2.8–8.8 ppbv, 2σ), and consistently low blanks (ranging from 4.1 ± 1.2 to 7.4 ± 1.4 ppbv), enabling paleo-atmospheric interpretations. Six new firn air [CO] Antarctic datasets collected between 1993 and 2016 CE at the DE08-2, DSSW19K, DSSW20K, South Pole, ABN, and Lock-In sites (and one previously published firn CO dataset at Berkner) were used to reconstruct the atmospheric history of CO from ~1897 CE using inverse modeling that incorporates the influence of gas transport in firn. Excellent consistency was observed between the youngest ice core gas [CO] and the [CO] from the base of the firn, and between the recent firn [CO] and atmospheric [CO] measurements at Mawson station (East Antarctica), yielding a consistent and contiguous record of CO across these different archives. Our Antarctic [CO] record is relatively stable from −835 to 1500 CE with mixing ratios within a 30–45 ppbv range (2σ). There is a ~5 ppbv decrease in [CO] to a minimum at around 1700 CE, during the Little Ice Age. CO mixing ratios then increase over time to reach a maximum of ~54 ppbv by ~1985 CE. Most of the industrial period [CO] growth occurred between about 1940 to 1985 CE, after which there ... |
---|