Modeling the marine chromium cycle: New constraints on global-scale processes

• Main Authors: Pöppelmeier, Frerk, Janssen, David J., Jaccard, Samuel L., Stocker, Thomas F.
• Format: Text
• Language: English
• Published: 2021
• Subjects: Arctic
• Online Access: https://doi.org/10.5194/bg-2021-106; https://bg.copernicus.org/preprints/bg-2021-106/

Chromium (Cr) and its isotopes hold great promise as tracer of past oxygenation and marine biological activity due to the different chemical properties of its two main oxidation states, Cr(III) and Cr(VI), and the associated fractionation during redox transformations. However, to date the Cr cycle remains poorly constrained due to insufficient knowledge about sources and sinks and the influence of biological activity on redox reactions. We therefore implemented the two oxidation states of Cr in the Bern3D Earth system model of intermediate complexity, in order to gain an improved understanding on the mechanisms that modulate the spatial distribution of Cr in the ocean. Due to the computational efficiency of the Bern3D model we are able to explore and constrain the range of a wide array of parameters. Our model simulates vertical, meridional, and inter-basin Cr concentration gradients in good agreement with observations. We find a mean ocean residence time of Cr between 5 and 8 kyr, and a benthic flux, emanating from all sediment surfaces, of of 0.1–0.2 nmol cm -2 yr -1 , both in the range of previous estimates. We further explore the origin of regional model-data mismatches through a number of sensitivity experiments. These indicate that the benthic Cr flux may be substantially lower in the Arctic than elsewhere. In addition, we find that a refined representation of oxygen minimum zones and their Cr redox potential yields Cr(III) concentrations and Cr removal rates in much improved agreement with observational data.