Enhancement of the North Atlantic CO2 sink by Arctic Waters

• Published in: Biogeosciences
• Main Authors: Olafsson, Jon, Olafsdottir, Solveig R., Takahashi, Taro, Danielsen, Magnus, Arnarson, Thorarinn S.
• Format: Text
• Language: English
• Published: 2021
• Subjects: Arctic; Iceland; North Atlantic; Northwest Atlantic
• Online Access: https://doi.org/10.5194/bg-18-1689-2021; https://bg.copernicus.org/articles/18/1689/2021/

The North Atlantic north of 50 ∘ N is one of the most intense ocean sink areas for atmospheric CO 2 considering the flux per unit area, 0.27 Pg-C yr −1 , equivalent to −2.5 mol C m −2 yr −1 . The northwest Atlantic Ocean is a region with high anthropogenic carbon inventories. This is on account of processes which sustain CO 2 air–sea fluxes, in particular strong seasonal winds, ocean heat loss, deep convective mixing, and CO 2 drawdown by primary production. The region is in the northern limb of the global thermohaline circulation, a path for the long-term deep-sea sequestration of carbon dioxide. The surface water masses in the North Atlantic are of contrasting origins and character, with the northward-flowing North Atlantic Drift, a Gulf Stream offspring, on the one hand and on the other hand the cold southward-moving low-salinity Polar and Arctic waters with signatures from Arctic freshwater sources. We have studied by observation the CO 2 air–sea flux of the relevant water masses in the vicinity of Iceland in all seasons and in different years. Here we show that the highest ocean CO 2 influx is to the Arctic and Polar waters, respectively, <math xmlns="http://www.w3.org/1998/Math/MathML" id="M13" display="inline" overflow="scroll" dspmath="mathml"><mrow><mo>-</mo><mn mathvariant="normal">3.8</mn><mo>±</mo><mn mathvariant="normal">0.4</mn></mrow></math> <svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="52pt" height="10pt" class="svg-formula" dspmath="mathimg" md5hash="bbacc4c36339bdcb3a2b068c678194a7"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="bg-18-1689-2021-ie00001.svg" width="52pt" height="10pt" src="bg-18-1689-2021-ie00001.png"/></svg:svg> and <math xmlns="http://www.w3.org/1998/Math/MathML" id="M14" display="inline" overflow="scroll" dspmath="mathml"><mrow><mo>-</mo><mn mathvariant="normal">4.4</mn><mo>±</mo><mn mathvariant="normal">0.3</mn></mrow></math> <svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="52pt" height="10pt" class="svg-formula" dspmath="mathimg" md5hash="7544a7297c48abf84be644a91d59315b"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="bg-18-1689-2021-ie00002.svg" width="52pt" height="10pt" src="bg-18-1689-2021-ie00002.png"/></svg:svg> mol C m −2 yr −1 . These waters are CO 2 undersaturated in all seasons. The Atlantic Water is a weak or neutral sink, near CO 2 saturation, after poleward drift from subtropical latitudes. These characteristics of the three water masses are confirmed by data from observations covering 30 years. We relate the Polar Water and Arctic Water persistent undersaturation and CO 2 influx to the excess alkalinity derived from Arctic sources. Carbonate chemistry equilibrium calculations clearly indicate that the excess alkalinity may support at least 0.058 Pg-C yr −1 , a significant portion of the North Atlantic CO 2 sink. The Arctic contribution to the North Atlantic CO 2 sink which we reveal was previously unrecognized. However, we point out that there are gaps and conflicts in the knowledge about the Arctic alkalinity and carbonate budgets and that future trends in the North Atlantic CO 2 sink are connected to developments in the rapidly warming and changing Arctic. The results we present need to be taken into consideration for the following question: will the North Atlantic continue to absorb CO 2 in the future as it has in the past?