A modular field system enabling cavity ring-down spectroscopy of in-situ vapor observations in harsh environments: The ISE-CUBE system

Over the last two decades, cavity ring-down spectroscopy (CRDS) has allowed for increasingly widespread, in-situ observations of trace gases in vapor, including the stable isotopic composition of water vapor. However, in-situ observation in harsh environments pose a particular challenge, as these CR...

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Bibliographic Details
Main Authors: Seidl, Andrew Walter, Sodemann, Harald, Steen-Larsen, Hans Christian
Format: Text
Language:English
Published: 2022
Subjects:
Online Access:https://doi.org/10.5194/amt-2022-208
https://amt.copernicus.org/preprints/amt-2022-208/
Description
Summary:Over the last two decades, cavity ring-down spectroscopy (CRDS) has allowed for increasingly widespread, in-situ observations of trace gases in vapor, including the stable isotopic composition of water vapor. However, in-situ observation in harsh environments pose a particular challenge, as these CRDS analyzers are designed for use in a conventional laboratory. As such, field deployments typically enclose the instrument in a "quasi-laboratory". These deployments often involve substantial logistical effort, in addition to potentially affecting the measurement site, such as impacting flow conditions around near-surface processes. We designed the ISE-CUBE system as a modular CRDS deployment system for stable water isotope measurements, with a specific focus on observing near-surface processes. We tested the system during a two-week field campaign during Feb–March 2020 in Ny-Ålesund, Svalbard, Norway, with ambient temperatures down to −30 °C, and winds gusting over 20 m s −1 . The system functioned suitably throughout the campaign, with field periods exhibiting only a minimal decrease in isotopic measurement precision ( δ 18 O: 0.06 ‰ & δ D: 0.47 ‰) as compared to optimal laboratory operation. Having proven itself in challenging arctic conditions, the ISE-CUBE system can be readily adapted to the particular needs of future stable water isotope researchers, wherever their research aims might take them.