Microscale measurements of oxygen diffusion and consumption in subaqueous sulfide tailings

• Published in: Geochimica et Cosmochimica Acta
• Main Authors: Elberling, Bo, Damgaard, Lars Riis
• Format: Article in Journal/Newspaper
• Language: English
• Published: 2001
• Subjects: Canada; Nanisivik
• Online Access: https://curis.ku.dk/portal/da/publications/microscale-measurements-of-oxygen-diffusion-and-consumption-in-subaqueous-sulfide-tailings(bc29a7d9-561a-4a9d-bd97-0d79f4d2231a).html; https://doi.org/10.1016/S0016-7037(01)00574-9; http://www.scopus.com/inward/record.url?scp=0034962422&partnerID=8YFLogxK

The disposal of sulfide mine tailings in an environmentally sound, yet cost-effective, manner is an issue facing most metal mines. Subaqueous tailing disposal is considered an attractive option for disposal that limits oxygen (O 2 ) availability within sulfide mine tailings and controlling sulfide oxidation and the resultant acid mine drainage (AMD). Assuming that O 2 profiles represent steady-state conditions, we aim to evaluate the depth-dependent and temperature-dependent rates of O 2 consumption in saturated mine tailings. Measurements include microscale O 2 gradients and diffusivity profiles within columns representing undisturbed mine tailing profiles from an impoundment near Nanisivik Mine in northern Canada. Measurements were made across the diffusive bondary layer (DBL) above the tailing-water interface as well as in the tailings below. Laboratory measurements of O 2 profiles are compared to in situ profiles. From the laboratory results it is possible to evaluate the O 2 flux across the DBL and the depth-integrated O 2 uptake. The results are compared with the average sulfate production rate over 3 months. O 2 uptake in saturated tailings is discussed in relation to O 2 uptake measured in columns after free drainage. The methods applied provide consistent O 2 consumption rates as well as reliable predictions for controlling AMD by keeping taillings under water.