Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films

Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spect...

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Published in:Polymer International
Main Authors: Monsalve, Leandro Nicolas, Petroselli, Gabriela, Erra Balsells, Rosa, Vazquez, Analia, Baldessari, Alicia
Format: Article in Journal/Newspaper
Language:English
Published: Elsevier
Subjects:
Lipase
Β-Peptoid
Polycaprolactone
Films
Surface Properties
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Argentina
Alicia
Vazquez
Antarc*
Antarctica
Online Access:http://hdl.handle.net/11336/7419
id ftconicet:oai:ri.conicet.gov.ar:11336/7419
record_format openpolar
spelling ftconicet:oai:ri.conicet.gov.ar:11336/7419 2023-10-09T21:46:57+02:00 Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films Monsalve, Leandro Nicolas Petroselli, Gabriela Erra Balsells, Rosa Vazquez, Analia Baldessari, Alicia application/pdf application/vnd.openxmlformats-officedocument.wordprocessingml.document http://hdl.handle.net/11336/7419 eng eng Elsevier info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pi.4660/abstract info:eu-repo/semantics/altIdentifier/doi/10.1002/pi.4660 http://hdl.handle.net/11336/7419 Monsalve, Leandro Nicolas; Petroselli, Gabriela; Erra Balsells, Rosa; Vazquez, Analia; Baldessari, Alicia; Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films; Elsevier; Polymer International; 63; 8; 8-2014; 1523-1530 1097-0126 info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ Lipase Β-Peptoid Polycaprolactone Films Surface Properties https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion ftconicet https://doi.org/10.1002/pi.4660 2023-09-24T18:31:36Z Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spectroscopic methods showing low molecular weight and low dispersity. Two derivatives of this beta-peptoid oligomer ae prepared by acetylation and by grafting polycaprolactone by ring opening polymerization from the pendant hydroxyl groups. These products are blended with polycaprolactone to make films by solvent casting. The inclusion of the acyl derivatives of the beta-peptoid to polycaprolactone affects the morphology of the film yielding micro- and nanostructured patterns. Fil: Monsalve, Leandro Nicolas. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina. Instituto Nacional de Tecnologia Industrial; Argentina Fil: Petroselli, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina Fil: Erra Balsells, Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina Fil: Vazquez, Analia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos Aplicados A la Química Orgánica (i); Argentina Article in Journal/Newspaper Antarc* Antarctica CONICET Digital (Consejo Nacional de Investigaciones Científicas y Técnicas) Argentina Alicia ENVELOPE(-63.483,-63.483,-64.833,-64.833) Vazquez ENVELOPE(-64.000,-64.000,-65.433,-65.433) Polymer International 63 8 1523 1530
institution Open Polar
collection CONICET Digital (Consejo Nacional de Investigaciones Científicas y Técnicas)
op_collection_id ftconicet
language English
topic Lipase
Β-Peptoid
Polycaprolactone
Films
Surface Properties
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
spellingShingle Lipase
Β-Peptoid
Polycaprolactone
Films
Surface Properties
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
Monsalve, Leandro Nicolas
Petroselli, Gabriela
Erra Balsells, Rosa
Vazquez, Analia
Baldessari, Alicia
Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
topic_facet Lipase
Β-Peptoid
Polycaprolactone
Films
Surface Properties
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
description Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spectroscopic methods showing low molecular weight and low dispersity. Two derivatives of this beta-peptoid oligomer ae prepared by acetylation and by grafting polycaprolactone by ring opening polymerization from the pendant hydroxyl groups. These products are blended with polycaprolactone to make films by solvent casting. The inclusion of the acyl derivatives of the beta-peptoid to polycaprolactone affects the morphology of the film yielding micro- and nanostructured patterns. Fil: Monsalve, Leandro Nicolas. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina. Instituto Nacional de Tecnologia Industrial; Argentina Fil: Petroselli, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina Fil: Erra Balsells, Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina Fil: Vazquez, Analia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos Aplicados A la Química Orgánica (i); Argentina
format Article in Journal/Newspaper
author Monsalve, Leandro Nicolas
Petroselli, Gabriela
Erra Balsells, Rosa
Vazquez, Analia
Baldessari, Alicia
author_facet Monsalve, Leandro Nicolas
Petroselli, Gabriela
Erra Balsells, Rosa
Vazquez, Analia
Baldessari, Alicia
author_sort Monsalve, Leandro Nicolas
title Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_short Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_full Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_fullStr Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_full_unstemmed Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
title_sort chemoenzymatic synthesis of a novel n-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
publisher Elsevier
url http://hdl.handle.net/11336/7419
long_lat ENVELOPE(-63.483,-63.483,-64.833,-64.833)
ENVELOPE(-64.000,-64.000,-65.433,-65.433)
geographic Argentina
Alicia
Vazquez
geographic_facet Argentina
Alicia
Vazquez
genre Antarc*
Antarctica
genre_facet Antarc*
Antarctica
op_relation info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pi.4660/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/pi.4660
http://hdl.handle.net/11336/7419
Monsalve, Leandro Nicolas; Petroselli, Gabriela; Erra Balsells, Rosa; Vazquez, Analia; Baldessari, Alicia; Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films; Elsevier; Polymer International; 63; 8; 8-2014; 1523-1530
1097-0126
op_rights info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
op_doi https://doi.org/10.1002/pi.4660
container_title Polymer International
container_volume 63
container_issue 8
container_start_page 1523
op_container_end_page 1530
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