Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films
Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spect...
| Published in: | Polymer International |
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| Main Authors: | , , , , |
| Format: | Article in Journal/Newspaper |
| Language: | English |
| Published: |
Elsevier
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| Subjects: | |
| Online Access: | http://hdl.handle.net/11336/7419 |
| _version_ | 1821772717727154176 |
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| author | Monsalve, Leandro Nicolas Petroselli, Gabriela Erra Balsells, Rosa Vazquez, Analia Baldessari, Alicia |
| author_facet | Monsalve, Leandro Nicolas Petroselli, Gabriela Erra Balsells, Rosa Vazquez, Analia Baldessari, Alicia |
| author_sort | Monsalve, Leandro Nicolas |
| collection | CONICET Digital (Consejo Nacional de Investigaciones Científicas y Técnicas) |
| container_issue | 8 |
| container_start_page | 1523 |
| container_title | Polymer International |
| container_volume | 63 |
| description | Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spectroscopic methods showing low molecular weight and low dispersity. Two derivatives of this beta-peptoid oligomer ae prepared by acetylation and by grafting polycaprolactone by ring opening polymerization from the pendant hydroxyl groups. These products are blended with polycaprolactone to make films by solvent casting. The inclusion of the acyl derivatives of the beta-peptoid to polycaprolactone affects the morphology of the film yielding micro- and nanostructured patterns. Fil: Monsalve, Leandro Nicolas. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina. Instituto Nacional de Tecnologia Industrial; Argentina Fil: Petroselli, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina Fil: Erra Balsells, Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina Fil: Vazquez, Analia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos Aplicados A la Química Orgánica (i); Argentina |
| format | Article in Journal/Newspaper |
| genre | Antarc* Antarctica |
| genre_facet | Antarc* Antarctica |
| geographic | Alicia Argentina Vazquez |
| geographic_facet | Alicia Argentina Vazquez |
| id | ftconicet:oai:ri.conicet.gov.ar:11336/7419 |
| institution | Open Polar |
| language | English |
| long_lat | ENVELOPE(-63.483,-63.483,-64.833,-64.833) ENVELOPE(-64.000,-64.000,-65.433,-65.433) |
| op_collection_id | ftconicet |
| op_container_end_page | 1530 |
| op_doi | https://doi.org/10.1002/pi.4660 |
| op_relation | info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pi.4660/abstract info:eu-repo/semantics/altIdentifier/doi/10.1002/pi.4660 http://hdl.handle.net/11336/7419 Monsalve, Leandro Nicolas; Petroselli, Gabriela; Erra Balsells, Rosa; Vazquez, Analia; Baldessari, Alicia; Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films; Elsevier; Polymer International; 63; 8; 8-2014; 1523-1530 1097-0126 |
| op_rights | info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
| publisher | Elsevier |
| record_format | openpolar |
| spelling | ftconicet:oai:ri.conicet.gov.ar:11336/7419 2025-01-16T19:39:21+00:00 Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films Monsalve, Leandro Nicolas Petroselli, Gabriela Erra Balsells, Rosa Vazquez, Analia Baldessari, Alicia application/pdf application/vnd.openxmlformats-officedocument.wordprocessingml.document http://hdl.handle.net/11336/7419 eng eng Elsevier info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/pi.4660/abstract info:eu-repo/semantics/altIdentifier/doi/10.1002/pi.4660 http://hdl.handle.net/11336/7419 Monsalve, Leandro Nicolas; Petroselli, Gabriela; Erra Balsells, Rosa; Vazquez, Analia; Baldessari, Alicia; Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films; Elsevier; Polymer International; 63; 8; 8-2014; 1523-1530 1097-0126 info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ Lipase Β-Peptoid Polycaprolactone Films Surface Properties https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion ftconicet https://doi.org/10.1002/pi.4660 2023-09-24T18:31:36Z Poly[N-(2-hydroxyethyl)-beta-propylamide] oligomer is syntehsized using a simple enzymatic procedure involving Candida antarctica lipase B. This novel compound is obtained by a green and chemoselective method from economic reactants in good yield. This beta-peptoid oligomer is characterized by spectroscopic methods showing low molecular weight and low dispersity. Two derivatives of this beta-peptoid oligomer ae prepared by acetylation and by grafting polycaprolactone by ring opening polymerization from the pendant hydroxyl groups. These products are blended with polycaprolactone to make films by solvent casting. The inclusion of the acyl derivatives of the beta-peptoid to polycaprolactone affects the morphology of the film yielding micro- and nanostructured patterns. Fil: Monsalve, Leandro Nicolas. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina. Instituto Nacional de Tecnologia Industrial; Argentina Fil: Petroselli, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina Fil: Erra Balsells, Rosa. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Centro de Investigaciones En Hidratos de Carbono; Argentina Fil: Vazquez, Analia. Consejo Nacional de Investigaciones Cientificas y Tecnicas. Oficina de Coordinacion Administrativa Houssay. Instituto de Tecnologia En Polimeros y Nanotecnologia; Argentina Fil: Baldessari, Alicia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Unidad de Microanálisis y Métodos Físicos Aplicados A la Química Orgánica (i); Argentina Article in Journal/Newspaper Antarc* Antarctica CONICET Digital (Consejo Nacional de Investigaciones Científicas y Técnicas) Alicia ENVELOPE(-63.483,-63.483,-64.833,-64.833) Argentina Vazquez ENVELOPE(-64.000,-64.000,-65.433,-65.433) Polymer International 63 8 1523 1530 |
| spellingShingle | Lipase Β-Peptoid Polycaprolactone Films Surface Properties https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 Monsalve, Leandro Nicolas Petroselli, Gabriela Erra Balsells, Rosa Vazquez, Analia Baldessari, Alicia Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films |
| title | Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films |
| title_full | Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films |
| title_fullStr | Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films |
| title_full_unstemmed | Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films |
| title_short | Chemoenzymatic synthesis of a novel N-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films |
| title_sort | chemoenzymatic synthesis of a novel n-2-hydroxyethyl)-beta-peptoid oligomer and application to porous polycaprolactone films |
| topic | Lipase Β-Peptoid Polycaprolactone Films Surface Properties https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| topic_facet | Lipase Β-Peptoid Polycaprolactone Films Surface Properties https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| url | http://hdl.handle.net/11336/7419 |