An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside
Methyl 2,3-di-O-acetyl-α,β-d-xylofuranoside was prepared as the sole regioisomer in 6372% yield, according to the applied mass of substrate, through a Candida antarctica lipase B catalysed alcoholysis of methyl 2,3,5-tri-O-acetyl-α,β-d-xylofuranoside. The product is a potential synthetic precursor f...
| Published in: | Biocatalysis and Biotransformation |
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| Main Authors: | , , |
| Format: | Article in Journal/Newspaper |
| Language: | English |
| Published: |
Taylor & Francis Ltd
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| Subjects: | |
| Online Access: | http://hdl.handle.net/11336/194493 |
| _version_ | 1821771147935481856 |
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| author | Gudiño, Esteban Dario Iribarren, Adolfo Marcelo Iglesias, Luis Emilio |
| author_facet | Gudiño, Esteban Dario Iribarren, Adolfo Marcelo Iglesias, Luis Emilio |
| author_sort | Gudiño, Esteban Dario |
| collection | CONICET Digital (Consejo Nacional de Investigaciones Científicas y Técnicas) |
| container_issue | 4 |
| container_start_page | 431 |
| container_title | Biocatalysis and Biotransformation |
| container_volume | 30 |
| description | Methyl 2,3-di-O-acetyl-α,β-d-xylofuranoside was prepared as the sole regioisomer in 6372% yield, according to the applied mass of substrate, through a Candida antarctica lipase B catalysed alcoholysis of methyl 2,3,5-tri-O-acetyl-α,β-d-xylofuranoside. The product is a potential synthetic precursor for 5-modified xylofuranosides and 5′-modified xylonucleosides. Fil: Gudiño, Esteban Dario. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Área Química. Laboratorio de Biotransformaciones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Iribarren, Adolfo Marcelo. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Área Química. Laboratorio de Biotransformaciones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Ingeniería Genética y Biología Molecular "Dr. Héctor N. Torres"; Argentina Fil: Iglesias, Luis Emilio. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Área Química. Laboratorio de Biotransformaciones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina |
| format | Article in Journal/Newspaper |
| genre | Antarc* Antarctica |
| genre_facet | Antarc* Antarctica |
| geographic | Argentina Quilmes |
| geographic_facet | Argentina Quilmes |
| id | ftconicet:oai:ri.conicet.gov.ar:11336/194493 |
| institution | Open Polar |
| language | English |
| long_lat | ENVELOPE(-55.617,-55.617,-63.233,-63.233) |
| op_collection_id | ftconicet |
| op_container_end_page | 434 |
| op_doi | https://doi.org/10.3109/10242422.2012.702110 |
| op_relation | info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.3109/10242422.2012.702110?journalCode=ibab20 info:eu-repo/semantics/altIdentifier/doi/10.3109/10242422.2012.702110 http://hdl.handle.net/11336/194493 Gudiño, Esteban Dario; Iribarren, Adolfo Marcelo; Iglesias, Luis Emilio; An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside; Taylor & Francis Ltd; Biocatalysis and Biotransformation; 30; 4; 1-2012; 431-434 1024-2422 CONICET Digital CONICET |
| op_rights | info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
| publisher | Taylor & Francis Ltd |
| record_format | openpolar |
| spelling | ftconicet:oai:ri.conicet.gov.ar:11336/194493 2025-01-16T19:37:59+00:00 An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside Gudiño, Esteban Dario Iribarren, Adolfo Marcelo Iglesias, Luis Emilio application/pdf http://hdl.handle.net/11336/194493 eng eng Taylor & Francis Ltd info:eu-repo/semantics/altIdentifier/url/https://www.tandfonline.com/doi/abs/10.3109/10242422.2012.702110?journalCode=ibab20 info:eu-repo/semantics/altIdentifier/doi/10.3109/10242422.2012.702110 http://hdl.handle.net/11336/194493 Gudiño, Esteban Dario; Iribarren, Adolfo Marcelo; Iglesias, Luis Emilio; An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside; Taylor & Francis Ltd; Biocatalysis and Biotransformation; 30; 4; 1-2012; 431-434 1024-2422 CONICET Digital CONICET info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ ANTARCTICA CANDIDA LIPASE B METHYL 2,3-DI-O-ACETYL- Α,Β-D-XYLOFURANOSIDE REGIOSELECTIVITY https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 info:eu-repo/semantics/article info:ar-repo/semantics/artículo info:eu-repo/semantics/publishedVersion ftconicet https://doi.org/10.3109/10242422.2012.702110 2023-09-24T20:19:52Z Methyl 2,3-di-O-acetyl-α,β-d-xylofuranoside was prepared as the sole regioisomer in 6372% yield, according to the applied mass of substrate, through a Candida antarctica lipase B catalysed alcoholysis of methyl 2,3,5-tri-O-acetyl-α,β-d-xylofuranoside. The product is a potential synthetic precursor for 5-modified xylofuranosides and 5′-modified xylonucleosides. Fil: Gudiño, Esteban Dario. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Área Química. Laboratorio de Biotransformaciones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Iribarren, Adolfo Marcelo. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Área Química. Laboratorio de Biotransformaciones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Ingeniería Genética y Biología Molecular "Dr. Héctor N. Torres"; Argentina Fil: Iglesias, Luis Emilio. Universidad Nacional de Quilmes. Departamento de Ciencia y Tecnología. Área Química. Laboratorio de Biotransformaciones; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Article in Journal/Newspaper Antarc* Antarctica CONICET Digital (Consejo Nacional de Investigaciones Científicas y Técnicas) Argentina Quilmes ENVELOPE(-55.617,-55.617,-63.233,-63.233) Biocatalysis and Biotransformation 30 4 431 434 |
| spellingShingle | ANTARCTICA CANDIDA LIPASE B METHYL 2,3-DI-O-ACETYL- Α,Β-D-XYLOFURANOSIDE REGIOSELECTIVITY https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 Gudiño, Esteban Dario Iribarren, Adolfo Marcelo Iglesias, Luis Emilio An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside |
| title | An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside |
| title_full | An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside |
| title_fullStr | An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside |
| title_full_unstemmed | An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside |
| title_short | An improved regioselective preparation of methyl 2,3-di-O-acetyl-α, β-d-xylofuranoside |
| title_sort | improved regioselective preparation of methyl 2,3-di-o-acetyl-α, β-d-xylofuranoside |
| topic | ANTARCTICA CANDIDA LIPASE B METHYL 2,3-DI-O-ACETYL- Α,Β-D-XYLOFURANOSIDE REGIOSELECTIVITY https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| topic_facet | ANTARCTICA CANDIDA LIPASE B METHYL 2,3-DI-O-ACETYL- Α,Β-D-XYLOFURANOSIDE REGIOSELECTIVITY https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
| url | http://hdl.handle.net/11336/194493 |