Atmospheric Chemistry and Physics Trends in long-term gaseous mercury observations in the Arctic and
for statistical time trends and for correlations with meteo-rological and climate data. A significant decreasing trend in annual GEM concentration is reported at Alert, with an estimated slope of −0.0086 ng m−3 yr−1 (−0.6 % yr−1) over this 13-year period. It is shown that there has been a shift in t...
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| Format: | Text |
| Language: | English |
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| Online Access: | http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.650.7584 http://www.atmos-chem-phys.net/10/4661/2010/acp-10-4661-2010.pdf |
| Summary: | for statistical time trends and for correlations with meteo-rological and climate data. A significant decreasing trend in annual GEM concentration is reported at Alert, with an estimated slope of −0.0086 ng m−3 yr−1 (−0.6 % yr−1) over this 13-year period. It is shown that there has been a shift in the month of minimum mean GEM concentration from May to April due to a change in the timing of springtime atmospheric mercury depletion events (AMDEs). These AMDEs are found to decrease with increasing local tem-perature within each month, both at Alert and at Amderma, Russia. These results support the temperature dependence suggested by previous experimental results and theoretical kinetic calculations on both bromine generation and mercury oxidation and highlight the potential for changes in Arctic mercury chemistry with climate. A correlation between total |
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