49. MOLECULAR AND ISOTOPIC ANALYSIS OF CORE GASES AND GAS HYDRATES, DEEP SEA DRILLING PROJECT LEG 961

• Main Authors: Ronald C. Pflaum, James M. Brooks, H. Benjamin Cox, Mahlon C. Kennicutt Ii, Der-duen Sheu
• Other Authors: The Pennsylvania State University CiteSeerX Archives
• Format: Text
• Language: English
• Subjects: Orca
• Online Access: http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.484.8076; http://www.deepseadrilling.org/96/volume/dsdp96_49.pdf

Molecular and isotopic compositions of void gases from Sites 618 and 619 were determined. The gases were predom-inantly methane with the C L /C 2 ratios averaging 4,000 and 26,000 at Sites 618 and 619, respectively. The δ 13C-Cj values at Site 618 were nearly constant, ranging from- 70.1 to- 73.7‰. δ1 3C-CHj values for Site 619 between 76 and 178 me-ters sub-bottom ranged from- 94.8 to- 70.8‰, becoming progressively heavier with depth. The molecular and isotop-ic compositions at both sites are characteristic of biogenic methane. Small spheres ( ~ 1-2 mm diameter) of gas hydrates were observed in the Orca Basin between 20 and 40 m sub-bot-tom and were often associated with sandy sections. The hydrate was predominantly methane with a δ13-Cj of-71‰ and trace amounts of ethane, propane, and carbon dioxide. The isotopic value for the methane was similar to that of the nearest gas pocket, indicating that hydrate was formed from predominantly biogenic methane without isotopic fractionation.