Electrochemical and Infrared Studies of the Reduction of Organic Carbonates

Electrolytes typically used in lithium batteries consist of a lithium salt dissolved in an organic solvent, or a mixture of these solvents. The solvents fall into two general classes: ethers or alkyl esters of carbonic acid. Because of lower volatility and higher flash point, the organic carbonates...

Full description

Bibliographic Details
Main Authors: Xuerong Zhang, Thomas J. Richardson, James K. Pugh, Philip N. Ross
Other Authors: The Pennsylvania State University CiteSeerX Archives
Format: Text
Language:English
Subjects:
Online Access:http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.159.2439
http://infrared.als.lbl.gov/pubs/RossCompendium2000-2.PDF
Description
Summary:Electrolytes typically used in lithium batteries consist of a lithium salt dissolved in an organic solvent, or a mixture of these solvents. The solvents fall into two general classes: ethers or alkyl esters of carbonic acid. Because of lower volatility and higher flash point, the organic carbonates are the preferred solvent class in commercial batteries. Propylene carbonate (PC) has many