Influences of Atlantic Ocean thermohaline circulation and Antarctic ice-sheet expansion on Pliocene deep Pacific carbonate chemistry

• Published in: Earth and Planetary Science Letters
• Main Authors: Qin, Bingbin, Li, Tiegang, Xiong, Zhifang, Algeo, Thomas J., Jia, Qi, Nurnberg, Dirk, Shi, Jiangnan
• Format: Report
• Language: English
• Published: ELSEVIER 2022
• Subjects: shell weight; A[CO2-3 ]; Panamanian Gateway; glaciation; atmosphericpCO2; Site U1490; Geochemistry & Geophysics; SEA-SURFACE TEMPERATURES; PLANKTONIC-FORAMINIFERA; TROPICAL PACIFIC; SOUTHERN-OCEAN; NORTH-ATLANTIC; WATER; MA; CALCIFICATION; EVOLUTION; NEODYMIUM; Antarctic; Pacific; Southern Ocean; Antarc*; Ice Sheet; NADW; North Atlantic Deep Water; North Atlantic; Planktonic foraminifera; Sea ice
• Online Access: http://ir.qdio.ac.cn/handle/337002/180294; https://doi.org/10.1016/j.epsl.2022.117868

Quantifying changes in seawater carbonate chemistry is crucial to deciphering of patterns and drivers of the oceanic carbon cycle and climate change. Here, we present a new deep-water carbonate ion saturation state (A[CO2- 3 ]) record for the Pliocene western tropical Pacific, reconstructed from the size -normalized weight of the planktonic foraminifer Trilobatus sacculifer of IODP Site U1490. A steep decline in deep-water A[CO2- 3 ] occurred at similar to 4.6 Ma synchronous to the enhanced production of North Atlantic Deep Water (NADW) related to the closure of the Panamanian Gateway. Subsequently, at the onset of the Northern Hemisphere glaciation at similar to 2.7 Ma the weakening of NADW formation resulted in a deep -water A[CO2- 3 ] peak. The changes in NADW production rate likely controlled a seesaw-like fluctuation in deep-water A[CO2- 3 ] between the Pacific and Atlantic oceans. During the late Pliocene (similar to 3.8-2.8 Ma), Antarctic ice-sheet/sea-ice expansions sequestered CO2 in the deep Pacific through ventilation of the deep watermass, leading to a long-term decrease in deep Pacific A[CO2-3]. We infer that fluctuating NADW production rates at similar to 4.6 Ma and similar to 2.7 Ma influenced inter-basinal fractionation of deep-ocean carbon between the Atlantic and Pacific, and that deep Pacific carbon storage linked to expansions of Antarctic ice sheet/sea ice contributed to the lowering of atmospheric pCO2 and global cooling during the late Pliocene.(c) 2022 Elsevier B.V. All rights reserved.