低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究
本研究以台南郊區中秋節時期、秋季一般空氣品質時期及高污染時期與代表低海拔偏遠地區的曾文水庫之大氣氣膠無機鹽類及二元有機酸，並以阿里山之背景資料，探討不同時空之大氣氣膠化學成份特性、生成來源及粒徑分佈。 曾文水庫偏遠地區及郊區秋季一般空氣品質時期大氣氣狀物之全日平均濃度高低為NH3＞SO2＞HNO3＞HNO2＞HCl＞oxalic acid，但在中秋節時期HCl濃度高於HNO3。中秋節時期及秋季一般空氣品質氣狀oxalic acid日間濃度較大，高污染時期則日夜濃度相當，顯示大氣中在日間有較多氣態oxalic acid來源。曾文水庫大氣PM2.5氣膠無機鹽類之全日平均濃度高低為SO42-＞NH4...
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| Language: | Chinese English |
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2008
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| Online Access: | https://ir.cnu.edu.tw/handle/310902800/9701 https://ir.cnu.edu.tw/bitstream/310902800/9701/1/index.html |
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ftchiananuniv:oai:ir.cnu.edu.tw:310902800/9701 |
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openpolar |
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Open Polar |
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Chia Nan University of Pharmacy & Science Institutional Repository (CHNAIR) |
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ftchiananuniv |
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Chinese English |
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二元有機酸 氣膠 aerosol dicarboxylic acid |
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二元有機酸 氣膠 aerosol dicarboxylic acid 馬玉芊 Yu-Chien Ma 低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究 |
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二元有機酸 氣膠 aerosol dicarboxylic acid |
| description |
本研究以台南郊區中秋節時期、秋季一般空氣品質時期及高污染時期與代表低海拔偏遠地區的曾文水庫之大氣氣膠無機鹽類及二元有機酸，並以阿里山之背景資料，探討不同時空之大氣氣膠化學成份特性、生成來源及粒徑分佈。 曾文水庫偏遠地區及郊區秋季一般空氣品質時期大氣氣狀物之全日平均濃度高低為NH3＞SO2＞HNO3＞HNO2＞HCl＞oxalic acid，但在中秋節時期HCl濃度高於HNO3。中秋節時期及秋季一般空氣品質氣狀oxalic acid日間濃度較大，高污染時期則日夜濃度相當，顯示大氣中在日間有較多氣態oxalic acid來源。曾文水庫大氣PM2.5氣膠無機鹽類之全日平均濃度高低為SO42-＞NH4+＞NO3-；中秋節時期，無機鹽類夜間濃度多高於日間，濃度高低為SO42-＞NO3-＞Na+，Na+在此時期在日、夜間濃度皆比秋季一般空氣品質時期高，除了部份的海鹽粒子外，另一部份可能來自烤肉燃燒之貢獻，另外，中秋節期間Cl-和K+之相關係數為0.76，顯示此時期之大氣環境除了燃放煙火所造成的污染外，亦存在烤肉之生物性燃燒排放的貢獻。 曾文水庫、郊區秋季一般空氣品質時期及高污染時期之PM2.5二元有機酸濃度高低依序為oxalic acid＞succinic acid＞glutaric acid，日間濃度皆高於夜間，但中秋節時期之glutaric acid濃度高於succinic acid，在日間之濃度為秋季一般空氣品質時期之1.4倍，夜間則為1.8倍，顯示夜間有較多之glutaric acid之生成來源，且中秋節時期Na+與glutaric acid之相關性為0.72，顯示中秋節時期的氣膠glutaric acid來自此時期特殊之人為活動所排放。曾文水庫之glutaric acid與succinic acid之相關性為0.70，而succinic acid與oxalic acid之間的相關性及malonic acid與oxalic acid之相關性皆很小，分別僅有0.49及0.27，顯示此偏遠的林地區域之oxalic acid來自當地生物排放。 曾文水庫偏遠地區之無機鹽類濃度粒徑主要分佈在0.54-2.5 μm的液滴峰(droplet mode)，並在10 nm之成核峰(nuclei mode)有初始氣膠微粒之生成，曾文水庫及阿里山之NO3-微粒分佈主要呈單峰分佈，在coarse mode之形成與Na+及succinic acid趨勢一致，顯示二地均有海洋飛沫所貢獻。然而台南郊區之中秋節時期Na+及Cl-濃度於各粒徑波峰皆比曾文水庫高，而二物種在coarse mode之中秋節時期/曾文水庫比值分別為8.63、5.46，顯示在中秋節時期的台南郊區有更明顯的海洋飛沫貢獻，中秋節期間氣膠glutaric acid、succinic acid及malonic acid在coarse mode為曾文水庫之36.09、10.41及14.49，也顯示特殊人為活動對大氣環境所造成的污染。Oxalic acid於台南郊區中秋節時期之質量中位數粒徑(Mass median aerodynamic diameter, MMAD)為0.63 μm，較秋季一般空氣品質時期的0.78 μm小，顯示特殊燃燒產生之oxalic acid分佈於較小尺寸；阿里山oxalic acid氣膠之MMAD為0.83 μm，比曾文水庫的0.73 μm大，而阿里山之平均相對濕度為88.5%較曾文水庫之74.5%高，雖然其MMAD均在雲霧凝結之液滴峰，但顯示氣膠吸濕增大之特性在阿里山背景地區較為明顯。 The spatial and temporal chemical compositions, characteristics, formation, sources, and particle distribution of aerosols in suburban Tainan in southern Taiwan during the Mid-Autumn Festival period, the fall moderate air quality period, and a high pollution loading (PM episode) period, and in the atmosphere of the remote Tseng-Wen Reservoir region are compared with the background information obtained in Alishan region. The order of magnitude for gaseous pollutants in the atmosphere of the remote Tseng-Wen Reservoir region and of the fall ... |
| author2 |
蔡瀛逸 嘉南藥理科技大學：環境工程與科學系所 |
| format |
Thesis |
| author |
馬玉芊 Yu-Chien Ma |
| author_facet |
馬玉芊 Yu-Chien Ma |
| author_sort |
馬玉芊 |
| title |
低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究 |
| title_short |
低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究 |
| title_full |
低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究 |
| title_fullStr |
低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究 |
| title_full_unstemmed |
低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究 |
| title_sort |
低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究 |
| publishDate |
2008 |
| url |
https://ir.cnu.edu.tw/handle/310902800/9701 https://ir.cnu.edu.tw/bitstream/310902800/9701/1/index.html |
| genre |
Arctic |
| genre_facet |
Arctic |
| op_relation |
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ftchiananuniv:oai:ir.cnu.edu.tw:310902800/9701 2023-05-15T14:28:23+02:00 低海拔偏遠地區及平地郊區之大氣氣膠二元有機酸之化學特性及其粒徑變異研究 Characterization of Compositions and Size Distributions of Dicarboxylic Acid in Low-altitude Remote and Suburban Aerosols 馬玉芊 Yu-Chien Ma 蔡瀛逸 嘉南藥理科技大學：環境工程與科學系所 2008 142 bytes application/octet-stream https://ir.cnu.edu.tw/handle/310902800/9701 https://ir.cnu.edu.tw/bitstream/310902800/9701/1/index.html zh_TW en_US chi eng 校內馬上公開，校外一年後公開 Acker, K., Mertes, S., Möller, D., Wieprecht, W., Auel, R., Kalaβ, 2002. Case study of cloud physical and chemical processes. Atmospheric Research 64, 41-51. Anlauf, K., Li, S.M., Leaitch, R., Brook, J., Hayden, K., Toom-Sauntry, D., Wiebe, A., 2006. Ionic composition and size characteristics of particles in the lower Fraser Vellay: Pacific 2001 field study. Atmospheric Environment 40, 2662-2675. Attri, A.K., Kumar, U., Jain, V.K., 2001. Microclimate formation of ozone by fireworks. Nature 411(6841), 1015. 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Atmospheric Environment 33, 843-853. 游智淵、張艮輝，「第三代台灣地區生物源排放量推估模式之建立與應用」，第18屆空氣 污染控制技術研討會論文集，台中，2004。 楊宏隆，「大氣懸浮微粒PM2.5及PM10之特性來源分析」，國立中興大學環境工程學系碩士 論文，台中，1998。 黃香儒，「秋冬季節之大氣氣膠無機鹽類及二元酸之組成及粒徑變異研究」，嘉南藥理科 技大學環境工程與科學系碩士論文，台南，2005。 翁子翔，「背景與郊區大氣氣膠無機鹽類及二元有機酸之化學特性及其粒徑變異研究」， 嘉南藥理科技大學環境工程與科學系碩士論文，台南，2006。 徐玉眉，「海鹽氣膠氯損失之研究」，國立台灣大學環境工程學研究所碩士論文，台北， 1990。 袁中新、李崇垓、劉山豪、袁菁，「南台灣都會區大氣氣膠中細微粒污染貢獻量解析」， 第八屆氣膠科技研討會論文集，41-46頁，2000。 https://ir.cnu.edu.tw/handle/310902800/9701 https://ir.cnu.edu.tw/bitstream/310902800/9701/1/index.html 二元有機酸 氣膠 aerosol dicarboxylic acid thesis 2008 ftchiananuniv 2022-05-15T05:25:33Z 本研究以台南郊區中秋節時期、秋季一般空氣品質時期及高污染時期與代表低海拔偏遠地區的曾文水庫之大氣氣膠無機鹽類及二元有機酸，並以阿里山之背景資料，探討不同時空之大氣氣膠化學成份特性、生成來源及粒徑分佈。 曾文水庫偏遠地區及郊區秋季一般空氣品質時期大氣氣狀物之全日平均濃度高低為NH3＞SO2＞HNO3＞HNO2＞HCl＞oxalic acid，但在中秋節時期HCl濃度高於HNO3。中秋節時期及秋季一般空氣品質氣狀oxalic acid日間濃度較大，高污染時期則日夜濃度相當，顯示大氣中在日間有較多氣態oxalic acid來源。曾文水庫大氣PM2.5氣膠無機鹽類之全日平均濃度高低為SO42-＞NH4+＞NO3-；中秋節時期，無機鹽類夜間濃度多高於日間，濃度高低為SO42-＞NO3-＞Na+，Na+在此時期在日、夜間濃度皆比秋季一般空氣品質時期高，除了部份的海鹽粒子外，另一部份可能來自烤肉燃燒之貢獻，另外，中秋節期間Cl-和K+之相關係數為0.76，顯示此時期之大氣環境除了燃放煙火所造成的污染外，亦存在烤肉之生物性燃燒排放的貢獻。 曾文水庫、郊區秋季一般空氣品質時期及高污染時期之PM2.5二元有機酸濃度高低依序為oxalic acid＞succinic acid＞glutaric acid，日間濃度皆高於夜間，但中秋節時期之glutaric acid濃度高於succinic acid，在日間之濃度為秋季一般空氣品質時期之1.4倍，夜間則為1.8倍，顯示夜間有較多之glutaric acid之生成來源，且中秋節時期Na+與glutaric acid之相關性為0.72，顯示中秋節時期的氣膠glutaric acid來自此時期特殊之人為活動所排放。曾文水庫之glutaric acid與succinic acid之相關性為0.70，而succinic acid與oxalic acid之間的相關性及malonic acid與oxalic acid之相關性皆很小，分別僅有0.49及0.27，顯示此偏遠的林地區域之oxalic acid來自當地生物排放。 曾文水庫偏遠地區之無機鹽類濃度粒徑主要分佈在0.54-2.5 μm的液滴峰(droplet mode)，並在10 nm之成核峰(nuclei mode)有初始氣膠微粒之生成，曾文水庫及阿里山之NO3-微粒分佈主要呈單峰分佈，在coarse mode之形成與Na+及succinic acid趨勢一致，顯示二地均有海洋飛沫所貢獻。然而台南郊區之中秋節時期Na+及Cl-濃度於各粒徑波峰皆比曾文水庫高，而二物種在coarse mode之中秋節時期/曾文水庫比值分別為8.63、5.46，顯示在中秋節時期的台南郊區有更明顯的海洋飛沫貢獻，中秋節期間氣膠glutaric acid、succinic acid及malonic acid在coarse mode為曾文水庫之36.09、10.41及14.49，也顯示特殊人為活動對大氣環境所造成的污染。Oxalic acid於台南郊區中秋節時期之質量中位數粒徑(Mass median aerodynamic diameter, MMAD)為0.63 μm，較秋季一般空氣品質時期的0.78 μm小，顯示特殊燃燒產生之oxalic acid分佈於較小尺寸；阿里山oxalic acid氣膠之MMAD為0.83 μm，比曾文水庫的0.73 μm大，而阿里山之平均相對濕度為88.5%較曾文水庫之74.5%高，雖然其MMAD均在雲霧凝結之液滴峰，但顯示氣膠吸濕增大之特性在阿里山背景地區較為明顯。 The spatial and temporal chemical compositions, characteristics, formation, sources, and particle distribution of aerosols in suburban Tainan in southern Taiwan during the Mid-Autumn Festival period, the fall moderate air quality period, and a high pollution loading (PM episode) period, and in the atmosphere of the remote Tseng-Wen Reservoir region are compared with the background information obtained in Alishan region. The order of magnitude for gaseous pollutants in the atmosphere of the remote Tseng-Wen Reservoir region and of the fall ... Thesis Arctic Chia Nan University of Pharmacy & Science Institutional Repository (CHNAIR) |