台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究

本研究探討台南郊區2005年5月至2008年12月底止，包括梅雨季節、颱風降雨與颱風外圍環流、夏季、秋冬乾季降雨及春季降雨之濕沉降特性，主要探討降雨的酸鹼度、無機鹽類及低分子量之二元有機酸之當量濃度變化及其相關性。 在台南郊區不同季節降雨型態之平均降雨，酸強度由高至低依序為秋冬乾季、梅雨季節、颱風外圍環流雨水、夏季、颱風降雨及春季，其pH值分別為5.29、5.32、5.45、5.46、5.56及5.74，而降雨的pH是由酸性離子SO42-、NO3-、HCO3-及鹼性離子NH4+、Ca2+所共同決定。各季節降雨中物種組成成份，所佔百分比不同，其中在颱風濕沉降中Cl- (24.56±26.24%)...

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Main Author: 李怡慧
Other Authors: 蔡瀛逸, 嘉南藥理科技大學：環境工程與科學系曁研究所
Format: Thesis
Language:Chinese
English
Published: 2009
Subjects:
濕沉降
Wet Deposition
Arctic
Online Access:https://ir.cnu.edu.tw/handle/310902800/22859
https://ir.cnu.edu.tw/bitstream/310902800/22859/2/index.html
id ftchiananuniv:oai:ir.cnu.edu.tw:310902800/22859
record_format openpolar
institution Open Polar
collection Chia Nan University of Pharmacy & Science Institutional Repository (CHNAIR)
op_collection_id ftchiananuniv
language Chinese
English
topic 濕沉降
Wet Deposition
spellingShingle 濕沉降
Wet Deposition
李怡慧
台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究
topic_facet 濕沉降
Wet Deposition
description 本研究探討台南郊區2005年5月至2008年12月底止，包括梅雨季節、颱風降雨與颱風外圍環流、夏季、秋冬乾季降雨及春季降雨之濕沉降特性，主要探討降雨的酸鹼度、無機鹽類及低分子量之二元有機酸之當量濃度變化及其相關性。 在台南郊區不同季節降雨型態之平均降雨，酸強度由高至低依序為秋冬乾季、梅雨季節、颱風外圍環流雨水、夏季、颱風降雨及春季，其pH值分別為5.29、5.32、5.45、5.46、5.56及5.74，而降雨的pH是由酸性離子SO42-、NO3-、HCO3-及鹼性離子NH4+、Ca2+所共同決定。各季節降雨中物種組成成份，所佔百分比不同，其中在颱風濕沉降中Cl- (24.56±26.24%)、Na+ (28.08±22.72%)及Mg2+ (8.24±4.30%)佔降雨物種當量濃度比例最高，在夏季濕沉降中，Na+(18.21±29.48%)佔降雨物種當量濃度比例很高，而在春季濕沉降中，Ca2+(22.06±14.24%)佔降雨物種當量濃度比例最高。此外五種濕沉降型態中，平均而言，二元有機酸佔物種組成成份的(0.25－0.53%)，二元有機酸均以oxalic acid為主要物種。 三種二元有機酸在各降雨型態中，以春季濕沉降所佔已分析物種組成比例為最高，主要乃因春季時期長期沒有降雨，而在降雨時，降雨雨量少及降雨強度小，導致濕沉降中之三種二元有機酸當量濃度較其他降雨型態為高。比較不同季節型態之二元有機酸之malonic acid:succinic acid (M:S)比值，在梅雨季節、颱風降雨、夏季、秋冬乾季及春季降雨型態的M:S比值，分別為1.84、0.82、1.20、1.50及1.56，其值介於低比值(0.3－0.5)與高比值3之間，由梅雨季節、颱風降雨、夏季、秋冬乾季及春季降雨型態逆軌跡圖所示，顯示降雨物種經長程傳輸，從海上吹經高雄市區，降雨之部份來源為市區交通的污染排放和在海洋上產生的光化產物溶入降雨中，在颱風外圍環流型態的M:S比值為4.54，其M:S的比值高於3，由颱風外圍環流降雨型態逆軌跡圖顯示降雨中之物種來源主要為顯示降雨明顯溶入光化產物的貢獻。 In this study, characteristics of the wet precipitation of the Mei-yu rain, typhoon precipitation and typhoon peripheral circumfluence and winter and spring in suburban Tainan from May 2005 till December 2008 were investigated. The investigation covered the acidity, inorganic salts and low-molecular-weight dicarboxylic acids (low-Mw DCAs) to study their equivalent concentration variations and correlations. For the various seasonal precipitation patterns in suburban Tainan, according to the acidity decreasing magnitudes, the rainwater pH values are 5.29 for winter precipitation 5.32 for the Mei-yu rainy season, 5.45 for typhoon peripheral circumfluence, 5.46 for summer shower, 5.56 for typhoon precipitation and 5.74 for spring precipitation. The pH is dependent on presence of anions, e.g. SO42-, NO3- and HCO3- as well as cations, e.g. NH4+ and Ca2+ in the rainwater. Further, as the percentage compositions of all chemical species in the various precipitation patterns are concerned, the typhoon wet precipitation has the highest percentages of Cl- (24.56±26.24%), Na+ (28.08±22.72%) and Mg2+ (8.24±4.30%). In summer wet precipitation, Na+ ...
author2 蔡瀛逸
嘉南藥理科技大學：環境工程與科學系曁研究所
format Thesis
author 李怡慧
author_facet 李怡慧
author_sort 李怡慧
title 台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究
title_short 台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究
title_full 台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究
title_fullStr 台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究
title_full_unstemmed 台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究
title_sort 台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究
publishDate 2009
url https://ir.cnu.edu.tw/handle/310902800/22859
https://ir.cnu.edu.tw/bitstream/310902800/22859/2/index.html
genre Arctic
genre_facet Arctic
op_relation 校內校外均不公開，學年度：97， 121 頁
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Nature 299, 548-550. 6. Buijsman, E., Mass, H.F.M., Asman, W.A.H., 1987. Anthropogenic NH3 emissions in Europe. Atmospheric Environment 21, 1009-1022. 7. Calert, J.G., Lazrus A., Kok, G.L., Heikes, B.G., Walega, J.G., Lind, J., Cantrell C.A., 1985. Chemical mechanism of acid rain generation in the troposphere. Nature 317, 27-35. 8. Charlson, R.J., Rodhe, H., 1982. Factors controlling the acidity of natural rainwater. Nature 295, 683-685. 9. Chebbi, A., Carlier, P., 1996. Carboxylic acids in the troposphere, occurrence, sources, and sinks: a review. Atmospheric Environment 30, 4233-4249. 10. Cruz, C.N., Pandis, S.N., 1997. A study of the ability of pure secondary organic aerosol to act as cloud condensation nuclei. Atmospheric Environment 33, 2661-2668. 11. Dikaiakos, J.G., Tsitouris, C.G., Siskos, P.A., Melissos, D.A., Nastos, P., 1990. Rainwater composition in Athens, Greece. Atmospheric Environment 24B, 171-176. 12. Driscoll, C.T., Johnson, N. M., Likens, G.E., Feller, M.C., 1988. 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https://ir.cnu.edu.tw/handle/310902800/22859
https://ir.cnu.edu.tw/bitstream/310902800/22859/2/index.html
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spelling ftchiananuniv:oai:ir.cnu.edu.tw:310902800/22859 2023-05-15T14:28:32+02:00 台南郊區濕沉降之無機鹽類與二元有機酸季節變異性研究 Seasonal Variations of Inorganic Salts and Dicarboxylic Acids in Wet Deposition in the Suburban Tainan 李怡慧 蔡瀛逸 嘉南藥理科技大學：環境工程與科學系曁研究所 2009 142 bytes text/html https://ir.cnu.edu.tw/handle/310902800/22859 https://ir.cnu.edu.tw/bitstream/310902800/22859/2/index.html zh_TW en_US chi eng 校內校外均不公開，學年度：97， 121 頁 1. Aherne, J., Farrell, E.P., 2002. Deposition of sulphur, nitrogen and acidity in precipitation over Ireland: chemistry, spatial distribution and long-term trends. Atmospheric Environment 36, 1379-1389. 2. Acker, K., Mertes, S., Möller, D., Wieprecht, W., Auel, R., Kalaβ, 2002. Case study of cloud physical and chemical processes. Atmospheric Research 64, 41-51. 3. Avery Jr., G.B., Kieber, R.J., Witt, M., Willey, J.D., 2006. Rainwater monocarboxylic and dicarboxylic acid concentrations in southeastern North Carolina, USA, as a function of air-mass back-trajectory. Atmospheric Environment 40, 1683-1693. 4. Avila, A., Alarcon, M., 1999. Relationship between precipitation chemistry and meteorological situations at a rural site in NE Spain. Atmospheric Environment 33, 1663-1677. 5. Breemen, N., Borrough, P.A., Velthorst, E.J., Dobben, H.F., Wit, T., Ridder, T.B., Reijnders, H.F.R., 1982. Soil acidification from atmospheric ammonium sulphate in forest canopy throughfall . Nature 299, 548-550. 6. Buijsman, E., Mass, H.F.M., Asman, W.A.H., 1987. Anthropogenic NH3 emissions in Europe. Atmospheric Environment 21, 1009-1022. 7. Calert, J.G., Lazrus A., Kok, G.L., Heikes, B.G., Walega, J.G., Lind, J., Cantrell C.A., 1985. Chemical mechanism of acid rain generation in the troposphere. Nature 317, 27-35. 8. Charlson, R.J., Rodhe, H., 1982. Factors controlling the acidity of natural rainwater. Nature 295, 683-685. 9. Chebbi, A., Carlier, P., 1996. Carboxylic acids in the troposphere, occurrence, sources, and sinks: a review. 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The investigation covered the acidity, inorganic salts and low-molecular-weight dicarboxylic acids (low-Mw DCAs) to study their equivalent concentration variations and correlations. For the various seasonal precipitation patterns in suburban Tainan, according to the acidity decreasing magnitudes, the rainwater pH values are 5.29 for winter precipitation 5.32 for the Mei-yu rainy season, 5.45 for typhoon peripheral circumfluence, 5.46 for summer shower, 5.56 for typhoon precipitation and 5.74 for spring precipitation. The pH is dependent on presence of anions, e.g. SO42-, NO3- and HCO3- as well as cations, e.g. NH4+ and Ca2+ in the rainwater. Further, as the percentage compositions of all chemical species in the various precipitation patterns are concerned, the typhoon wet precipitation has the highest percentages of Cl- (24.56±26.24%), Na+ (28.08±22.72%) and Mg2+ (8.24±4.30%). In summer wet precipitation, Na+ ... Thesis Arctic Chia Nan University of Pharmacy & Science Institutional Repository (CHNAIR)

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