Air/Sea Transfer of Highly Soluble Gases Over Coastal Waters
The deposition of soluble trace gases to the sea surface is not well studied due to a lack of flux measurements over the ocean. Here we report simultaneous air/sea eddy covariance flux measurements of water vapor, sulfur dioxide (SO2), and momentum from a coastal North Atlantic pier. Gas transfer ve...
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ftchapmanuniv:oai:digitalcommons.chapman.edu:sees_articles-1257 2023-05-15T17:33:07+02:00 Air/Sea Transfer of Highly Soluble Gases Over Coastal Waters Porter, J. G. de Bruyn, Warren J. Miller, S. D. Saltzman, E. S. 2020-01-07T08:00:00Z application/pdf https://digitalcommons.chapman.edu/sees_articles/257 https://digitalcommons.chapman.edu/cgi/viewcontent.cgi?article=1257&context=sees_articles unknown Chapman University Digital Commons https://digitalcommons.chapman.edu/sees_articles/257 https://digitalcommons.chapman.edu/cgi/viewcontent.cgi?article=1257&context=sees_articles American Geophysical Union Biology, Chemistry, and Environmental Sciences Faculty Articles and Research air/sea gas exchange sulfur cycle gas deposition air/sea exchange sulfur dioxide Atmospheric Sciences Environmental Chemistry Oceanography Other Oceanography and Atmospheric Sciences and Meteorology text 2020 ftchapmanuniv 2022-03-07T15:38:15Z The deposition of soluble trace gases to the sea surface is not well studied due to a lack of flux measurements over the ocean. Here we report simultaneous air/sea eddy covariance flux measurements of water vapor, sulfur dioxide (SO2), and momentum from a coastal North Atlantic pier. Gas transfer velocities were on average about 20% lower for SO2 than for H2O. This difference is attributed to the difference in molecular diffusivity between the two molecules (D SO 2/D H 2O = 0.5), in reasonable agreement with bulk parameterizations in air/sea gas models. This study demonstrates that it is possible to observe the effect of molecular diffusivity on air‐side resistance to gas transfer. The slope of observed relationship between gas transfer velocity and friction velocity is slightly smaller than predicted by gas transfer models, possibly due to wind/wave interactions that are unaccounted for in current models. Text North Atlantic Chapman University Digital Commons |
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Chapman University Digital Commons |
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topic |
air/sea gas exchange sulfur cycle gas deposition air/sea exchange sulfur dioxide Atmospheric Sciences Environmental Chemistry Oceanography Other Oceanography and Atmospheric Sciences and Meteorology |
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air/sea gas exchange sulfur cycle gas deposition air/sea exchange sulfur dioxide Atmospheric Sciences Environmental Chemistry Oceanography Other Oceanography and Atmospheric Sciences and Meteorology Porter, J. G. de Bruyn, Warren J. Miller, S. D. Saltzman, E. S. Air/Sea Transfer of Highly Soluble Gases Over Coastal Waters |
topic_facet |
air/sea gas exchange sulfur cycle gas deposition air/sea exchange sulfur dioxide Atmospheric Sciences Environmental Chemistry Oceanography Other Oceanography and Atmospheric Sciences and Meteorology |
description |
The deposition of soluble trace gases to the sea surface is not well studied due to a lack of flux measurements over the ocean. Here we report simultaneous air/sea eddy covariance flux measurements of water vapor, sulfur dioxide (SO2), and momentum from a coastal North Atlantic pier. Gas transfer velocities were on average about 20% lower for SO2 than for H2O. This difference is attributed to the difference in molecular diffusivity between the two molecules (D SO 2/D H 2O = 0.5), in reasonable agreement with bulk parameterizations in air/sea gas models. This study demonstrates that it is possible to observe the effect of molecular diffusivity on air‐side resistance to gas transfer. The slope of observed relationship between gas transfer velocity and friction velocity is slightly smaller than predicted by gas transfer models, possibly due to wind/wave interactions that are unaccounted for in current models. |
format |
Text |
author |
Porter, J. G. de Bruyn, Warren J. Miller, S. D. Saltzman, E. S. |
author_facet |
Porter, J. G. de Bruyn, Warren J. Miller, S. D. Saltzman, E. S. |
author_sort |
Porter, J. G. |
title |
Air/Sea Transfer of Highly Soluble Gases Over Coastal Waters |
title_short |
Air/Sea Transfer of Highly Soluble Gases Over Coastal Waters |
title_full |
Air/Sea Transfer of Highly Soluble Gases Over Coastal Waters |
title_fullStr |
Air/Sea Transfer of Highly Soluble Gases Over Coastal Waters |
title_full_unstemmed |
Air/Sea Transfer of Highly Soluble Gases Over Coastal Waters |
title_sort |
air/sea transfer of highly soluble gases over coastal waters |
publisher |
Chapman University Digital Commons |
publishDate |
2020 |
url |
https://digitalcommons.chapman.edu/sees_articles/257 https://digitalcommons.chapman.edu/cgi/viewcontent.cgi?article=1257&context=sees_articles |
genre |
North Atlantic |
genre_facet |
North Atlantic |
op_source |
Biology, Chemistry, and Environmental Sciences Faculty Articles and Research |
op_relation |
https://digitalcommons.chapman.edu/sees_articles/257 https://digitalcommons.chapman.edu/cgi/viewcontent.cgi?article=1257&context=sees_articles |
op_rights |
American Geophysical Union |
_version_ |
1766131522455207936 |