Experimental Investigation into Factors Influencing Methane Hydrate Formation and a Novel Method for Hydrate Formation in Porous Media

The behaviors of methane hydrate formation in porous media are investigated in three-dimensional vessels. The effects of the fugacity difference, the water-gas ratio, and the volume of the vessel on the formation rate of methane hydrate are studied. The results show that the formation rates are disp...

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Bibliographic Details
Published in:Energy & Fuels
Main Authors: Wang, Yi, Li, Xiao-Sen, Xu, Wen-Yue, Li, Qing-Ping, Zhang, Yu, Li, Gang, Huang, Ning-Sheng, Feng, Jing-Chun
Format: Article in Journal/Newspaper
Language:English
Published: 2013
Subjects:
Online Access:http://ir.giec.ac.cn/handle/344007/9089
https://doi.org/10.1021/ef400720h
Description
Summary:The behaviors of methane hydrate formation in porous media are investigated in three-dimensional vessels. The effects of the fugacity difference, the water-gas ratio, and the volume of the vessel on the formation rate of methane hydrate are studied. The results show that the formation rates are disproportionate to the fugacity differences but in proportion to the volume of the vessel and the change of the initial gas-water ratio has little effect on the rate of hydrate formation. Meanwhile, according to the discussion about the temperatures and resistances in hydrate reservoir, it is confirmed that methane hydrate forms from the boundaries to the center of the vessel. Furthermore, a new method is designed to form methane hydrate samples in porous sediments with high hydrate/water saturation and low gas saturation.