Kinetic Effects of Ionic Liquids on Methane Hydrate
The kinetic effects of several kinds of ionic liquids (ILs) on the formation of methane hydrate were experimentally investigated on both the macroscale and microscale levels. These ILs were 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIm]-BF4), 1-butyl-3-methylimidazolium tetrafluoroborate ([BM...
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AMER CHEMICAL SOC
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ftchacadsciegiec:oai:ir.giec.ac.cn:344007/24636 2023-05-15T17:11:12+02:00 Kinetic Effects of Ionic Liquids on Methane Hydrate Shen, Xiao-dong Zhou, Xue-bing Liang, De-qing 2019-02-01 http://ir.giec.ac.cn/handle/344007/24636 https://doi.org/10.1021/acs.energyfuels.8b03108 英语 eng AMER CHEMICAL SOC ENERGY & FUELS http://ir.giec.ac.cn/handle/344007/24636 doi:10.1021/acs.energyfuels.8b03108 DUAL FUNCTION INHIBITORS PHASE-EQUILIBRIA CO2 HYDRATE DISSOCIATION CONDITIONS INDUCTION TIME AMINO-ACIDS WATER SOLVENTS RISK CHLORIDE Energy & Fuels Engineering Chemical 期刊论文 2019 ftchacadsciegiec https://doi.org/10.1021/acs.energyfuels.8b03108 2022-09-23T14:15:08Z The kinetic effects of several kinds of ionic liquids (ILs) on the formation of methane hydrate were experimentally investigated on both the macroscale and microscale levels. These ILs were 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIm]-BF4), 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm]-BF4), 1-butyl-3-methylimidazolium iodide ([BMIm]-I), and N-butyl-N-methylpyrrolidinium tetrafluoroborate ([Py14]-BF4). Formation temperature, max subcooling, induction time, and growth rate of methane gas hydrates were used to evaluate the kinetic effects of ionic liquids in a high-pressure cell and flow loop. As evaluated from the indicator of the formation temperature in the high-pressure cell, the sequence of inhibition performance of ILs was as follows: pure water < 1 wt % [EMIm]-BF4 < 1 wt % PVP < 1 wt % [BMIm]-I < 1 wt % [BMIm]-BF4 < 1 wt % [Py14]-BF4. ILs could not slow the growth rates of methane hydrate effectively and even promote the gas consumption rates irrespective of in a high-pressure cell or flow loop. RXRD spectra showed that ILs could not change the structure of methane hydrate. Cryo-scanning electron microscopy images showed that there was a porous texture of methane hydrate containing ILs. Raman spectra showed that ILs interact with the cages of methane hydrate. Report Methane hydrate Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences: GIEC OpenIR Energy & Fuels 33 2 1422 1432 |
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Open Polar |
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Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences: GIEC OpenIR |
op_collection_id |
ftchacadsciegiec |
language |
English |
topic |
DUAL FUNCTION INHIBITORS PHASE-EQUILIBRIA CO2 HYDRATE DISSOCIATION CONDITIONS INDUCTION TIME AMINO-ACIDS WATER SOLVENTS RISK CHLORIDE Energy & Fuels Engineering Chemical |
spellingShingle |
DUAL FUNCTION INHIBITORS PHASE-EQUILIBRIA CO2 HYDRATE DISSOCIATION CONDITIONS INDUCTION TIME AMINO-ACIDS WATER SOLVENTS RISK CHLORIDE Energy & Fuels Engineering Chemical Shen, Xiao-dong Zhou, Xue-bing Liang, De-qing Kinetic Effects of Ionic Liquids on Methane Hydrate |
topic_facet |
DUAL FUNCTION INHIBITORS PHASE-EQUILIBRIA CO2 HYDRATE DISSOCIATION CONDITIONS INDUCTION TIME AMINO-ACIDS WATER SOLVENTS RISK CHLORIDE Energy & Fuels Engineering Chemical |
description |
The kinetic effects of several kinds of ionic liquids (ILs) on the formation of methane hydrate were experimentally investigated on both the macroscale and microscale levels. These ILs were 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIm]-BF4), 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm]-BF4), 1-butyl-3-methylimidazolium iodide ([BMIm]-I), and N-butyl-N-methylpyrrolidinium tetrafluoroborate ([Py14]-BF4). Formation temperature, max subcooling, induction time, and growth rate of methane gas hydrates were used to evaluate the kinetic effects of ionic liquids in a high-pressure cell and flow loop. As evaluated from the indicator of the formation temperature in the high-pressure cell, the sequence of inhibition performance of ILs was as follows: pure water < 1 wt % [EMIm]-BF4 < 1 wt % PVP < 1 wt % [BMIm]-I < 1 wt % [BMIm]-BF4 < 1 wt % [Py14]-BF4. ILs could not slow the growth rates of methane hydrate effectively and even promote the gas consumption rates irrespective of in a high-pressure cell or flow loop. RXRD spectra showed that ILs could not change the structure of methane hydrate. Cryo-scanning electron microscopy images showed that there was a porous texture of methane hydrate containing ILs. Raman spectra showed that ILs interact with the cages of methane hydrate. |
format |
Report |
author |
Shen, Xiao-dong Zhou, Xue-bing Liang, De-qing |
author_facet |
Shen, Xiao-dong Zhou, Xue-bing Liang, De-qing |
author_sort |
Shen, Xiao-dong |
title |
Kinetic Effects of Ionic Liquids on Methane Hydrate |
title_short |
Kinetic Effects of Ionic Liquids on Methane Hydrate |
title_full |
Kinetic Effects of Ionic Liquids on Methane Hydrate |
title_fullStr |
Kinetic Effects of Ionic Liquids on Methane Hydrate |
title_full_unstemmed |
Kinetic Effects of Ionic Liquids on Methane Hydrate |
title_sort |
kinetic effects of ionic liquids on methane hydrate |
publisher |
AMER CHEMICAL SOC |
publishDate |
2019 |
url |
http://ir.giec.ac.cn/handle/344007/24636 https://doi.org/10.1021/acs.energyfuels.8b03108 |
genre |
Methane hydrate |
genre_facet |
Methane hydrate |
op_relation |
ENERGY & FUELS http://ir.giec.ac.cn/handle/344007/24636 doi:10.1021/acs.energyfuels.8b03108 |
op_doi |
https://doi.org/10.1021/acs.energyfuels.8b03108 |
container_title |
Energy & Fuels |
container_volume |
33 |
container_issue |
2 |
container_start_page |
1422 |
op_container_end_page |
1432 |
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1766068029466083328 |