Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework
Nitrous oxide (N2O) is an important greenhouse gas and the major source of stratospheric reactive nitrogen (NOy), an active participant in the stratospheric chemistry controlling ozone depletion. Tropospheric N2O abundances are increasing at nearly 0.3% yr-1 and this increase is expected to continue...
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ftcdlib:qt41b0c6t4 2023-05-15T14:03:27+02:00 Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework Olsen, SC McLinden, CA Prather, MJ 28771 - 28784 2001-11-27 application/pdf http://www.escholarship.org/uc/item/41b0c6t4 english eng eScholarship, University of California qt41b0c6t4 http://www.escholarship.org/uc/item/41b0c6t4 Attribution (CC BY): http://creativecommons.org/licenses/by/3.0/ CC-BY Olsen, SC; McLinden, CA; & Prather, MJ. (2001). Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework. Journal of Geophysical Research Atmospheres, 106(D22), 28771 - 28784. doi:10.1029/2001JD000559. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/41b0c6t4 article 2001 ftcdlib https://doi.org/10.1029/2001JD000559 2018-11-16T23:51:57Z Nitrous oxide (N2O) is an important greenhouse gas and the major source of stratospheric reactive nitrogen (NOy), an active participant in the stratospheric chemistry controlling ozone depletion. Tropospheric N2O abundances are increasing at nearly 0.3% yr-1 and this increase is expected to continue in the near future as are direct stratospheric NOy perturbations, for example, from aircraft. In order to test and gain confidence in three-dimensional (3-D) model simulations of the stratospheric N2O-NOy system, a simplified photochemistry for N2O and NOy is developed for use in chemistry transport models (CTMs). This chemical model allows for extensive CTM simulations focusing on uncertainties in chemistry and transport. We compare 3-D model simulations with measurements and evaluate the effect on N2O and NOy of potential errors in model transport, in column and local ozone, and in stratospheric temperatures. For example, with the three different 3-D wind fields used here, modeled N2O lifetimes vary from 173 to 115 years, and the unrealistically long lifetimes produce clear errors in equatorial N2O profiles. The impact of Antarctic denitrification and an in situ atmospheric N2O source are also evaluated. The modeled N2O and NOy distributions are obviously sensitive to model transport, particularly the strength of tropical upwelling in the stratosphere. Midlatitude, lower-stratospheric NOy/N2O correlations, including seasonal amplitudes, are well reproduced by the standard model when denitrification is included. These correlations are sensitive to changes in stratospheric chemistry but relatively insensitive to model transport. The lower stratospheric NOy/N2O correlation slope gives the correct net NOy production of about 0.5 Tg N yr-1 (i.e., the cross-tropopause flux as in the Plumb-Ko relation) only when N2O values from 250 to 310 ppb are used. As a consequence, the Synoz calibration of the flux of O3 from the stratosphere to the troposphere needs to be corrected to 550 ± 140 Tg O3 yr-1. Copyright 2001 by the American Geophysical Union. Article in Journal/Newspaper Antarc* Antarctic University of California: eScholarship Antarctic Journal of Geophysical Research: Atmospheres 106 D22 28771 28784 |
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Open Polar |
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University of California: eScholarship |
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ftcdlib |
language |
English |
description |
Nitrous oxide (N2O) is an important greenhouse gas and the major source of stratospheric reactive nitrogen (NOy), an active participant in the stratospheric chemistry controlling ozone depletion. Tropospheric N2O abundances are increasing at nearly 0.3% yr-1 and this increase is expected to continue in the near future as are direct stratospheric NOy perturbations, for example, from aircraft. In order to test and gain confidence in three-dimensional (3-D) model simulations of the stratospheric N2O-NOy system, a simplified photochemistry for N2O and NOy is developed for use in chemistry transport models (CTMs). This chemical model allows for extensive CTM simulations focusing on uncertainties in chemistry and transport. We compare 3-D model simulations with measurements and evaluate the effect on N2O and NOy of potential errors in model transport, in column and local ozone, and in stratospheric temperatures. For example, with the three different 3-D wind fields used here, modeled N2O lifetimes vary from 173 to 115 years, and the unrealistically long lifetimes produce clear errors in equatorial N2O profiles. The impact of Antarctic denitrification and an in situ atmospheric N2O source are also evaluated. The modeled N2O and NOy distributions are obviously sensitive to model transport, particularly the strength of tropical upwelling in the stratosphere. Midlatitude, lower-stratospheric NOy/N2O correlations, including seasonal amplitudes, are well reproduced by the standard model when denitrification is included. These correlations are sensitive to changes in stratospheric chemistry but relatively insensitive to model transport. The lower stratospheric NOy/N2O correlation slope gives the correct net NOy production of about 0.5 Tg N yr-1 (i.e., the cross-tropopause flux as in the Plumb-Ko relation) only when N2O values from 250 to 310 ppb are used. As a consequence, the Synoz calibration of the flux of O3 from the stratosphere to the troposphere needs to be corrected to 550 ± 140 Tg O3 yr-1. Copyright 2001 by the American Geophysical Union. |
format |
Article in Journal/Newspaper |
author |
Olsen, SC McLinden, CA Prather, MJ |
spellingShingle |
Olsen, SC McLinden, CA Prather, MJ Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework |
author_facet |
Olsen, SC McLinden, CA Prather, MJ |
author_sort |
Olsen, SC |
title |
Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework |
title_short |
Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework |
title_full |
Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework |
title_fullStr |
Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework |
title_full_unstemmed |
Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework |
title_sort |
stratospheric n 2 o-no y system: testing uncertainties in a three-dimensional framework |
publisher |
eScholarship, University of California |
publishDate |
2001 |
url |
http://www.escholarship.org/uc/item/41b0c6t4 |
op_coverage |
28771 - 28784 |
geographic |
Antarctic |
geographic_facet |
Antarctic |
genre |
Antarc* Antarctic |
genre_facet |
Antarc* Antarctic |
op_source |
Olsen, SC; McLinden, CA; & Prather, MJ. (2001). Stratospheric N 2 O-NO y system: Testing uncertainties in a three-dimensional framework. Journal of Geophysical Research Atmospheres, 106(D22), 28771 - 28784. doi:10.1029/2001JD000559. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/41b0c6t4 |
op_relation |
qt41b0c6t4 http://www.escholarship.org/uc/item/41b0c6t4 |
op_rights |
Attribution (CC BY): http://creativecommons.org/licenses/by/3.0/ |
op_rightsnorm |
CC-BY |
op_doi |
https://doi.org/10.1029/2001JD000559 |
container_title |
Journal of Geophysical Research: Atmospheres |
container_volume |
106 |
container_issue |
D22 |
container_start_page |
28771 |
op_container_end_page |
28784 |
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1766274115119874048 |