QuEChERS extraction for multi-residue analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological samples.
International audience In this study, a fast and rugged method is presented for the analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological tissues using a simple Quick, Easy, Cheap, Efficient, Rugged and Safe (QuEChERS) extraction and a clean-up by Gel Permeation Chromatography (GPC) and silica Sol...
Published in: | Talanta |
---|---|
Main Authors: | , , , , , |
Other Authors: | , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
HAL CCSD
2017
|
Subjects: | |
Online Access: | https://hal-riip.archives-ouvertes.fr/pasteur-01535228 https://doi.org/10.1016/j.talanta.2016.12.080 |
id |
ftccsdartic:oai:HAL:pasteur-01535228v1 |
---|---|
record_format |
openpolar |
spelling |
ftccsdartic:oai:HAL:pasteur-01535228v1 2023-05-15T15:31:49+02:00 QuEChERS extraction for multi-residue analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological samples. Cloutier, Pierre-Luc Fortin, Frédérik Groleau, Paule Emilie Brousseau, Pauline Fournier, Michel Desrosiers, Mélanie Institut Armand Frappier (INRS-IAF) Institut National de la Recherche Scientifique Québec (INRS)-Réseau International des Instituts Pasteur (RIIP) Centre d'expertise en analyse environnementale du Québec 2017-04-01 https://hal-riip.archives-ouvertes.fr/pasteur-01535228 https://doi.org/10.1016/j.talanta.2016.12.080 en eng HAL CCSD Elsevier info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2016.12.080 info:eu-repo/semantics/altIdentifier/pmid/28153263 pasteur-01535228 https://hal-riip.archives-ouvertes.fr/pasteur-01535228 doi:10.1016/j.talanta.2016.12.080 PUBMED: 28153263 ISSN: 0039-9140 Talanta https://hal-riip.archives-ouvertes.fr/pasteur-01535228 Talanta, Elsevier, 2017, 165, pp.332-338. ⟨10.1016/j.talanta.2016.12.080⟩ Polychlorinated biphenyls (PCBs) Polychlorinated dibenzodioxins and dibenzofurans (PCDD/Fs) Cheap Easy Efficient Environmental biomonitoring Gel permeation chromatography (GPC) Polybrominated diphenyl ethers (PBDEs) Polycyclic aromatic hydrocarbons (PAHs) Quick Rugged and Safe (QuEChERS) [SDV]Life Sciences [q-bio] [SDV.BIO]Life Sciences [q-bio]/Biotechnology [SHS.ENVIR]Humanities and Social Sciences/Environmental studies info:eu-repo/semantics/article Journal articles 2017 ftccsdartic https://doi.org/10.1016/j.talanta.2016.12.080 2020-12-25T10:35:34Z International audience In this study, a fast and rugged method is presented for the analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological tissues using a simple Quick, Easy, Cheap, Efficient, Rugged and Safe (QuEChERS) extraction and a clean-up by Gel Permeation Chromatography (GPC) and silica Solid Phase Extraction (SPE). Development was performed on blue mussels (Mytilus edulis) and Atlantic salmon (Salmo salar) for evaluation of two ranges of lipid and water content of biological tissues. Statistical validation was performed with Atlantic salmon samples. Forty-five PAHs were analyzed including the priority list of the US EPA and the European Union with 41 PCBs, 24 PBDEs and 17 PCDD/Fs. Instrumental analyses were performed on Gas Chromatography - High Resolution Mass Spectrometry (GC-HRMS). Accuracy was evaluated for PCBs and PCDD/Fs with a certified reference material furnished by the National Research Council Canada (NRCC) and also compared with results obtained by the conventional Soxhlet extraction. Statistical validation showed recoveries for PCBs, PAHs, PBDEs and PCDD/Fs close to 100% with average Relative Standard Deviation (RSD) lower than 10% and internal standard recoveries in the range of 70% with average RSD ranging from 5-15%. Average calculated Method Detection Limits (MDLs) were lower than 0.05μg/Kg for PCBs, 0.2μg/Kg for PAHs and PBDEs and 1ng/Kg for PCDD/Fs. The method is a faster and cheaper alternative to the time-consuming conventional method that has been used in most environmental laboratories. Article in Journal/Newspaper Atlantic salmon Salmo salar Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Canada Talanta 165 332 338 |
institution |
Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
Polychlorinated biphenyls (PCBs) Polychlorinated dibenzodioxins and dibenzofurans (PCDD/Fs) Cheap Easy Efficient Environmental biomonitoring Gel permeation chromatography (GPC) Polybrominated diphenyl ethers (PBDEs) Polycyclic aromatic hydrocarbons (PAHs) Quick Rugged and Safe (QuEChERS) [SDV]Life Sciences [q-bio] [SDV.BIO]Life Sciences [q-bio]/Biotechnology [SHS.ENVIR]Humanities and Social Sciences/Environmental studies |
spellingShingle |
Polychlorinated biphenyls (PCBs) Polychlorinated dibenzodioxins and dibenzofurans (PCDD/Fs) Cheap Easy Efficient Environmental biomonitoring Gel permeation chromatography (GPC) Polybrominated diphenyl ethers (PBDEs) Polycyclic aromatic hydrocarbons (PAHs) Quick Rugged and Safe (QuEChERS) [SDV]Life Sciences [q-bio] [SDV.BIO]Life Sciences [q-bio]/Biotechnology [SHS.ENVIR]Humanities and Social Sciences/Environmental studies Cloutier, Pierre-Luc Fortin, Frédérik Groleau, Paule Emilie Brousseau, Pauline Fournier, Michel Desrosiers, Mélanie QuEChERS extraction for multi-residue analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological samples. |
topic_facet |
Polychlorinated biphenyls (PCBs) Polychlorinated dibenzodioxins and dibenzofurans (PCDD/Fs) Cheap Easy Efficient Environmental biomonitoring Gel permeation chromatography (GPC) Polybrominated diphenyl ethers (PBDEs) Polycyclic aromatic hydrocarbons (PAHs) Quick Rugged and Safe (QuEChERS) [SDV]Life Sciences [q-bio] [SDV.BIO]Life Sciences [q-bio]/Biotechnology [SHS.ENVIR]Humanities and Social Sciences/Environmental studies |
description |
International audience In this study, a fast and rugged method is presented for the analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological tissues using a simple Quick, Easy, Cheap, Efficient, Rugged and Safe (QuEChERS) extraction and a clean-up by Gel Permeation Chromatography (GPC) and silica Solid Phase Extraction (SPE). Development was performed on blue mussels (Mytilus edulis) and Atlantic salmon (Salmo salar) for evaluation of two ranges of lipid and water content of biological tissues. Statistical validation was performed with Atlantic salmon samples. Forty-five PAHs were analyzed including the priority list of the US EPA and the European Union with 41 PCBs, 24 PBDEs and 17 PCDD/Fs. Instrumental analyses were performed on Gas Chromatography - High Resolution Mass Spectrometry (GC-HRMS). Accuracy was evaluated for PCBs and PCDD/Fs with a certified reference material furnished by the National Research Council Canada (NRCC) and also compared with results obtained by the conventional Soxhlet extraction. Statistical validation showed recoveries for PCBs, PAHs, PBDEs and PCDD/Fs close to 100% with average Relative Standard Deviation (RSD) lower than 10% and internal standard recoveries in the range of 70% with average RSD ranging from 5-15%. Average calculated Method Detection Limits (MDLs) were lower than 0.05μg/Kg for PCBs, 0.2μg/Kg for PAHs and PBDEs and 1ng/Kg for PCDD/Fs. The method is a faster and cheaper alternative to the time-consuming conventional method that has been used in most environmental laboratories. |
author2 |
Institut Armand Frappier (INRS-IAF) Institut National de la Recherche Scientifique Québec (INRS)-Réseau International des Instituts Pasteur (RIIP) Centre d'expertise en analyse environnementale du Québec |
format |
Article in Journal/Newspaper |
author |
Cloutier, Pierre-Luc Fortin, Frédérik Groleau, Paule Emilie Brousseau, Pauline Fournier, Michel Desrosiers, Mélanie |
author_facet |
Cloutier, Pierre-Luc Fortin, Frédérik Groleau, Paule Emilie Brousseau, Pauline Fournier, Michel Desrosiers, Mélanie |
author_sort |
Cloutier, Pierre-Luc |
title |
QuEChERS extraction for multi-residue analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological samples. |
title_short |
QuEChERS extraction for multi-residue analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological samples. |
title_full |
QuEChERS extraction for multi-residue analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological samples. |
title_fullStr |
QuEChERS extraction for multi-residue analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological samples. |
title_full_unstemmed |
QuEChERS extraction for multi-residue analysis of PCBs, PAHs, PBDEs and PCDD/Fs in biological samples. |
title_sort |
quechers extraction for multi-residue analysis of pcbs, pahs, pbdes and pcdd/fs in biological samples. |
publisher |
HAL CCSD |
publishDate |
2017 |
url |
https://hal-riip.archives-ouvertes.fr/pasteur-01535228 https://doi.org/10.1016/j.talanta.2016.12.080 |
geographic |
Canada |
geographic_facet |
Canada |
genre |
Atlantic salmon Salmo salar |
genre_facet |
Atlantic salmon Salmo salar |
op_source |
ISSN: 0039-9140 Talanta https://hal-riip.archives-ouvertes.fr/pasteur-01535228 Talanta, Elsevier, 2017, 165, pp.332-338. ⟨10.1016/j.talanta.2016.12.080⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2016.12.080 info:eu-repo/semantics/altIdentifier/pmid/28153263 pasteur-01535228 https://hal-riip.archives-ouvertes.fr/pasteur-01535228 doi:10.1016/j.talanta.2016.12.080 PUBMED: 28153263 |
op_doi |
https://doi.org/10.1016/j.talanta.2016.12.080 |
container_title |
Talanta |
container_volume |
165 |
container_start_page |
332 |
op_container_end_page |
338 |
_version_ |
1766362323734233088 |