ELECTRONIC STRUCTURE OF THE IRON IN DEOXIGENATED MYOGLOBIN FROM MÖSSBAUER SPECTROSCOPY
New measurements of the temperature dependence of the quadrupole splitting of iron in deoxigenated sperm whale myoglobin are reported. The energy separation of the low lying electronic terms of the iron is obtained by a direct least squares fit to the temperature variation of the electric field grad...
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Online Access: | https://hal.science/jpa-00215822 https://hal.science/jpa-00215822/document https://hal.science/jpa-00215822/file/ajp-jphyscol197435C665.pdf https://doi.org/10.1051/jphyscol:1974665 |
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ftccsdartic:oai:HAL:jpa-00215822v1 2023-11-12T04:26:48+01:00 ELECTRONIC STRUCTURE OF THE IRON IN DEOXIGENATED MYOGLOBIN FROM MÖSSBAUER SPECTROSCOPY Eicher, H. Parak, F. Bade, D. Tejada, J. 1974 https://hal.science/jpa-00215822 https://hal.science/jpa-00215822/document https://hal.science/jpa-00215822/file/ajp-jphyscol197435C665.pdf https://doi.org/10.1051/jphyscol:1974665 en eng HAL CCSD info:eu-repo/semantics/altIdentifier/doi/10.1051/jphyscol:1974665 jpa-00215822 https://hal.science/jpa-00215822 https://hal.science/jpa-00215822/document https://hal.science/jpa-00215822/file/ajp-jphyscol197435C665.pdf doi:10.1051/jphyscol:1974665 info:eu-repo/semantics/OpenAccess Journal de Physique Colloques https://hal.science/jpa-00215822 Journal de Physique Colloques, 1974, 35 (C6), pp.C6-363-C6-366. ⟨10.1051/jphyscol:1974665⟩ [PHYS.HIST]Physics [physics]/Physics archives info:eu-repo/semantics/article Journal articles 1974 ftccsdartic https://doi.org/10.1051/jphyscol:1974665 2023-10-21T23:47:36Z New measurements of the temperature dependence of the quadrupole splitting of iron in deoxigenated sperm whale myoglobin are reported. The energy separation of the low lying electronic terms of the iron is obtained by a direct least squares fit to the temperature variation of the electric field gradient. Taking the 5B2 term as the reference level (E = 0) the following energy scheme was deduced : lAl(60 cm-1) 5E(106 cm-1) 3E(809 cm-1) D(- 298 cm-1) yielding η(77 K) = - 13.3. These results are consistent with Mössbauer spectra of the iron in single crystals of deoxigenated myoglobin recently reported by Gonser et al. Article in Journal/Newspaper Sperm whale Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
institution |
Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
[PHYS.HIST]Physics [physics]/Physics archives |
spellingShingle |
[PHYS.HIST]Physics [physics]/Physics archives Eicher, H. Parak, F. Bade, D. Tejada, J. ELECTRONIC STRUCTURE OF THE IRON IN DEOXIGENATED MYOGLOBIN FROM MÖSSBAUER SPECTROSCOPY |
topic_facet |
[PHYS.HIST]Physics [physics]/Physics archives |
description |
New measurements of the temperature dependence of the quadrupole splitting of iron in deoxigenated sperm whale myoglobin are reported. The energy separation of the low lying electronic terms of the iron is obtained by a direct least squares fit to the temperature variation of the electric field gradient. Taking the 5B2 term as the reference level (E = 0) the following energy scheme was deduced : lAl(60 cm-1) 5E(106 cm-1) 3E(809 cm-1) D(- 298 cm-1) yielding η(77 K) = - 13.3. These results are consistent with Mössbauer spectra of the iron in single crystals of deoxigenated myoglobin recently reported by Gonser et al. |
format |
Article in Journal/Newspaper |
author |
Eicher, H. Parak, F. Bade, D. Tejada, J. |
author_facet |
Eicher, H. Parak, F. Bade, D. Tejada, J. |
author_sort |
Eicher, H. |
title |
ELECTRONIC STRUCTURE OF THE IRON IN DEOXIGENATED MYOGLOBIN FROM MÖSSBAUER SPECTROSCOPY |
title_short |
ELECTRONIC STRUCTURE OF THE IRON IN DEOXIGENATED MYOGLOBIN FROM MÖSSBAUER SPECTROSCOPY |
title_full |
ELECTRONIC STRUCTURE OF THE IRON IN DEOXIGENATED MYOGLOBIN FROM MÖSSBAUER SPECTROSCOPY |
title_fullStr |
ELECTRONIC STRUCTURE OF THE IRON IN DEOXIGENATED MYOGLOBIN FROM MÖSSBAUER SPECTROSCOPY |
title_full_unstemmed |
ELECTRONIC STRUCTURE OF THE IRON IN DEOXIGENATED MYOGLOBIN FROM MÖSSBAUER SPECTROSCOPY |
title_sort |
electronic structure of the iron in deoxigenated myoglobin from mössbauer spectroscopy |
publisher |
HAL CCSD |
publishDate |
1974 |
url |
https://hal.science/jpa-00215822 https://hal.science/jpa-00215822/document https://hal.science/jpa-00215822/file/ajp-jphyscol197435C665.pdf https://doi.org/10.1051/jphyscol:1974665 |
genre |
Sperm whale |
genre_facet |
Sperm whale |
op_source |
Journal de Physique Colloques https://hal.science/jpa-00215822 Journal de Physique Colloques, 1974, 35 (C6), pp.C6-363-C6-366. ⟨10.1051/jphyscol:1974665⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1051/jphyscol:1974665 jpa-00215822 https://hal.science/jpa-00215822 https://hal.science/jpa-00215822/document https://hal.science/jpa-00215822/file/ajp-jphyscol197435C665.pdf doi:10.1051/jphyscol:1974665 |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1051/jphyscol:1974665 |
_version_ |
1782340651335024640 |