Iron in Nepheline: Crystal Chemical Features and Petrological Applications
International audience Nepheline is a nominally anhydrous aluminosilicate that typically contains an impurity of ferric iron replacing aluminum in tetrahedral sites. However, previous researchers noted the constant presence of ferrous iron in the chemical composition of nepheline from the rocks of t...
Published in: | Minerals |
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Main Authors: | , , , , , , |
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Format: | Article in Journal/Newspaper |
Language: | English |
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HAL CCSD
2022
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Online Access: | https://hal-insu.archives-ouvertes.fr/insu-03883099 https://hal-insu.archives-ouvertes.fr/insu-03883099/document https://hal-insu.archives-ouvertes.fr/insu-03883099/file/minerals-12-01257-v2.pdf https://doi.org/10.3390/min12101257 |
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Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
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English |
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[SDU.STU]Sciences of the Universe [physics]/Earth Sciences [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry [SDU.STU.MI]Sciences of the Universe [physics]/Earth Sciences/Mineralogy |
spellingShingle |
[SDU.STU]Sciences of the Universe [physics]/Earth Sciences [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry [SDU.STU.MI]Sciences of the Universe [physics]/Earth Sciences/Mineralogy Mikhailova, Julia Aksenov, Sergey Pakhomovsky, Yakov Moine, Bertrand Dusséaux, Camille Vaitieva, Yulia Voronin, Mikhail Iron in Nepheline: Crystal Chemical Features and Petrological Applications |
topic_facet |
[SDU.STU]Sciences of the Universe [physics]/Earth Sciences [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry [SDU.STU.MI]Sciences of the Universe [physics]/Earth Sciences/Mineralogy |
description |
International audience Nepheline is a nominally anhydrous aluminosilicate that typically contains an impurity of ferric iron replacing aluminum in tetrahedral sites. However, previous researchers noted the constant presence of ferrous iron in the chemical composition of nepheline from the rocks of the Khibiny and Lovozero massifs (Kola Peninsula, Russia). We have carried out microprobe, spectroscopic, chemical and crystal chemical studies of nepheline from the Lovozero massif. We have established the presence of molecular water in nepheline, and also that the incorporation of ferrous iron into nepheline crystal structure is associated with the simultaneous increasing of the coordination number from four to five (or six) due to the inclusion of the ‘additional’ water molecules that form point [FeO4(H2O)n]-defects (where n = 1, 2) in the tetrahedral framework. The nepheline iron content is closely related to the presence of small needle-like aegirine inclusions. The total iron content in nepheline saturated with aegirine needles is approximately an order of magnitude lower than in nepheline free from aegirine inclusions. Most likely the aegirine inclusions in nepheline are formed as a result of the decomposition of the nepheline–“iron nepheline” solid solution. We propose that this process is triggered by the oxidation of ferrous iron in the crystal structure of nepheline. |
author2 |
Laboratoire Magmas et Volcans (LMV) Institut national des sciences de l'Univers (INSU - CNRS)-Institut de Recherche pour le Développement et la société-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Observatoire de Physique du Globe de Clermont-Ferrand (OPGC) Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA) Institut des Sciences de la Terre (ISTerre) Institut national des sciences de l'Univers (INSU - CNRS)-Institut de recherche pour le développement IRD : UR219-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Gustave Eiffel-Université Grenoble Alpes (UGA) ANR-20-CE01-0020,H2Kola,Sources, distribution et flux d'hydrogène (H2) et des gaz associés dans les complexes alcalins (exemple de Khibiny et Lovozero, péninsule de Kola, Russie): conséquences métallogéniques et environnementales(2020) |
format |
Article in Journal/Newspaper |
author |
Mikhailova, Julia Aksenov, Sergey Pakhomovsky, Yakov Moine, Bertrand Dusséaux, Camille Vaitieva, Yulia Voronin, Mikhail |
author_facet |
Mikhailova, Julia Aksenov, Sergey Pakhomovsky, Yakov Moine, Bertrand Dusséaux, Camille Vaitieva, Yulia Voronin, Mikhail |
author_sort |
Mikhailova, Julia |
title |
Iron in Nepheline: Crystal Chemical Features and Petrological Applications |
title_short |
Iron in Nepheline: Crystal Chemical Features and Petrological Applications |
title_full |
Iron in Nepheline: Crystal Chemical Features and Petrological Applications |
title_fullStr |
Iron in Nepheline: Crystal Chemical Features and Petrological Applications |
title_full_unstemmed |
Iron in Nepheline: Crystal Chemical Features and Petrological Applications |
title_sort |
iron in nepheline: crystal chemical features and petrological applications |
publisher |
HAL CCSD |
publishDate |
2022 |
url |
https://hal-insu.archives-ouvertes.fr/insu-03883099 https://hal-insu.archives-ouvertes.fr/insu-03883099/document https://hal-insu.archives-ouvertes.fr/insu-03883099/file/minerals-12-01257-v2.pdf https://doi.org/10.3390/min12101257 |
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ENVELOPE(33.210,33.210,67.679,67.679) ENVELOPE(35.016,35.016,68.006,68.006) |
geographic |
Kola Peninsula Khibiny Lovozero |
geographic_facet |
Kola Peninsula Khibiny Lovozero |
genre |
kola peninsula |
genre_facet |
kola peninsula |
op_source |
ISSN: 2075-163X Minerals https://hal-insu.archives-ouvertes.fr/insu-03883099 Minerals, 2022, 12 (10), pp.1257. ⟨10.3390/min12101257⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.3390/min12101257 insu-03883099 https://hal-insu.archives-ouvertes.fr/insu-03883099 https://hal-insu.archives-ouvertes.fr/insu-03883099/document https://hal-insu.archives-ouvertes.fr/insu-03883099/file/minerals-12-01257-v2.pdf doi:10.3390/min12101257 |
op_rights |
http://creativecommons.org/licenses/by/ info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.3390/min12101257 |
container_title |
Minerals |
container_volume |
12 |
container_issue |
10 |
container_start_page |
1257 |
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1772183958419668992 |
spelling |
ftccsdartic:oai:HAL:insu-03883099v1 2023-07-23T04:20:10+02:00 Iron in Nepheline: Crystal Chemical Features and Petrological Applications Mikhailova, Julia Aksenov, Sergey Pakhomovsky, Yakov Moine, Bertrand Dusséaux, Camille Vaitieva, Yulia Voronin, Mikhail Laboratoire Magmas et Volcans (LMV) Institut national des sciences de l'Univers (INSU - CNRS)-Institut de Recherche pour le Développement et la société-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Observatoire de Physique du Globe de Clermont-Ferrand (OPGC) Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA) Institut des Sciences de la Terre (ISTerre) Institut national des sciences de l'Univers (INSU - CNRS)-Institut de recherche pour le développement IRD : UR219-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Gustave Eiffel-Université Grenoble Alpes (UGA) ANR-20-CE01-0020,H2Kola,Sources, distribution et flux d'hydrogène (H2) et des gaz associés dans les complexes alcalins (exemple de Khibiny et Lovozero, péninsule de Kola, Russie): conséquences métallogéniques et environnementales(2020) 2022-10 https://hal-insu.archives-ouvertes.fr/insu-03883099 https://hal-insu.archives-ouvertes.fr/insu-03883099/document https://hal-insu.archives-ouvertes.fr/insu-03883099/file/minerals-12-01257-v2.pdf https://doi.org/10.3390/min12101257 en eng HAL CCSD MDPI info:eu-repo/semantics/altIdentifier/doi/10.3390/min12101257 insu-03883099 https://hal-insu.archives-ouvertes.fr/insu-03883099 https://hal-insu.archives-ouvertes.fr/insu-03883099/document https://hal-insu.archives-ouvertes.fr/insu-03883099/file/minerals-12-01257-v2.pdf doi:10.3390/min12101257 http://creativecommons.org/licenses/by/ info:eu-repo/semantics/OpenAccess ISSN: 2075-163X Minerals https://hal-insu.archives-ouvertes.fr/insu-03883099 Minerals, 2022, 12 (10), pp.1257. ⟨10.3390/min12101257⟩ [SDU.STU]Sciences of the Universe [physics]/Earth Sciences [SDU.STU.GC]Sciences of the Universe [physics]/Earth Sciences/Geochemistry [SDU.STU.MI]Sciences of the Universe [physics]/Earth Sciences/Mineralogy info:eu-repo/semantics/article Journal articles 2022 ftccsdartic https://doi.org/10.3390/min12101257 2023-07-01T23:36:49Z International audience Nepheline is a nominally anhydrous aluminosilicate that typically contains an impurity of ferric iron replacing aluminum in tetrahedral sites. However, previous researchers noted the constant presence of ferrous iron in the chemical composition of nepheline from the rocks of the Khibiny and Lovozero massifs (Kola Peninsula, Russia). We have carried out microprobe, spectroscopic, chemical and crystal chemical studies of nepheline from the Lovozero massif. We have established the presence of molecular water in nepheline, and also that the incorporation of ferrous iron into nepheline crystal structure is associated with the simultaneous increasing of the coordination number from four to five (or six) due to the inclusion of the ‘additional’ water molecules that form point [FeO4(H2O)n]-defects (where n = 1, 2) in the tetrahedral framework. The nepheline iron content is closely related to the presence of small needle-like aegirine inclusions. The total iron content in nepheline saturated with aegirine needles is approximately an order of magnitude lower than in nepheline free from aegirine inclusions. Most likely the aegirine inclusions in nepheline are formed as a result of the decomposition of the nepheline–“iron nepheline” solid solution. We propose that this process is triggered by the oxidation of ferrous iron in the crystal structure of nepheline. Article in Journal/Newspaper kola peninsula Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Kola Peninsula Khibiny ENVELOPE(33.210,33.210,67.679,67.679) Lovozero ENVELOPE(35.016,35.016,68.006,68.006) Minerals 12 10 1257 |