Year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites
International audience Multiple year-round records of bulk and size-segregated compositions of aerosol were obtained at the coastal Dumont d'Urville (DDU) and inland Concordia sites located in East Antarctica. They document the sea-salt aerosol load and composition including, for the first time...
Published in: | Journal of Geophysical Research: Atmospheres |
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Main Authors: | , , , |
Other Authors: | , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
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HAL CCSD
2016
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Online Access: | https://hal-insu.archives-ouvertes.fr/insu-01351746 https://hal-insu.archives-ouvertes.fr/insu-01351746/document https://hal-insu.archives-ouvertes.fr/insu-01351746/file/2015JD024066.pdf https://doi.org/10.1002/2015JD024066 |
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ftccsdartic:oai:HAL:insu-01351746v1 |
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Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
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ftccsdartic |
language |
English |
topic |
[SDE]Environmental Sciences |
spellingShingle |
[SDE]Environmental Sciences Legrand, Michel R. Xin, Yang Preunkert, Susanne Theys, Nicolas Year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites |
topic_facet |
[SDE]Environmental Sciences |
description |
International audience Multiple year-round records of bulk and size-segregated compositions of aerosol were obtained at the coastal Dumont d'Urville (DDU) and inland Concordia sites located in East Antarctica. They document the sea-salt aerosol load and composition including, for the first time in Antarctica, the bromide depletion of sea-salt aerosol relative to sodium with respect to seawater. In parallel, measurements of bromide trapped in mist chambers and denuder tubes were done to investigate the concentrations of gaseous inorganic bromine species. These data are compared to simulations done with an off-line chemistry transport model, coupled with a full tropospheric bromine chemistry scheme and a process-based sea-salt production module that includes both sea-ice-sourced and open-ocean-sourced aerosol emissions. Observed and simulated sea-salt concentrations sometime differ by up to a factor of 2 to 3, particularly at DDU possibly due to local wind pattern. In spite of these discrepancies, both at coastal and inland Antarctica, the dominance of sea-ice-related processes with respect to open ocean emissions for the sea-salt aerosol load in winter is confirmed. For summer, observations and simulations point out sea salt as the main source of gaseous inorganic bromine species. Investigations of bromide in snow pit samples do not support the importance of snowpack bromine emissions over the Antarctic Plateau. To evaluate the overall importance of the bromine chemistry over East Antarctica, BrO simulations were also discussed with respect data derived from GOME-2 satellite observations over Antarctica. |
author2 |
Laboratoire de glaciologie et géophysique de l'environnement (LGGE) Observatoire des Sciences de l'Univers de Grenoble (OSUG ) Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes 2016-2019 (UGA 2016-2019 )-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes 2016-2019 (UGA 2016-2019 )-Centre National de la Recherche Scientifique (CNRS) Natural Environment Research Council (NERC) Belgian Institute for Space Aeronomy / Institut d'Aéronomie Spatiale de Belgique (BIRA-IASB) |
format |
Article in Journal/Newspaper |
author |
Legrand, Michel R. Xin, Yang Preunkert, Susanne Theys, Nicolas |
author_facet |
Legrand, Michel R. Xin, Yang Preunkert, Susanne Theys, Nicolas |
author_sort |
Legrand, Michel R. |
title |
Year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites |
title_short |
Year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites |
title_full |
Year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites |
title_fullStr |
Year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites |
title_full_unstemmed |
Year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites |
title_sort |
year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (dumont d'urville) and central (concordia) east antarctic sites |
publisher |
HAL CCSD |
publishDate |
2016 |
url |
https://hal-insu.archives-ouvertes.fr/insu-01351746 https://hal-insu.archives-ouvertes.fr/insu-01351746/document https://hal-insu.archives-ouvertes.fr/insu-01351746/file/2015JD024066.pdf https://doi.org/10.1002/2015JD024066 |
long_lat |
ENVELOPE(140.017,140.017,-66.667,-66.667) ENVELOPE(140.013,140.013,-66.667,-66.667) |
geographic |
Antarctic Dumont d'Urville Dumont-d'Urville East Antarctica The Antarctic |
geographic_facet |
Antarctic Dumont d'Urville Dumont-d'Urville East Antarctica The Antarctic |
genre |
Antarc* Antarctic Antarctica East Antarctica Sea ice |
genre_facet |
Antarc* Antarctic Antarctica East Antarctica Sea ice |
op_source |
ISSN: 2169-897X EISSN: 2169-8996 Journal of Geophysical Research: Atmospheres https://hal-insu.archives-ouvertes.fr/insu-01351746 Journal of Geophysical Research: Atmospheres, American Geophysical Union, 2016, 121 (2), pp.997-1023. ⟨10.1002/2015JD024066⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1002/2015JD024066 insu-01351746 https://hal-insu.archives-ouvertes.fr/insu-01351746 https://hal-insu.archives-ouvertes.fr/insu-01351746/document https://hal-insu.archives-ouvertes.fr/insu-01351746/file/2015JD024066.pdf doi:10.1002/2015JD024066 |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1002/2015JD024066 |
container_title |
Journal of Geophysical Research: Atmospheres |
container_volume |
121 |
container_issue |
2 |
container_start_page |
997 |
op_container_end_page |
1023 |
_version_ |
1766264163982639104 |
spelling |
ftccsdartic:oai:HAL:insu-01351746v1 2023-05-15T13:56:37+02:00 Year-round records of sea salt, gaseous, and particulate inorganic bromine in the atmospheric boundary layer at coastal (Dumont d'Urville) and central (Concordia) East Antarctic sites Legrand, Michel R. Xin, Yang Preunkert, Susanne Theys, Nicolas Laboratoire de glaciologie et géophysique de l'environnement (LGGE) Observatoire des Sciences de l'Univers de Grenoble (OSUG ) Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes 2016-2019 (UGA 2016-2019 )-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes 2016-2019 (UGA 2016-2019 )-Centre National de la Recherche Scientifique (CNRS) Natural Environment Research Council (NERC) Belgian Institute for Space Aeronomy / Institut d'Aéronomie Spatiale de Belgique (BIRA-IASB) 2016-01 https://hal-insu.archives-ouvertes.fr/insu-01351746 https://hal-insu.archives-ouvertes.fr/insu-01351746/document https://hal-insu.archives-ouvertes.fr/insu-01351746/file/2015JD024066.pdf https://doi.org/10.1002/2015JD024066 en eng HAL CCSD American Geophysical Union info:eu-repo/semantics/altIdentifier/doi/10.1002/2015JD024066 insu-01351746 https://hal-insu.archives-ouvertes.fr/insu-01351746 https://hal-insu.archives-ouvertes.fr/insu-01351746/document https://hal-insu.archives-ouvertes.fr/insu-01351746/file/2015JD024066.pdf doi:10.1002/2015JD024066 info:eu-repo/semantics/OpenAccess ISSN: 2169-897X EISSN: 2169-8996 Journal of Geophysical Research: Atmospheres https://hal-insu.archives-ouvertes.fr/insu-01351746 Journal of Geophysical Research: Atmospheres, American Geophysical Union, 2016, 121 (2), pp.997-1023. ⟨10.1002/2015JD024066⟩ [SDE]Environmental Sciences info:eu-repo/semantics/article Journal articles 2016 ftccsdartic https://doi.org/10.1002/2015JD024066 2021-11-07T00:11:43Z International audience Multiple year-round records of bulk and size-segregated compositions of aerosol were obtained at the coastal Dumont d'Urville (DDU) and inland Concordia sites located in East Antarctica. They document the sea-salt aerosol load and composition including, for the first time in Antarctica, the bromide depletion of sea-salt aerosol relative to sodium with respect to seawater. In parallel, measurements of bromide trapped in mist chambers and denuder tubes were done to investigate the concentrations of gaseous inorganic bromine species. These data are compared to simulations done with an off-line chemistry transport model, coupled with a full tropospheric bromine chemistry scheme and a process-based sea-salt production module that includes both sea-ice-sourced and open-ocean-sourced aerosol emissions. Observed and simulated sea-salt concentrations sometime differ by up to a factor of 2 to 3, particularly at DDU possibly due to local wind pattern. In spite of these discrepancies, both at coastal and inland Antarctica, the dominance of sea-ice-related processes with respect to open ocean emissions for the sea-salt aerosol load in winter is confirmed. For summer, observations and simulations point out sea salt as the main source of gaseous inorganic bromine species. Investigations of bromide in snow pit samples do not support the importance of snowpack bromine emissions over the Antarctic Plateau. To evaluate the overall importance of the bromine chemistry over East Antarctica, BrO simulations were also discussed with respect data derived from GOME-2 satellite observations over Antarctica. Article in Journal/Newspaper Antarc* Antarctic Antarctica East Antarctica Sea ice Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Antarctic Dumont d'Urville ENVELOPE(140.017,140.017,-66.667,-66.667) Dumont-d'Urville ENVELOPE(140.013,140.013,-66.667,-66.667) East Antarctica The Antarctic Journal of Geophysical Research: Atmospheres 121 2 997 1023 |