Mass-Independent Sulfur Isotopic Compositions in Stratospheric Volcanic Eruptions

• Published in: Science
• Main Authors: Baroni, Mélanie, H. Thiemens, Mark, Delmas, Robert, Savarino, Joël
• Other Authors: Laboratoire de glaciologie et géophysique de l'environnement (LGGE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire des Sciences de l'Univers de Grenoble (OSUG), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national des sciences de l'Univers (INSU - CNRS)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS), Department of Chemistry and Biochemistry, University of California Los Angeles (UCLA), University of California-University of California
• Format: Article in Journal/Newspaper
• Language: English
• Published: HAL CCSD 2007
• Subjects: [SDU.STU.GL]Sciences of the Universe [physics]/Earth Sciences/Glaciology; [SDU.STU.VO]Sciences of the Universe [physics]/Earth Sciences/Volcanology; Antarctic; The Antarctic; Antarc*
• Online Access: https://hal-insu.archives-ouvertes.fr/insu-00375891; https://doi.org/10.1126/science.1131754

International audience The observed mass-independent sulfur isotopic composition (33S) of volcanic sulfate from the Agung (March 1963) and Pinatubo (June 1991) eruptions recorded in the Antarctic snow provides a mechanism for documenting stratospheric events. The sign of 33S changes over time from an initial positive component to a negative value. 33S is created during photochemical oxidation of sulfur dioxide to sulfuric acid on a monthly time scale, which indicates a fast process. The reproducibility of the results reveals that 33S is a reliable tracer to chemically identify atmospheric processes involved during stratospheric volcanism.