Inter-laboratory comparison on a reference material for seawater spectrophotometric pH T measurements
International audience Reference materials, as well as inter-laboratory comparisons (ILCs), are two essential metrology principles allowing the validation and evaluation of a measurement method. This paper describes the use of a reference material for seawater pH(T) measurements in an inter-laborato...
Published in: | 2023 IEEE International Workshop on Metrology for the Sea; Learning to Measure Sea Health Parameters (MetroSea) |
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Language: | English |
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HAL CCSD
2023
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Online Access: | https://hal.univ-brest.fr/hal-04402616 https://doi.org/10.1109/MetroSea58055.2023.10317274 |
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Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
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[SDE]Environmental Sciences |
spellingShingle |
[SDE]Environmental Sciences Capitaine, Gaëlle Demeyer, Séverine Stoica, Daniela Alliouane, Samir Petton, Sébastien Rimmelin-Maury, Peggy Savoye, Nicolas Wagener, Thibaut Fisicaro, Paola Inter-laboratory comparison on a reference material for seawater spectrophotometric pH T measurements |
topic_facet |
[SDE]Environmental Sciences |
description |
International audience Reference materials, as well as inter-laboratory comparisons (ILCs), are two essential metrology principles allowing the validation and evaluation of a measurement method. This paper describes the use of a reference material for seawater pH(T) measurements in an inter-laboratory comparison carried out with the French coastal observation service SOMLIT, and laboratories within the project CocoriCO(2). The interpretation of the ILC results demonstrated the capability of the spectrophotometric measurement method to provide compatible results with the reference value. The ILC data also allowed the estimation of an uncertainty budget of the spectrophotometric pH(T) measurement method following the ISO standard 21748 guidelines. The estimated standard uncertainty of the method is of 0.0046 in terms of pH(T). This level of uncertainty doesn't meet the requirements of the "climate" quality objective of the Global Ocean Acidification Observing Network for the monitoring of ocean acidification. However, some recommendations that may allow reducing this uncertainty are proposed in the paper. |
author2 |
Institut méditerranéen d'océanologie (MIO) Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS) Laboratoire National de Métrologie et d’Essais (LNE) Laboratoire d'océanographie de Villefranche (LOV) Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de la Mer de Villefranche (IMEV) Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) Laboratoire des Sciences de l'Environnement Marin (LEMAR) (LEMAR) Institut de Recherche pour le Développement (IRD)-Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER)-Université de Brest (UBO)-Institut Universitaire Européen de la Mer (IUEM) Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) Institut Universitaire Européen de la Mer (IUEM) Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS) Earth and Planetary Observation Centre (EPOC) University of Stirling Laboratoire National de Métrologie et d'Essais Trappes (LNE ) |
format |
Conference Object |
author |
Capitaine, Gaëlle Demeyer, Séverine Stoica, Daniela Alliouane, Samir Petton, Sébastien Rimmelin-Maury, Peggy Savoye, Nicolas Wagener, Thibaut Fisicaro, Paola |
author_facet |
Capitaine, Gaëlle Demeyer, Séverine Stoica, Daniela Alliouane, Samir Petton, Sébastien Rimmelin-Maury, Peggy Savoye, Nicolas Wagener, Thibaut Fisicaro, Paola |
author_sort |
Capitaine, Gaëlle |
title |
Inter-laboratory comparison on a reference material for seawater spectrophotometric pH T measurements |
title_short |
Inter-laboratory comparison on a reference material for seawater spectrophotometric pH T measurements |
title_full |
Inter-laboratory comparison on a reference material for seawater spectrophotometric pH T measurements |
title_fullStr |
Inter-laboratory comparison on a reference material for seawater spectrophotometric pH T measurements |
title_full_unstemmed |
Inter-laboratory comparison on a reference material for seawater spectrophotometric pH T measurements |
title_sort |
inter-laboratory comparison on a reference material for seawater spectrophotometric ph t measurements |
publisher |
HAL CCSD |
publishDate |
2023 |
url |
https://hal.univ-brest.fr/hal-04402616 https://doi.org/10.1109/MetroSea58055.2023.10317274 |
genre |
Ocean acidification |
genre_facet |
Ocean acidification |
op_source |
2023 IEEE International Workshop on Metrology for the Sea; Learning to Measure Sea Health Parameters (MetroSea) https://hal.univ-brest.fr/hal-04402616 2023 IEEE International Workshop on Metrology for the Sea; Learning to Measure Sea Health Parameters (MetroSea), IEEE, pp.11-15, 2023, ⟨10.1109/MetroSea58055.2023.10317274⟩ |
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info:eu-repo/semantics/altIdentifier/doi/10.1109/MetroSea58055.2023.10317274 hal-04402616 https://hal.univ-brest.fr/hal-04402616 doi:10.1109/MetroSea58055.2023.10317274 |
op_doi |
https://doi.org/10.1109/MetroSea58055.2023.10317274 |
container_title |
2023 IEEE International Workshop on Metrology for the Sea; Learning to Measure Sea Health Parameters (MetroSea) |
container_start_page |
11 |
op_container_end_page |
15 |
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1792052585983639552 |
spelling |
ftccsdartic:oai:HAL:hal-04402616v1 2024-02-27T08:44:12+00:00 Inter-laboratory comparison on a reference material for seawater spectrophotometric pH T measurements Capitaine, Gaëlle Demeyer, Séverine Stoica, Daniela Alliouane, Samir Petton, Sébastien Rimmelin-Maury, Peggy Savoye, Nicolas Wagener, Thibaut Fisicaro, Paola Institut méditerranéen d'océanologie (MIO) Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Toulon (UTLN)-Centre National de la Recherche Scientifique (CNRS) Laboratoire National de Métrologie et d’Essais (LNE) Laboratoire d'océanographie de Villefranche (LOV) Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Institut de la Mer de Villefranche (IMEV) Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) Laboratoire des Sciences de l'Environnement Marin (LEMAR) (LEMAR) Institut de Recherche pour le Développement (IRD)-Institut Français de Recherche pour l'Exploitation de la Mer (IFREMER)-Université de Brest (UBO)-Institut Universitaire Européen de la Mer (IUEM) Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS) Institut Universitaire Européen de la Mer (IUEM) Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Brest (UBO)-Centre National de la Recherche Scientifique (CNRS) Earth and Planetary Observation Centre (EPOC) University of Stirling Laboratoire National de Métrologie et d'Essais Trappes (LNE ) 2023 https://hal.univ-brest.fr/hal-04402616 https://doi.org/10.1109/MetroSea58055.2023.10317274 en eng HAL CCSD IEEE info:eu-repo/semantics/altIdentifier/doi/10.1109/MetroSea58055.2023.10317274 hal-04402616 https://hal.univ-brest.fr/hal-04402616 doi:10.1109/MetroSea58055.2023.10317274 2023 IEEE International Workshop on Metrology for the Sea; Learning to Measure Sea Health Parameters (MetroSea) https://hal.univ-brest.fr/hal-04402616 2023 IEEE International Workshop on Metrology for the Sea; Learning to Measure Sea Health Parameters (MetroSea), IEEE, pp.11-15, 2023, ⟨10.1109/MetroSea58055.2023.10317274⟩ [SDE]Environmental Sciences info:eu-repo/semantics/other Proceedings 2023 ftccsdartic https://doi.org/10.1109/MetroSea58055.2023.10317274 2024-01-28T00:05:54Z International audience Reference materials, as well as inter-laboratory comparisons (ILCs), are two essential metrology principles allowing the validation and evaluation of a measurement method. This paper describes the use of a reference material for seawater pH(T) measurements in an inter-laboratory comparison carried out with the French coastal observation service SOMLIT, and laboratories within the project CocoriCO(2). The interpretation of the ILC results demonstrated the capability of the spectrophotometric measurement method to provide compatible results with the reference value. The ILC data also allowed the estimation of an uncertainty budget of the spectrophotometric pH(T) measurement method following the ISO standard 21748 guidelines. The estimated standard uncertainty of the method is of 0.0046 in terms of pH(T). This level of uncertainty doesn't meet the requirements of the "climate" quality objective of the Global Ocean Acidification Observing Network for the monitoring of ocean acidification. However, some recommendations that may allow reducing this uncertainty are proposed in the paper. Conference Object Ocean acidification Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) 2023 IEEE International Workshop on Metrology for the Sea; Learning to Measure Sea Health Parameters (MetroSea) 11 15 |