Analysis of the impact of high moisture contents on the combustion of Russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling
The study analyzes the impact of high moisture contents in Russian peat samples on their combustion in a thermobalance, under heating rates between 5 and 100 °C/min. Raw and dried peat samples were humidified with high amounts of water (water mass percentages of 50, 60, 70, and 80%), to mimic actual...
Published in: | Biomass Conversion and Biorefinery |
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Online Access: | https://hal.archives-ouvertes.fr/hal-03654848 https://doi.org/10.1007/s13399-022-02622-x |
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ftccsdartic:oai:HAL:hal-03654848v1 2023-05-15T17:46:06+02:00 Analysis of the impact of high moisture contents on the combustion of Russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling Kangash, Alexei Kehrli, Damaris Maryandyshev, Pavel Brillard, Alain Lyubov, Viktor Brilhac, Jean-Francois Laboratoire de gestion des risques et environnement - LGRE (GRE) Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA)) 2022-04-05 https://hal.archives-ouvertes.fr/hal-03654848 https://doi.org/10.1007/s13399-022-02622-x en eng HAL CCSD Springer info:eu-repo/semantics/altIdentifier/doi/10.1007/s13399-022-02622-x hal-03654848 https://hal.archives-ouvertes.fr/hal-03654848 doi:10.1007/s13399-022-02622-x ISSN: 2190-6815 EISSN: 2190-6823 Biomass Conversion and Biorefinery https://hal.archives-ouvertes.fr/hal-03654848 Biomass Conversion and Biorefinery, Springer, 2022, ⟨10.1007/s13399-022-02622-x⟩ [SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering info:eu-repo/semantics/article Journal articles 2022 ftccsdartic https://doi.org/10.1007/s13399-022-02622-x 2022-11-20T00:19:26Z The study analyzes the impact of high moisture contents in Russian peat samples on their combustion in a thermobalance, under heating rates between 5 and 100 °C/min. Raw and dried peat samples were humidified with high amounts of water (water mass percentages of 50, 60, 70, and 80%), to mimic actual peat which is taken from the topsoil in Northwest Russia. The thermogravimetric profiles associated with the combustion of the raw and wet samples were compared. Gaseous emissions (CO, CO2, NO, NO2, and total hydrocarbons (THC)) were continuously measured during complementary combustion experiments performed in a horizontal oven under isothermal temperatures of 600, 700, 800, or 900 °C, then compared, to analyze the impact of the moisture contents. Kinetic modeling of the combustion processes of the raw and wet peat samples was finally performed using the Extended Independent Parallel Reaction model. Three constituents were considered, among which the moisture contents. The impact of the high moisture contents on the optimal values of the kinetic parameters thus obtained is analyzed. This impact on the combustion behavior of wet peat samples is finally proved to be almost negligible, when applying low heating rates between 5 and 100 °C/min. Nevertheless, observing the threshold of 52% for the moisture content of peat samples imposed by the Russian standards GOST R 50,902–2011 reduces the energy required for the drying process. Article in Journal/Newspaper Northwest Russia Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Biomass Conversion and Biorefinery |
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Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering |
spellingShingle |
[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering Kangash, Alexei Kehrli, Damaris Maryandyshev, Pavel Brillard, Alain Lyubov, Viktor Brilhac, Jean-Francois Analysis of the impact of high moisture contents on the combustion of Russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling |
topic_facet |
[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering |
description |
The study analyzes the impact of high moisture contents in Russian peat samples on their combustion in a thermobalance, under heating rates between 5 and 100 °C/min. Raw and dried peat samples were humidified with high amounts of water (water mass percentages of 50, 60, 70, and 80%), to mimic actual peat which is taken from the topsoil in Northwest Russia. The thermogravimetric profiles associated with the combustion of the raw and wet samples were compared. Gaseous emissions (CO, CO2, NO, NO2, and total hydrocarbons (THC)) were continuously measured during complementary combustion experiments performed in a horizontal oven under isothermal temperatures of 600, 700, 800, or 900 °C, then compared, to analyze the impact of the moisture contents. Kinetic modeling of the combustion processes of the raw and wet peat samples was finally performed using the Extended Independent Parallel Reaction model. Three constituents were considered, among which the moisture contents. The impact of the high moisture contents on the optimal values of the kinetic parameters thus obtained is analyzed. This impact on the combustion behavior of wet peat samples is finally proved to be almost negligible, when applying low heating rates between 5 and 100 °C/min. Nevertheless, observing the threshold of 52% for the moisture content of peat samples imposed by the Russian standards GOST R 50,902–2011 reduces the energy required for the drying process. |
author2 |
Laboratoire de gestion des risques et environnement - LGRE (GRE) Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA)) |
format |
Article in Journal/Newspaper |
author |
Kangash, Alexei Kehrli, Damaris Maryandyshev, Pavel Brillard, Alain Lyubov, Viktor Brilhac, Jean-Francois |
author_facet |
Kangash, Alexei Kehrli, Damaris Maryandyshev, Pavel Brillard, Alain Lyubov, Viktor Brilhac, Jean-Francois |
author_sort |
Kangash, Alexei |
title |
Analysis of the impact of high moisture contents on the combustion of Russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling |
title_short |
Analysis of the impact of high moisture contents on the combustion of Russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling |
title_full |
Analysis of the impact of high moisture contents on the combustion of Russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling |
title_fullStr |
Analysis of the impact of high moisture contents on the combustion of Russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling |
title_full_unstemmed |
Analysis of the impact of high moisture contents on the combustion of Russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling |
title_sort |
analysis of the impact of high moisture contents on the combustion of russian peat under low heating rates, on the subsequent gaseous emissions and on the associated kinetic modeling |
publisher |
HAL CCSD |
publishDate |
2022 |
url |
https://hal.archives-ouvertes.fr/hal-03654848 https://doi.org/10.1007/s13399-022-02622-x |
genre |
Northwest Russia |
genre_facet |
Northwest Russia |
op_source |
ISSN: 2190-6815 EISSN: 2190-6823 Biomass Conversion and Biorefinery https://hal.archives-ouvertes.fr/hal-03654848 Biomass Conversion and Biorefinery, Springer, 2022, ⟨10.1007/s13399-022-02622-x⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1007/s13399-022-02622-x hal-03654848 https://hal.archives-ouvertes.fr/hal-03654848 doi:10.1007/s13399-022-02622-x |
op_doi |
https://doi.org/10.1007/s13399-022-02622-x |
container_title |
Biomass Conversion and Biorefinery |
_version_ |
1766149454782529536 |