Differing Mechanisms of New Particle Formation at Two Arctic Sites
International audience New particle formation in the Arctic atmosphere is an important source of aerosol particles. Understanding the processes of Arctic secondary aerosol formation is crucial due to their significant impact on cloud properties and therefore Arctic amplification. We observed the mol...
Published in: | Geophysical Research Letters |
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Main Authors: | , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , |
Other Authors: | , , , , , , , , , , , , , , , , , , , , , , , |
Format: | Article in Journal/Newspaper |
Language: | English |
Published: |
HAL CCSD
2020
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Subjects: | |
Online Access: | https://hal.archives-ouvertes.fr/hal-03150305 https://hal.archives-ouvertes.fr/hal-03150305/document https://hal.archives-ouvertes.fr/hal-03150305/file/2020GL091334.pdf https://doi.org/10.1029/2020GL091334 |
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ftccsdartic:oai:HAL:hal-03150305v1 |
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record_format |
openpolar |
institution |
Open Polar |
collection |
Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) |
op_collection_id |
ftccsdartic |
language |
English |
topic |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere [SDU.STU.ME]Sciences of the Universe [physics]/Earth Sciences/Meteorology |
spellingShingle |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere [SDU.STU.ME]Sciences of the Universe [physics]/Earth Sciences/Meteorology Beck, Lisa, Sarnela, Nina Junninen, Heikki Hoppe, Clara, Garmash, Olga Bianchi, Federico Riva, Matthieu Rose, Clémence Peräkylä, Otso Wimmer, Daniela Kausiala, Oskari Jokinen, Tuija Ahonen, Lauri Mikkilä, Jyri Hakala, Jani He, Xu-Cheng Kontkanen, Jenni Wolf, Klara, Cappelletti, David Mazzola, Mauro Traversi, Rita Petroselli, Chiara Viola, Angelo, Vitale, Vito Lange, Robert Massling, Andreas Nøjgaard, Jakob, Krejci, Radovan Karlsson, Linn Zieger, Paul Jang, Sehyun Lee, Kitack Vakkari, Ville Lampilahti, Janne Thakur, Roseline, Leino, Katri Kangasluoma, Juha Duplissy, Ella-Maria Siivola, Erkki Marbouti, Marjan Tham, Yee, Saiz-Lopez, Alfonso Petäjä, Tuukka Ehn, Mikael Worsnop, Douglas, Skov, Henrik Kulmala, Markku Kerminen, Veli-Matti Sipilä, Mikko Differing Mechanisms of New Particle Formation at Two Arctic Sites |
topic_facet |
[PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere [SDU.STU.ME]Sciences of the Universe [physics]/Earth Sciences/Meteorology |
description |
International audience New particle formation in the Arctic atmosphere is an important source of aerosol particles. Understanding the processes of Arctic secondary aerosol formation is crucial due to their significant impact on cloud properties and therefore Arctic amplification. We observed the molecular formation of new particles from low-volatility vapors at two Arctic sites with differing surroundings. In Svalbard, sulfuric acid (SA) and methane sulfonic acid (MSA) contribute to the formation of secondary aerosol and to some extent to cloud condensation nuclei (CCN). This occurs via ion-induced nucleation of SA and NH 3 and subsequent growth by mainly SA and MSA condensation during springtime and highly oxygenated organic molecules during summertime. By contrast, in an ice-covered region around Villum, we observed new particle formation driven by iodic acid but its concentration was insufficient to grow nucleated particles to CCN sizes. Our results provide new insight about sources and precursors of Arctic secondary aerosol particles. Plain Language Summary Cloud properties are sensitive to the formation of new aerosol particles in the Arctic atmosphere, yet little is known about the chemistry and processes controlling this phenomenon. Here, based on comprehensive in situ measurements, we identify the very first steps of atmospheric new particle formation, that is, formation of small clusters from compounds present in the gas phase, and candidates for the subsequent growth of these clusters to larger sizes, at two Arctic sites: one surrounded by open waters, the other one by sea ice. We show how environmental differences affect secondary aerosol formation via emissions and atmospheric chemistry of aerosol precursor gases. Our results provide previously unidentified insight into how future changes in the Polar environment could BECK ET AL. |
author2 |
Institute for Atmospheric and Earth System Research (INAR) University of Helsinki University of Tartu Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung (AWI) Université Claude Bernard Lyon 1 (UCBL) Université de Lyon Laboratoire de Météorologie Physique (LaMP) Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA) Department of Chemistry, Biology & Biotechnology, University of Perugia Università degli Studi di Perugia (UNIPG) Consiglio Nazionale delle Ricerche Bologna (CNR) Università degli Studi di Firenze = University of Florence Firenze (UNIFI) Consiglio Nazionale delle Ricerche (CNR) iCLIMATE Aarhus University Interdisciplinary Centre for Climate Change Aarhus University Aarhus Stockholm University Bolin Centre for Climate Research Pohang University of Science and Technology (POSTECH) Finnish Meteorological Institute (FMI) North-West University Potchefstroom (NWU) Beijing University of Chemical Technology Spanish National Research Council Madrid (CSIC) Aerodyne Research Inc. Nanjing University (NJU) |
format |
Article in Journal/Newspaper |
author |
Beck, Lisa, Sarnela, Nina Junninen, Heikki Hoppe, Clara, Garmash, Olga Bianchi, Federico Riva, Matthieu Rose, Clémence Peräkylä, Otso Wimmer, Daniela Kausiala, Oskari Jokinen, Tuija Ahonen, Lauri Mikkilä, Jyri Hakala, Jani He, Xu-Cheng Kontkanen, Jenni Wolf, Klara, Cappelletti, David Mazzola, Mauro Traversi, Rita Petroselli, Chiara Viola, Angelo, Vitale, Vito Lange, Robert Massling, Andreas Nøjgaard, Jakob, Krejci, Radovan Karlsson, Linn Zieger, Paul Jang, Sehyun Lee, Kitack Vakkari, Ville Lampilahti, Janne Thakur, Roseline, Leino, Katri Kangasluoma, Juha Duplissy, Ella-Maria Siivola, Erkki Marbouti, Marjan Tham, Yee, Saiz-Lopez, Alfonso Petäjä, Tuukka Ehn, Mikael Worsnop, Douglas, Skov, Henrik Kulmala, Markku Kerminen, Veli-Matti Sipilä, Mikko |
author_facet |
Beck, Lisa, Sarnela, Nina Junninen, Heikki Hoppe, Clara, Garmash, Olga Bianchi, Federico Riva, Matthieu Rose, Clémence Peräkylä, Otso Wimmer, Daniela Kausiala, Oskari Jokinen, Tuija Ahonen, Lauri Mikkilä, Jyri Hakala, Jani He, Xu-Cheng Kontkanen, Jenni Wolf, Klara, Cappelletti, David Mazzola, Mauro Traversi, Rita Petroselli, Chiara Viola, Angelo, Vitale, Vito Lange, Robert Massling, Andreas Nøjgaard, Jakob, Krejci, Radovan Karlsson, Linn Zieger, Paul Jang, Sehyun Lee, Kitack Vakkari, Ville Lampilahti, Janne Thakur, Roseline, Leino, Katri Kangasluoma, Juha Duplissy, Ella-Maria Siivola, Erkki Marbouti, Marjan Tham, Yee, Saiz-Lopez, Alfonso Petäjä, Tuukka Ehn, Mikael Worsnop, Douglas, Skov, Henrik Kulmala, Markku Kerminen, Veli-Matti Sipilä, Mikko |
author_sort |
Beck, Lisa, |
title |
Differing Mechanisms of New Particle Formation at Two Arctic Sites |
title_short |
Differing Mechanisms of New Particle Formation at Two Arctic Sites |
title_full |
Differing Mechanisms of New Particle Formation at Two Arctic Sites |
title_fullStr |
Differing Mechanisms of New Particle Formation at Two Arctic Sites |
title_full_unstemmed |
Differing Mechanisms of New Particle Formation at Two Arctic Sites |
title_sort |
differing mechanisms of new particle formation at two arctic sites |
publisher |
HAL CCSD |
publishDate |
2020 |
url |
https://hal.archives-ouvertes.fr/hal-03150305 https://hal.archives-ouvertes.fr/hal-03150305/document https://hal.archives-ouvertes.fr/hal-03150305/file/2020GL091334.pdf https://doi.org/10.1029/2020GL091334 |
long_lat |
ENVELOPE(67.017,67.017,-71.033,-71.033) |
geographic |
Arctic Beck Svalbard |
geographic_facet |
Arctic Beck Svalbard |
genre |
Arctic Sea ice Svalbard |
genre_facet |
Arctic Sea ice Svalbard |
op_source |
ISSN: 0094-8276 EISSN: 1944-8007 Geophysical Research Letters https://hal.archives-ouvertes.fr/hal-03150305 Geophysical Research Letters, American Geophysical Union, 2020, ⟨10.1029/2020GL091334⟩ |
op_relation |
info:eu-repo/semantics/altIdentifier/doi/10.1029/2020GL091334 hal-03150305 https://hal.archives-ouvertes.fr/hal-03150305 https://hal.archives-ouvertes.fr/hal-03150305/document https://hal.archives-ouvertes.fr/hal-03150305/file/2020GL091334.pdf doi:10.1029/2020GL091334 |
op_rights |
info:eu-repo/semantics/OpenAccess |
op_doi |
https://doi.org/10.1029/2020GL091334 |
container_title |
Geophysical Research Letters |
container_volume |
48 |
container_issue |
4 |
_version_ |
1766309848397381632 |
spelling |
ftccsdartic:oai:HAL:hal-03150305v1 2023-05-15T14:37:38+02:00 Differing Mechanisms of New Particle Formation at Two Arctic Sites Beck, Lisa, Sarnela, Nina Junninen, Heikki Hoppe, Clara, Garmash, Olga Bianchi, Federico Riva, Matthieu Rose, Clémence Peräkylä, Otso Wimmer, Daniela Kausiala, Oskari Jokinen, Tuija Ahonen, Lauri Mikkilä, Jyri Hakala, Jani He, Xu-Cheng Kontkanen, Jenni Wolf, Klara, Cappelletti, David Mazzola, Mauro Traversi, Rita Petroselli, Chiara Viola, Angelo, Vitale, Vito Lange, Robert Massling, Andreas Nøjgaard, Jakob, Krejci, Radovan Karlsson, Linn Zieger, Paul Jang, Sehyun Lee, Kitack Vakkari, Ville Lampilahti, Janne Thakur, Roseline, Leino, Katri Kangasluoma, Juha Duplissy, Ella-Maria Siivola, Erkki Marbouti, Marjan Tham, Yee, Saiz-Lopez, Alfonso Petäjä, Tuukka Ehn, Mikael Worsnop, Douglas, Skov, Henrik Kulmala, Markku Kerminen, Veli-Matti Sipilä, Mikko Institute for Atmospheric and Earth System Research (INAR) University of Helsinki University of Tartu Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung (AWI) Université Claude Bernard Lyon 1 (UCBL) Université de Lyon Laboratoire de Météorologie Physique (LaMP) Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA) Department of Chemistry, Biology & Biotechnology, University of Perugia Università degli Studi di Perugia (UNIPG) Consiglio Nazionale delle Ricerche Bologna (CNR) Università degli Studi di Firenze = University of Florence Firenze (UNIFI) Consiglio Nazionale delle Ricerche (CNR) iCLIMATE Aarhus University Interdisciplinary Centre for Climate Change Aarhus University Aarhus Stockholm University Bolin Centre for Climate Research Pohang University of Science and Technology (POSTECH) Finnish Meteorological Institute (FMI) North-West University Potchefstroom (NWU) Beijing University of Chemical Technology Spanish National Research Council Madrid (CSIC) Aerodyne Research Inc. Nanjing University (NJU) 2020-12-28 https://hal.archives-ouvertes.fr/hal-03150305 https://hal.archives-ouvertes.fr/hal-03150305/document https://hal.archives-ouvertes.fr/hal-03150305/file/2020GL091334.pdf https://doi.org/10.1029/2020GL091334 en eng HAL CCSD American Geophysical Union info:eu-repo/semantics/altIdentifier/doi/10.1029/2020GL091334 hal-03150305 https://hal.archives-ouvertes.fr/hal-03150305 https://hal.archives-ouvertes.fr/hal-03150305/document https://hal.archives-ouvertes.fr/hal-03150305/file/2020GL091334.pdf doi:10.1029/2020GL091334 info:eu-repo/semantics/OpenAccess ISSN: 0094-8276 EISSN: 1944-8007 Geophysical Research Letters https://hal.archives-ouvertes.fr/hal-03150305 Geophysical Research Letters, American Geophysical Union, 2020, ⟨10.1029/2020GL091334⟩ [PHYS.PHYS.PHYS-AO-PH]Physics [physics]/Physics [physics]/Atmospheric and Oceanic Physics [physics.ao-ph] [SDU.OCEAN]Sciences of the Universe [physics]/Ocean Atmosphere [SDU.STU.ME]Sciences of the Universe [physics]/Earth Sciences/Meteorology info:eu-repo/semantics/article Journal articles 2020 ftccsdartic https://doi.org/10.1029/2020GL091334 2021-12-19T00:28:27Z International audience New particle formation in the Arctic atmosphere is an important source of aerosol particles. Understanding the processes of Arctic secondary aerosol formation is crucial due to their significant impact on cloud properties and therefore Arctic amplification. We observed the molecular formation of new particles from low-volatility vapors at two Arctic sites with differing surroundings. In Svalbard, sulfuric acid (SA) and methane sulfonic acid (MSA) contribute to the formation of secondary aerosol and to some extent to cloud condensation nuclei (CCN). This occurs via ion-induced nucleation of SA and NH 3 and subsequent growth by mainly SA and MSA condensation during springtime and highly oxygenated organic molecules during summertime. By contrast, in an ice-covered region around Villum, we observed new particle formation driven by iodic acid but its concentration was insufficient to grow nucleated particles to CCN sizes. Our results provide new insight about sources and precursors of Arctic secondary aerosol particles. Plain Language Summary Cloud properties are sensitive to the formation of new aerosol particles in the Arctic atmosphere, yet little is known about the chemistry and processes controlling this phenomenon. Here, based on comprehensive in situ measurements, we identify the very first steps of atmospheric new particle formation, that is, formation of small clusters from compounds present in the gas phase, and candidates for the subsequent growth of these clusters to larger sizes, at two Arctic sites: one surrounded by open waters, the other one by sea ice. We show how environmental differences affect secondary aerosol formation via emissions and atmospheric chemistry of aerosol precursor gases. Our results provide previously unidentified insight into how future changes in the Polar environment could BECK ET AL. Article in Journal/Newspaper Arctic Sea ice Svalbard Archive ouverte HAL (Hyper Article en Ligne, CCSD - Centre pour la Communication Scientifique Directe) Arctic Beck ENVELOPE(67.017,67.017,-71.033,-71.033) Svalbard Geophysical Research Letters 48 4 |